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公开(公告)号:US3887601A
公开(公告)日:1975-06-03
申请号:US38286373
申请日:1973-07-26
Applicant: UNION CARBIDE CORP
Inventor: KANNER BERNARD , PROKAI BELA , ROSEMUND WALTER R
CPC classification number: C08J9/0061 , C07F7/12 , C08G77/46 , C08J2375/06 , C08J2483/00
Abstract: Organosilicone polymers are provided containing siliconcontaining units A, B and C, where A is SiO4/2, B is a monofunctional siloxy unit in which silicon is bonded to at least one organic moiety bearing an organic-capped poly(oxyalkylene) chain, and C is a monofunctional trihydrocarbylsiloxy unit, and in which there are from about 0.75 to about 2 moles of A, and from about 0.1 to about 1 mole of C, per mole of B. The polymers are useful as surfactants and find particular application in the manufacture of flexible polyester urethane cellular products, including flame-retarded foams.
Abstract translation: 提供了含有含硅单元A,B和C的有机硅聚合物,其中A是SiO 4/2,B是单官能甲硅烷氧基单元,其中硅键合至至少一个有机封端的聚(氧化烯)链的有机部分, 并且C是单官能三烃基甲硅烷氧基单元,其中每摩尔B具有约0.75至约2摩尔的A和约0.1至约1摩尔的C。该聚合物可用作表面活性剂,并且特别适用于 制造柔性聚酯氨酯泡沫产品,包括阻燃泡沫。
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公开(公告)号:CA1032693A
公开(公告)日:1978-06-06
申请号:CA180420
申请日:1973-09-06
Applicant: UNION CARBIDE CORP
Inventor: KANNER BERNARD , PROKAI BELA , ROSEMUND WALTER R
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公开(公告)号:CA1040788A
公开(公告)日:1978-10-17
申请号:CA197574
申请日:1974-04-16
Applicant: UNION CARBIDE CORP
Inventor: ROSEMUND WALTER R , SANDNER MICHAEL R , TRECKER DAVID J
Abstract: BETA-AMINO NITRILE CATALYSTS FOR POLYURETHANE PREPARATION Cellular urethane polymers essentially free of the strong, objectionable amine odor characteristic of N-ethylmorpholine, are provided by effecting the polyurethane forming reaction in the presence of beta-tert-amino nitriles. In view of their low residual odor and effectiveness in the catalysis of the water-isocyanate reaction, the beta-amino nitriles either alone or in combination with other tertiary amines, are used with particular advantage as direct replacements for N-ethyl-morpholine in the manufacture of water-blown flexible polyurethanes, both molded and free-rise, including highresilience foam as well as foams stabilized with either organosilicone or silicon-free organic surfactants. Especially effective for the formation of flexible polyester foam stabilized with either type of surfactant are blends of the beta-amino nitrile catalyst such as, in particular, 3-(N,N-dimethylamino)propionitrile, with dimethylethanolamine or a bis¢2-(N,N-dimethylamino)alkyl!-ether. S P E C I F I C A T I O N
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公开(公告)号:CA1043682A
公开(公告)日:1978-12-05
申请号:CA225981
申请日:1975-04-29
Applicant: UNION CARBIDE CORP
Inventor: ROSEMUND WALTER R , ROSE CHARLES V
Abstract: POLYURETHANE FOAM COMPOSITION AND METHOD OF MAKING SAME One-shot, flexible polyurethane foams capable of being thermally bonded to various substrates are produced by adding low molecular weight alkylene glycols, glycol ethers, triols, alkanolamine, or polyhydric phenols as modifiers to conventional polyisocyanate foaming mixtures. S P E C I F I C A T I O N
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