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公开(公告)号:WO2007078277A3
公开(公告)日:2007-11-22
申请号:PCT/US2005047012
申请日:2005-12-23
Applicant: UNITED TECHNOLOGIES CORP , GUMMALLA MALLIKA , VANDERSPURT THOMAS HENRY , SHE YING , DARDAS ZISSIS , OLSOMMER BENOIT
Inventor: GUMMALLA MALLIKA , VANDERSPURT THOMAS HENRY , SHE YING , DARDAS ZISSIS , OLSOMMER BENOIT
IPC: B01J8/04
CPC classification number: H01M8/0668 , C01B3/12 , C01B3/38 , C01B3/48 , C01B2203/0288 , C01B2203/041 , C01B2203/066 , H01M2008/1095
Abstract: The fuel processing system of the present invention supplies a flow of H2-r?ch reformate to a water gas shift membrane reactor, comprising a water gas shift reaction region and a permeate region, separated by an H2-separat?on membrane H2 formed over a catalyst in the reaction region selectively passes through the H2-separat?on membrane to the permeate region for delivery to a use point (such as the fuel cell of a fuel cell power plant) A sweep gas, preferably steam, removes the H2 from the permeate region The direction of sweep gas flow relative to the reformate flow is controlled for H2-separat?on performance and is used to determine the loading of the catalyst in the reaction region Coolant, thermal and/or pressure control subsystems of the fuel cell power plant may be integrated with the fuel processing system
Abstract translation: 本发明的燃料处理系统将H2-r→ch重整产物流向水煤气变换膜反应器提供,包括水气转换反应区和渗透区,由形成在其上的H 2分离膜H2分离 反应区域中的催化剂选择性地通过膜上的H 2分离膜到达渗透区域以输送到使用点(例如燃料电池发电厂的燃料电池)。吹扫气体,优选蒸汽,将H 2从 渗透区域相对于重整油流动的吹扫气体流动方向被控制用于H 2分离性能,并且用于确定催化剂在反应区域中的负载燃料电池的冷却剂,热和/或压力控制子系统 发电厂可以与燃料处理系统集成
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公开(公告)号:AT423605T
公开(公告)日:2009-03-15
申请号:AT05251812
申请日:2005-03-23
Applicant: UNITED TECHNOLOGIES CORP
Inventor: BURLATSKY SERGEI F , GUMMALLA MALLIKA , SPADACCINI LOUIS J , LAMM FOSTER PHILIP
IPC: B01D19/00 , F23K5/08 , B01D61/00 , B01D63/08 , B64D37/34 , C10G31/09 , C10G31/11 , C10L1/04 , F02C7/22 , F02C7/224
Abstract: A fuel system for an energy conversion device includes a deoxygenator system (14) with a porous membrane. The deoxygenator includes an oxygen receiving channel (40) separated from the fuel channel (38) by the porous membrane (36). The capillary forces counteract the pressure differential across the membrane, preventing any leakage of the fuel, while the oxygen concentration differential across the membrane allows for deoxygenation of the fuel through the porous membrane.
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公开(公告)号:DE602005012881D1
公开(公告)日:2009-04-09
申请号:DE602005012881
申请日:2005-03-23
Applicant: UNITED TECHNOLOGIES CORP
Inventor: BURLATSKY SERGEI F , GUMMALLA MALLIKA , SPADACCINI LOUIS J , LAMM FOSTER PHILIP
IPC: B01D19/00 , F23K5/08 , B01D61/00 , B01D63/08 , B64D37/34 , C10G31/09 , C10G31/11 , C10L1/04 , F02C7/22 , F02C7/224
Abstract: A fuel system for an energy conversion device includes a deoxygenator system (14) with a porous membrane. The deoxygenator includes an oxygen receiving channel (40) separated from the fuel channel (38) by the porous membrane (36). The capillary forces counteract the pressure differential across the membrane, preventing any leakage of the fuel, while the oxygen concentration differential across the membrane allows for deoxygenation of the fuel through the porous membrane.
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公开(公告)号:CA2568552A1
公开(公告)日:2007-07-18
申请号:CA2568552
申请日:2006-11-20
Applicant: UNITED TECHNOLOGIES CORP
Inventor: CHIAPETTA LOUIS , SPADACCINI LOUIS J , GUMMALLA MALLIKA , CHOI DOCHUL , HUANG HE
Abstract: A fuel system for an energy conversion device includes a deoxygenator system with a multitude of flow impingement elements which are interleaved t o provide a fuel channel with intricate two-dimensional flow characteristics. The flow impingement elements break up the boundary layers and enhance the transport of oxygen from the core of the of the fuel flow within the fuel channel to the oxygen permeable membrane surfaces by directing the fuel flow in a direction normal to the oxygen permeable membrane. The rapid mixing of the relatively rich oxygen co re of the fuel with the relatively oxygen-poor flow near the oxygen permeable membrane enhances the overall removal rate of oxygen from the fuel. Because this process can be accomplished in fuel channels of relatively larger flow areas while maintaining laminar flow, the pressure drop sustained is relatively low.
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公开(公告)号:CA2862291C
公开(公告)日:2017-09-05
申请号:CA2862291
申请日:2012-01-20
Applicant: UNITED TECHNOLOGIES CORP
Inventor: PROTSAILO LESIA V , STOLAR LAURA ROEN , MARZULLO JESSE M , GUMMALLA MALLIKA , BURLATSKY SERGEI F
IPC: H01M8/1004 , H01M4/92 , H01M4/96
Abstract: An example of a stable electrode structure is to use a gradient electrode that employs large platinum particle catalyst in the close proximity to the membrane supported on conventional carbon and small platinum particles in the section of the electrode closer to a GDL supported on a stabilized carbon. Some electrode parameters that contribute to electrode performance stability and reduced change in ECA are platinum-to-carbon ratio, size of platinum particles in various parts of the electrode, use of other stable catalysts instead of large particle size platinum (alloy, etc), depth of each gradient sublayer. Another example of a stable electrode structure is to use a mixture of platinum particle sizes on a carbon support, such as using platinum particles that may be 6 nanometers and 3 nanometers. A conductive support is typically one or more of the carbon blacks.
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公开(公告)号:CA2862291A1
公开(公告)日:2013-07-25
申请号:CA2862291
申请日:2012-01-20
Applicant: UNITED TECHNOLOGIES CORP
Inventor: PROTSAILO LESIA V , STOLAR LAURA ROEN , MARZULLO JESSE M , GUMMALLA MALLIKA , BURLATSKY SERGEI F
Abstract: An example of a stable electrode structure is to use a gradient electrode that employs large platinum particle catalyst in the close proximity to the membrane supported on conventional carbon and small platinum particles in the section of the electrode closer to a GDL supported on a stabilized carbon. Some electrode parameters that contribute to electrode performance stability and reduced change in ECA are platinum-to-carbon ratio, size of platinum particles in various parts of the electrode, use of other stable catalysts instead of large particle size platinum (alloy, etc), depth of each gradient sublayer. Another example of a stable electrode structure is to use a mixture of platinum particle sizes on a carbon support, such as using platinum particles that may be 6 nanometers and 3 nanometers. A conductive support is typically one or more of the carbon blacks.
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公开(公告)号:CA2496929A1
公开(公告)日:2005-09-24
申请号:CA2496929
申请日:2005-02-11
Applicant: UNITED TECHNOLOGIES CORP
Inventor: BURLATSKY SERGEI F , LAMM FOSTER PHILIP , GUMMALLA MALLIKA , SPADACCINI LOUIS J
IPC: F23K5/08 , B01D19/00 , B01D61/00 , B01D63/08 , B64D37/34 , C10G31/09 , C10G31/11 , C10L1/04 , F02C7/22 , F02C7/224 , B01D53/22 , F02M33/00
Abstract: A fuel system for an energy conversion device includes a deoxygenator syst em with a porous membrane. The deoxygenator includes an oxygen receiving channe l separated from the fuel channel by the porous membrane. The capillary forces counteract the pressure differential across the membrane, preventing any leakage of the fuel, while the oxygen concentration differential across the membrane allows for deoxygenation of the fuel through the porous membrane.
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