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1.发明申请METHODS FOR THE SPRAY APPLICATION OF COATINGS USING SUBCRITICAL COMPRESSED FLUIDS TO REDUCE VISCOSITY AND ENHANCE ATOMIZATION 审中-公开使用亚临界压缩流体喷涂涂料以降低粘度并增强雾化的方法
公开(公告)号：WO0029127A2
公开(公告)日：2000-05-25
申请号：PCT/US9927303
申请日：1999-11-17
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： NIELSEN KENNETH ANDREW
CPC classification number: B05D1/025 , B05D2401/90
Abstract: Processes are disclosed for the use of subcritical compressed fluids, such as carbon dioxide or ethane, to reduce viscosity and to enhance atomization when spray applying coating compositions containing low molecular weight polymers to substrates, by using spray conditions that produce choked flow in the liquid mixture being sprayed, wherein the subcritical compressed fluid is a gas at standard conditions of 0 DEG C temperature and one atmosphere pressure and is miscible with the coating composition.
Abstract translation: 公开了使用亚临界压缩流体如二氧化碳或乙烷来降低粘度并在通过使用在液体混合物中产生堵塞流的喷雾条件将含有低分子量聚合物的涂料组合物喷涂到基材上时增强雾化的方法 其中亚临界压缩流体是在0℃温度和1个大气压的标准条件下的气体并且可与涂料组合物混溶。
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2.发明申请SUBCRITICAL COMPRESSED FLUIDS AS VISCOSITY REDUCING DILUENTS FOR TRANSPORTABLE COMPOSITIONS 审中-公开亚临界压缩液作为粘度降低可运输组合物的稀释液
公开(公告)号：WO9211310A3
公开(公告)日：1993-06-10
申请号：PCT/US9109187
申请日：1991-12-18
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： NIELSEN KENNETH ANDREW
CPC classification number: C09D7/00 , B05D1/025 , B05D2401/90
Abstract: Processes are disclosed for reducing the viscosity of compositions containing one or more polymeric compounds so as to make them transportable by adding a subcritical compressed fluid, which fluid is a gas at standard conditions of 0 °C and one atmosphere pressure.
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3.发明申请CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF HYDROCARBONS AND PREPARATION THEREOF 审中-公开氢氧化物脱氢催化剂及其制备方法
公开(公告)号：WO0222258A3
公开(公告)日：2002-06-20
申请号：PCT/US0128924
申请日：2001-09-13
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： CANTRELL RICK DAVID , GHENCIU ANCA , CAMBPELL KENNETH DWIGHT , MINAHAN DAVID MICHAEL ANTHONY , BHASIN MADAN MOHAN , WESTWOOD ALISTAIR DUNCAN , NIELSEN KENNETH ANDREW
IPC: B01J23/10 , B01J27/232 , B01J27/236 , B01J27/25 , B01J37/14 , C01F17/00 , C07B61/00 , C07C2/84 , C07C5/48 , C07C9/06 , C07C9/08 , C07C11/04 , B01J37/08
CPC classification number: C07C2/84 , B01J23/10 , B01J27/232 , C01F17/005 , C01P2002/01 , C01P2006/12 , C07C5/48 , C07C2527/232 , C07C2527/236 , Y02P20/52 , C07C11/04
Abstract: The present invention provides a catalyst for the oxidative dehydrogenation of a lower hydrocarbon to form at least one higher hydrocarbon and/or lower olefin. In one embodiment, the catalyst includes a nonstoichiometric rare earth oxycarbonate of the formula MxCyOz having a disordered and/or defect structure, wherein M is at elast one rare earth element selected from the group consisting of La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; X = 2; Z = 3 + AY; A is less than about 1.8, and Y is the number of carbom atoms in the oxycarbonate. When used for the oxidative dehydrogenation of a lower hydrocarbon at a pressure above bout 100 psig. the catalyst has a selectivity of at least about 40 percent to at least one higher hydrocarbon and/or lower olefin. Methods for preparing catalysts taught by the invention and processes for using the catalysts for the oxidative dehydrogenation of lower hydrocarbons are also provided.
Abstract translation: 本发明提供了用于低级烃的氧化脱氢以形成至少一种较高级烃和/或低级烯烃的催化剂。 在一个实施方案中，催化剂包括具有无序和/或缺陷结构的式MxCyOz的非化学计量稀土氧碳酸盐，其中M为选自La，Pr，Nd，Sm，Eu的弹性一种稀土元素， Gd，Tb，Dy，Ho，Er和Tm; X = 2; Z = 3 + AY; A小于约1.8，Y是碳酸酯中的碳原子数。 当在高于100psig的压力下用于低级烃的氧化脱氢。 催化剂对至少一种较高级烃和/或低级烯烃具有至少约40％的选择性。 还提供了用于制备本发明教导的催化剂的方法和使用该催化剂用于低级烃的氧化脱氢的方法。
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公开(公告)号：ES2151581T3
公开(公告)日：2001-01-01
申请号：ES95308100
申请日：1995-11-13
Applicant: UNION CARBIDE CHEM PLASTIC
Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.
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公开(公告)号：AT195665T
公开(公告)日：2000-09-15
申请号：AT95308100
申请日：1995-11-13
Applicant: UNION CARBIDE CHEM PLASTIC
Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.
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Patent Agency Ranking
公开(公告)号：CA2305356A1
公开(公告)日：1999-04-22
申请号：CA2305356
申请日：1998-10-09
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： CESARETTI RICHARD SCOTT , GOAD JEFFREY DALE , BAUMERT DUANE FRANCIS , NIELSEN KENNETH ANDREW
IPC: D06B1/02 , B05D1/02 , B05D7/00 , C09K3/30 , D06M23/06 , D06M23/10 , D21H21/22 , D21H23/24 , D21H23/50
Abstract: The present invention is directed to methods for the spray application of additive compositions containing additive materials in the manufacture of sheet material products, such as paper products, textile products, and flexible sheet products by using compressed fluids, such as carbon dioxide and ethane, as a spraying medium. Additive compositions with high viscosity and which are substantially free of water and/or volatile solvent can be applied to sheet materials. Water-borne additive compositions with reduced water content can also be applied to sheet materials. One preferred spray method uses a decompressive spray of the compressed fluid which produces a uniform spray pattern and a narrow droplet size distribution that can improve application efficiency and quality when additive compositions are applied during the spraying step to rapidly conveyed sheet materials.
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公开(公告)号：AU692936B2
公开(公告)日：1998-06-18
申请号：AU3779495
申请日：1995-11-13
Applicant: UNION CARBIDE CHEM PLASTIC
IPC: B01D1/18 , B01J37/02 , B05D1/02 , C08J3/12 , C09D5/02 , B01J37/00 , C09D5/03 , C09D101/14 , C09D127/06 , C09D133/08 , C09D171/02 , B05B7/14 , B05B12/10 , B05B1/00 , B01J35/02
Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.
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8.发明专利
公开(公告)号：AU692476B2
公开(公告)日：1998-06-11
申请号：AU7854994
申请日：1994-09-27
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： NIELSEN KENNETH ANDREW
Abstract: The present invention is directed to methods for spraying polymeric compositions with supercritical or subcritical compressed fluids such as carbon dioxide or ethane over a wider range of spray conditions to provide improved spray application quality with reduced emission of solvent. The methods are accomplished by using an elongated spray orifice to transform narrow, fishtail, liquid-film sprays to wider, feathered, decompressive sprays.
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公开(公告)号：ES2111701T3
公开(公告)日：1998-03-16
申请号：ES93120448
申请日：1993-12-17
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： NIELSEN KENNETH ANDREW , BUSBY DAVID CHARLES , DONOHUE MARC DAVID , GLANCY CHARLES WILLIAM
Abstract: A process of spraying a polymeric compsn. to form a spray of finely atomised liq. droplets comprises (1) forming in a closed system a liq. mixt. a temp. T0 comprising: (a) a non-volatile fraction contg. at least one polymer that is cable of being sprayed; and (b) a solvent fraction that is partially miscible with (a) and contains an amt. of at least one compressed fluid sufficient, when it is added to (a); (i) to make the viscosity of the mixt. suitable for spraying; and (ii) to let the liq. mixt. form a liq. compressed fluid phase at temp. T0 the compressed fluid being a gas at 0 deg. C and 1 atmos. pressure; and (2) spraying the liq. mixt. by passing it at temp. T0 and spray pressure P, into an orifice, through which the mixt. flows to form a liq. spray, where spray pressure P1 is above the min. pressure P2 at which the liq. mixt. forms a liq. compressed fluid phase at temp. T0, thus passing the liq. mixt. through the liq.-liq. region of the polymer compsn. and compressed fluid during depressurisation.
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公开(公告)号：DE69316733D1
公开(公告)日：1998-03-05
申请号：DE69316733
申请日：1993-12-17
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor： NIELSEN KENNETH ANDREW , BUSBY DAVID CHARLES , DONOHUE MARC DAVID , GLANCY CHARLES WILLIAM
Abstract: A process of spraying a polymeric compsn. to form a spray of finely atomised liq. droplets comprises (1) forming in a closed system a liq. mixt. a temp. T0 comprising: (a) a non-volatile fraction contg. at least one polymer that is cable of being sprayed; and (b) a solvent fraction that is partially miscible with (a) and contains an amt. of at least one compressed fluid sufficient, when it is added to (a); (i) to make the viscosity of the mixt. suitable for spraying; and (ii) to let the liq. mixt. form a liq. compressed fluid phase at temp. T0 the compressed fluid being a gas at 0 deg. C and 1 atmos. pressure; and (2) spraying the liq. mixt. by passing it at temp. T0 and spray pressure P, into an orifice, through which the mixt. flows to form a liq. spray, where spray pressure P1 is above the min. pressure P2 at which the liq. mixt. forms a liq. compressed fluid phase at temp. T0, thus passing the liq. mixt. through the liq.-liq. region of the polymer compsn. and compressed fluid during depressurisation.
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