公开(公告)号：AT229931T

公开(公告)日：2003-01-15

申请号：AT97918801

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRIGGS JOHN ROBERT ,  OLSON KURT KAMAR ,  TJADEN ERIK BRUCE ,  GURAM ANIL SAKHARAM ,  PACKETT DIANE LEE ,  EISENSCHMID THOMAS CARL ,  BRIGHAM ELAINE SUSAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to hydrocarbonylation in the presence of a hydrocarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.

公开(公告)号：AT223368T

公开(公告)日：2002-09-15

申请号：AT97921364

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRIGGS JOHN ROBERT ,  PACKETT DIANE LEE ,  BRYANT DAVID ROBERT ,  PHILLIPS AILENE GARDNER ,  SCHRECK DAVID JAMES ,  OLSON KURT DAMAR ,  TJADEN ERICK BRUCE ,  GURAM ANIL SAKHARAM ,  EISENSCHMID THOMAS CARL ,  BRAGHAM ELAINE SUSAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to hydrocarbonylation in the presence of a hydrocarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.

公开(公告)号：BR9708856A

公开(公告)日：1999-08-03

申请号：BR9708856

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRIGGS JOHN ROBERT ,  OLSON KURT KAMAR ,  TJADEN ERIK BRUCE ,  GURAM ANIL SAKHARAM ,  PACKETT DIANE LEE ,  EISENSCHMID THOMAS CARL ,  BRUGHAM ELAIN SUSAN

IPC: C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19

公开(公告)号：PL329409A1

公开(公告)日：1999-03-29

申请号：PL32940997

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： PACKETT DIANE LEE ,  BRIGGS JOHN ROBERT ,  BRYANT DAVID ROBERT ,  SCHRECK DAVID JAMES ,  PHILLIPS AILENE GARDNER ,  OLSON KURT DAMAR ,  TJADEN ERICK BRUCE ,  GURAM ANIL SAKHARAM ,  EISENSCHMID THOMAS CARL ,  BRAGHAM ELAINE SUSAN

IPC: C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  B01J31/24 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to hydrocarbonylation in the presence of a hydrocarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.

公开(公告)号：CA2252478A1

公开(公告)日：1997-10-30

申请号：CA2252478

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： EISENSCHMID THOMAS CARL ,  GURAM ANIL SAKHARAM ,  BRYANT DAVID ROBERT ,  TJADEN ERICK BRUCE ,  PHILLIPS AILENE GARDNER ,  OLSON KURT DAMAR ,  SCHRECK DAVID JAMES ,  BRAGHAM ELAINE SUSAN ,  BRIGGS JOHN ROBERT ,  PACKETT DIANE LEE

IPC: B01J31/24 ,  C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36 ,  C07C33/025 ,  C07D307/20

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to reductive hydroformylation in the presence of a reductive hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.

公开(公告)号：PL329372A1

公开(公告)日：1999-03-29

申请号：PL32937297

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRIGGS JOHN ROBERT ,  OLSON KURT KAMAR ,  TJADEN ERIK BRUCE ,  GURAM ANIL SAKHARAM ,  PACKETT DIANE LEE ,  EISENSCHMID THOMAS CARL ,  BRIGHAM ELAINE SUSAN

IPC: C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  B01J31/24 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to hydrocarbonylation in the presence of a hydrocarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.

公开(公告)号：MX9808489A

公开(公告)日：1999-02-28

申请号：MX9808489

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： BRIGGS JOHN ROBERT ,  OLSON KURT KAMAR ,  TJADEN ERIK BRUCE ,  GURAM ANIL SAKHARAM ,  PACKETT DIANE LEE ,  EISENSCHMID THOMAS CARL ,  BRIGHAM ELAINE SUSAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

公开(公告)号：CA2285745A1

公开(公告)日：1998-10-22

申请号：CA2285745

申请日：1998-04-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： PACKETT DIANE LEE ,  BRIGGS JOHN ROBERT ,  OLSON KURT DAMAR ,  MAHER JOHN MICHAEL ,  EISENSCHMID THOMAS CARL

IPC: B01J31/24 ,  C07B61/00 ,  C07D201/02 ,  C07D201/08 ,  C07D223/10 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactams, e.g., epsilon caprolactam, which comprises: (a) subjecting one or more substituted or unsubstituted alkadienes to hydroxycarbonylation in the presence of a hydroxycarbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and neutralization with a base to produce one or more substituted or unsubstituted pentenoic acid salts; (b) subjecting said one or more substituted or unsubstituted pentenoic acid salts to hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted formylvaleric acid salts and/or one or more substituted or unsubstituted epsilon caprolactam precursors; and (c) subjecting said one or more substituted or unsubstituted formylvaleric acid salts and/or said one or more substituted or unsubstituted epsilon caprolactam precursors to reductive amination in the presence of a reductive amination catalyst and cyclization optionally in the presence of a cyclization catalyst to produce said one or more substituted or unsubstituted epsilon caprolactams. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactams as the principal product(s) of reaction.

公开(公告)号：ID19360A

公开(公告)日：1998-07-02

申请号：ID971376

申请日：1997-04-24

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： GURAM ANIL SHAKARAM ,  BRIGGS JOHN ROBERT ,  PACKETT DIANE LEE ,  OLSON KURT DAMAR ,  EISENSCHMID THOMAS CARL

IPC: C07C27/22 ,  C07C29/141 ,  C07C29/16 ,  C07C29/46 ,  C07C31/20 ,  C07C33/025 ,  C07C45/49 ,  C07C45/50 ,  C07C45/67 ,  C07C47/12 ,  C07C47/21

Abstract: This invention relates in part to processes for producing one or more substituted or unsubstituted 1,6-hexanediols which comprise subjecting one or more substituted or unsubstituted penten-1-ols to reductive hydroformylation in the presence of a reductive hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted 1,6-hexanediols. The substituted and unsubstituted 1,6-hexanediols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted 1,6-hexanediols as principal product(s) of reaction.

公开(公告)号：AU2658197A

公开(公告)日：1997-11-12

申请号：AU2658197

申请日：1997-04-23

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： GURAM ANIL SAKHARAM ,  BRIGGS JOHN ROBERT ,  OLSON KURT DAMAR ,  EISENSCHMID THOMAS CARL ,  PACKETT DIANE LEE ,  TJADEN ERIK BRUCE

IPC: C07C29/16 ,  C07C45/49 ,  C07C47/12 ,  C07C47/21 ,  C07C31/20