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1.发明申请公开(公告)号：US20200223710A1
公开(公告)日：2020-07-16
申请号：US16083801
申请日：2017-08-24
Inventor： Changzheng Wu , Bo Yang , Yi Xie
Abstract: The present disclosure provides a photochromic nanomaterial capable of blocking ultraviolet rays with a general formula of MaObXc, a production method and use thereof, wherein the M, O and X and a, b and c are as defined herein. The nanomaterial may be prepared by the following method: heating a mixture of an M-containing cation source compound, a polyol, a surfactant and first solvent under agitation, to obtain a hot first solution; mixing an X-containing anion source compound and a second solvent, to obtain a second solution; injecting the second solution into the hot first solution, to perform a reaction and obtain a reaction mixture; and subjecting the reaction mixture to post-treatment. The nanomaterial of the present disclosure can block 80% or more of UV rays, in particular, may change to a transparent dark color and reduce the transmittance under irradiation by strong light, whereas may restore colorless transparent state under irradiation by weak or non-strong light. Additionally, the present disclosure may have following features: a simple processing flow, low cost, high productivity, applicability in the industrial production, etc.
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2.发明授权公开(公告)号：US11008220B2
公开(公告)日：2021-05-18
申请号：US16083801
申请日：2017-08-24
Inventor： Changzheng Wu , Bo Yang , Yi Xie
Abstract: The present disclosure provides a photochromic nanomaterial capable of blocking ultraviolet rays with a general formula of MaObXc, a production method and use thereof, wherein the M, O and X and a, b and c are as defined herein. The nanomaterial may be prepared by the following method: heating a mixture of an M-containing cation source compound, a polyol, a surfactant and first solvent under agitation, to obtain a hot first solution; mixing an X-containing anion source compound and a second solvent, to obtain a second solution; injecting the second solution into the hot first solution, to perform a reaction and obtain a reaction mixture; and subjecting the reaction mixture to post-treatment. The nanomaterial of the present disclosure can block 80% or more of UV rays, in particular, may change to a transparent dark color and reduce the transmittance under irradiation by strong light, whereas may restore colorless transparent state under irradiation by weak or non-strong light. Additionally, the present disclosure may have following features: a simple processing flow, low cost, high productivity, applicability in the industrial production, etc.
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