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公开(公告)号：KR870000200B1
公开(公告)日：1987-02-16
申请号：KR820003667
申请日：1982-08-16
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BRYANT DAVID R
Abstract: Aldehydes are produced by hydroformylating an olefinically unsatd. compd. with CO and H2 in a reaction medium contg. a rhodium complex catalyst, free triarylphosphine ligand and free organic tert. bisphosphine monoxide ligand of formula(I) with the mole ration of triarylphosphine ligand to (I) being (2-30):1 (Ar is an opt. substd. aryl; R1, R2 and R3 are opt. subst. monovalent hydrocarbyl; and Y is a divalent bridging gp.). Also clamined is a rhodium complex hydroformylating catalystic precursor compsn. comprising a solubilised rhodium carbonyl phosphorus acetylacetonate complex, an organic solvent and the ligands given above.
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公开(公告)号：CS271475B2
公开(公告)日：1990-10-12
申请号：CS527687
申请日：1987-07-10
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BRYANT DAVID R
Abstract: A nonaqueous hydroformylation process for producing aldehydes using low volatile, organic soluble monosulfonated tertiary phosphine salt ligands.
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公开(公告)号：CS271311B2
公开(公告)日：1990-09-12
申请号：CS109185
申请日：1985-02-15
Applicant: UNION CARBIDE CORP
Inventor： BILLIG ERNST , ABATJOGLOU ANTHONY G , BRYANT DAVID R , MURRAY REX E , MAHER JOHN M
IPC: C07C47/02 , B01J27/18 , B01J31/18 , B01J31/20 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F9/06 , C07F9/547 , C07F9/6564 , C07F9/6574 , C07F9/6578 , C07F15/00
Abstract: Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.
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公开(公告)号：HUT47515A
公开(公告)日：1989-03-28
申请号：HU382586
申请日：1986-09-04
Applicant: UNION CARBIDE CORP
Inventor： BILLIG ERNST , ABATJOGLOU ANTHONY G , BRYANT DAVID R
IPC: B01J31/24 , B01J31/00 , B01J31/22 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C47/042 , C07C67/00 , C07F9/09 , C07F9/145 , C07F9/6574 , C07F9/6578 , C07F15/00 , C07C27/20 , C07F9/14
Abstract: Transition metal-bis-phosphite catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-bis-phosphite compositions, bis-phosphite ligands and transition metal-bis-phosphite catalysts.
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公开(公告)号：CA1212961A
公开(公告)日：1986-10-21
申请号：CA407995
申请日：1982-07-23
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , KAPICAK LOUIS A
Abstract: PROCESS FOR PREPARING ORGANIC TERTIARY POLYPHOSPHINE MONOOXIDES Process for producing organic tertiary polyphosphine monooxides which comprises reacting an organic tertiary polyphosphine with an organic monofunctional alkylating agent to form an intermediate monophosphonium salt of the polyphosphine starting material and then hydrolyzing the salt so produced to the desired polyphosphine monooxide product. S P E C I F I C A T I O N
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Patent Agency Ranking
公开(公告)号：CA1186342A
公开(公告)日：1985-04-30
申请号：CA397823
申请日：1982-03-08
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BRYANT DAVID R
IPC: C07C43/18 , C07C29/17 , C07C31/10 , C07C41/00 , C07C41/34 , C07C41/36 , C07C41/44 , C07C43/00 , C07C43/15 , C07C43/188 , C07C45/53 , C07C45/62 , C07C67/00
Abstract: PROCESS FOR REMOVING HYDROPEROXIDES AND ALDEHYDES FROM ALLYL-ALKYL ETHER Described herein is a process for the conversion of hydroperoxides, present in allyl-alkyl ethers to products including .alpha.,.beta.-unsaturated aldehydes and for reducing such .alpha.,.beta.-unsaturated aldehydes to alcohols prior to the use of the ether as a feedstock in a hydroformylation reaction to produce the corresponding ether aldehyde. The process involves contacting the ether with a metal hydride, either in aqueous solution and/or by means of an ion exchange resin. Such treatment decomposes the hydroperoxides and then reduces their .alpha.,.beta.unsaturated aldehyde decomposition products, thereby reducing the catalyst inhibition period present in the hydroformylation reaction which is observed when such .alpha.,.beta.-unsaturated aldehyde impurities are present. S P E C I F I C A T I O N _ _ _ _ _ _ _ _ _ _ _ _ _
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公开(公告)号：CS109185A2
公开(公告)日：1990-02-12
申请号：CS109185
申请日：1985-02-15
Applicant: UNION CARBIDE CORP
Inventor： BILLIG ERNST , ABATJOGLOU ANTHONY G , BRYANT DAVID R , MURRAY REX E , MAHER JOHN M
IPC: C07C47/02 , B01J27/18 , B01J31/18 , B01J31/20 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F9/06 , C07F9/547 , C07F9/6564 , C07F9/6574 , C07F9/6578 , C07F15/00
Abstract: Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.
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公开(公告)号：CA1183123A
公开(公告)日：1985-02-26
申请号：CA407975
申请日：1982-07-23
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BRYANT DAVID R
IPC: B01J31/00 , B01J31/24 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , B01J27/18 , B01J23/46 , C07C45/49
Abstract: A rhodium catalyzed hydrotormylation process carried out in the presence of free triarylphosphine ligand and free organic tertiary bisphosphine monooxide ligand, and catalytic precursor solutions for said process.
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公开(公告)号：CS8705276A2
公开(公告)日：1990-02-12
申请号：CS527687
申请日：1987-07-10
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BRYANT DAVID R
CPC classification number: C07C45/50 , C07F9/5004 , Y02P20/582 , C07C47/02
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公开(公告)号：CA1183122A
公开(公告)日：1985-02-26
申请号：CA407964
申请日：1982-07-23
Applicant: UNION CARBIDE CORP
Inventor： ABATJOGLOU ANTHONY G , BILLIG ERNST
Abstract: A hydroformylation process for producing aldehydes using a bisphosphine monooxide ligand and catalytic precursor solutions for said process.
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