公开(公告)号：US11953821B2

公开(公告)日：2024-04-09

申请号：US17688250

申请日：2022-03-07

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Kamil Mielczarek ,  Vivek V. Dhas

IPC: G03C8/36 ,  B05D1/38 ,  B05D3/10 ,  C01D3/12 ,  C01G21/16 ,  C07C19/00 ,  C09D11/52 ,  H01G9/20 ,  H10K30/00 ,  H10K30/15 ,  H10K71/12 ,  C07C233/03 ,  C07C317/04 ,  G03C1/035 ,  H10K71/15 ,  H10K71/40 ,  H10K102/10

CPC classification number: G03C8/365 ,  B05D1/38 ,  B05D3/107 ,  C01D3/12 ,  C01G21/16 ,  C07C19/00 ,  C09D11/52 ,  H01G9/2059 ,  H10K30/151 ,  H10K30/451 ,  H10K71/12 ,  C07C233/03 ,  C07C317/04 ,  G03C2001/03558 ,  H01G9/2009 ,  H01G9/2031 ,  H10K71/15 ,  H10K71/40 ,  H10K2102/102

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.

公开(公告)号：US20240008295A1

公开(公告)日：2024-01-04

申请号：US18469253

申请日：2023-09-18

Applicant: CubicPV Inc.

Inventor： Michael D. Irwin ,  Jerred A. Chute ,  Vivek V. Dhas

IPC: H10K30/00 ,  H03K17/22 ,  H10K71/40 ,  H03K5/19 ,  H03K5/24 ,  H10K85/30 ,  H10K71/12 ,  B05D3/10 ,  H10K30/15 ,  B05D1/38 ,  H01G9/20 ,  H01L31/0304

CPC classification number: H10K30/451 ,  H03K17/223 ,  H10K71/40 ,  H03K5/19 ,  H03K5/2472 ,  H10K85/30 ,  H10K71/12 ,  B05D3/107 ,  H10K30/151 ,  B05D1/38 ,  H10K30/15 ,  H01G9/2045 ,  H01L31/0304 ,  Y02E10/542 ,  H01L2031/0344

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of preparing a lead and tin halide precursor ink. Preparing a lead and tin halide precursor ink comprises the steps of introducing a lead halide and a tin halide into a vessel; introducing a first solvent to the vessel; and contacting the lead halide and the halide with the first solvent to dissolve the lead halide and the tin halide to form the lead and tin halide precursor ink; depositing the lead and tin halide precursor ink onto a substrate; drying the lead and tin halide precursor ink to form a thin film; annealing the thin film; and rinsing the thin film with a solvent comprising: a second solvent; a first salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide; and a second salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide.

公开(公告)号：US11800726B1

公开(公告)日：2023-10-24

申请号：US17970465

申请日：2022-10-20

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Jerred A. Chute ,  Vivek V. Dhas

IPC: B05D1/38 ,  H10K30/00 ,  H01G9/20 ,  B05D3/10 ,  H01L31/0304 ,  H03K5/19 ,  H03K5/24 ,  H03K17/22 ,  H10K30/15 ,  H10K71/12 ,  H10K71/40 ,  H10K85/30 ,  H01L31/0256

CPC classification number: H10K30/451 ,  B05D1/38 ,  B05D3/107 ,  H01G9/2045 ,  H01L31/0304 ,  H03K5/19 ,  H03K5/2472 ,  H03K17/223 ,  H10K30/15 ,  H10K30/151 ,  H10K71/12 ,  H10K71/40 ,  H10K85/30 ,  H01L2031/0344 ,  Y02E10/542 ,  Y02E10/549

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of preparing a bismuth halide precursor ink. Preparing a bismuth halide precursor ink comprises the steps of introducing a bismuth halide into a vessel; introducing a first solvent to the vessel; and contacting the bismuth halide with the first solvent to dissolve the bismuth halide to form the bismuth halide precursor ink; depositing the bismuth halide precursor ink onto a substrate; drying the bismuth halide precursor ink to form a thin film; annealing the thin film; and rinsing the thin film with a solvent comprising: a second solvent; a first salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide; and a second salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide.

公开(公告)号：US20220033658A1

公开(公告)日：2022-02-03

申请号：US17506194

申请日：2021-10-20

Applicant: CubicPV Inc.

Inventor： Michael D. Irwin ,  Jerred A. Chute ,  Vivek V. Dhas ,  Kamil Mielczarek

IPC: C09D1/00 ,  H01L51/42 ,  C09D7/63 ,  H01L31/032 ,  H01G9/20 ,  C09D11/02 ,  H01L51/00 ,  H01L51/44 ,  H01G9/00 ,  C09D7/20 ,  C09D11/36

Abstract: Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes. The active layer may have perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.

公开(公告)号：US12302681B2

公开(公告)日：2025-05-13

申请号：US18469253

申请日：2023-09-18

Applicant: CubicPV Inc.

Inventor： Michael D. Irwin ,  Jerred A. Chute ,  Vivek V. Dhas

IPC: B05D1/38 ,  B05D3/10 ,  H01G9/20 ,  H01L31/0304 ,  H03K5/19 ,  H03K5/24 ,  H03K17/22 ,  H10K30/00 ,  H10K30/15 ,  H10K71/12 ,  H10K71/40 ,  H10K85/30 ,  H01L31/0256

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of preparing a lead and tin halide precursor ink. Preparing a lead and tin halide precursor ink comprises the steps of introducing a lead halide and a tin halide into a vessel; introducing a first solvent to the vessel; and contacting the lead halide and the halide with the first solvent to dissolve the lead halide and the tin halide to form the lead and tin halide precursor ink; depositing the lead and tin halide precursor ink onto a substrate; drying the lead and tin halide precursor ink to form a thin film; annealing the thin film; and rinsing the thin film with a solvent comprising: a second solvent; a first salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide; and a second salt selected from the group consisting of methylammonium halide, formamidinimum halide, guanidinium halide, 1,2,2-triaminovinylammonium halide, and 5-aminovaleric acid hydrohalide.

公开(公告)号：US12089485B2

公开(公告)日：2024-09-10

申请号：US17325597

申请日：2021-05-20

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Vivek V. Dhas

IPC: H01G9/20 ,  H01L31/053 ,  H01L31/18 ,  H10K30/00 ,  H10K30/15 ,  H10K30/30 ,  H10K30/35 ,  H10K30/88 ,  H10K85/30 ,  H01L31/0256 ,  H10K85/60

CPC classification number: H10K85/30 ,  H01G9/2009 ,  H01G9/2027 ,  H01G9/2031 ,  H01G9/2045 ,  H01G9/2059 ,  H01L31/053 ,  H01L31/18 ,  H10K30/00 ,  H10K30/15 ,  H10K30/151 ,  H10K30/30 ,  H10K30/352 ,  H10K30/88 ,  H01L2031/0344 ,  H10K85/633 ,  H10K85/636 ,  Y02E10/542 ,  Y02E10/549

Abstract: Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes, the active layer having perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.

公开(公告)号：US20240118602A1

公开(公告)日：2024-04-11

申请号：US18391079

申请日：2023-12-20

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Kamil Mielczarek ,  Vivek V. Dhas

IPC: G03C8/36 ,  B05D1/38 ,  B05D3/10 ,  C01D3/12 ,  C01G21/16 ,  C07C19/00 ,  C09D11/52 ,  H01G9/20 ,  H10K30/00 ,  H10K30/15 ,  H10K71/12

CPC classification number: G03C8/365 ,  B05D1/38 ,  B05D3/107 ,  C01D3/12 ,  C01G21/16 ,  C07C19/00 ,  C09D11/52 ,  H01G9/2059 ,  H10K30/151 ,  H10K30/451 ,  H10K71/12 ,  C07C233/03

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.

公开(公告)号：US20230167326A1

公开(公告)日：2023-06-01

申请号：US18070267

申请日：2022-11-28

Applicant: CubicPV Inc.

Inventor： Michael D. Irwin ,  Minh Tu Nguyen ,  Vivek V. Dhas ,  Erin Senehira ,  Marissa Mitchell

IPC: C09D11/52 ,  C01G21/16 ,  C09D11/033

CPC classification number: C09D11/52 ,  C01G21/16 ,  C09D11/033 ,  H01L51/4213

Abstract: A method including depositing a lead halide precursor ink onto a substrate; drying the lead halide precursor ink to form a first thin film; annealing the first thin film; and forming a perovskite material layer, wherein forming the perovskite material layer includes: depositing a benzylammonium halide precursor ink onto the first thin film; drying the benzylammonium halide precursor ink; depositing a formamidinium halide precursor ink onto the benzylammonium halide precursor ink; drying the formamidinium halide precursor ink to form a second thin film; and annealing the second thin film.

公开(公告)号：US11508924B2

公开(公告)日：2022-11-22

申请号：US16939907

申请日：2020-07-27

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Jerred A. Chute ,  Vivek V. Dhas

IPC: H01L51/42 ,  H01G9/20 ,  B05D1/38 ,  B05D3/10 ,  H01L31/0304 ,  H01L51/00 ,  H03K5/19 ,  H03K5/24 ,  H03K17/22 ,  H01L31/0256

Abstract: A method for preparing photoactive perovskite materials. The method comprises the step of preparing a germanium halide precursor ink. Preparing a germanium halide precursor ink comprises the steps of: introducing a germanium halide into a vessel, introducing a first solvent to the vessel, and contacting the germanium halide with the first solvent to dissolve the germanium halide. The method further comprises depositing the germanium halide precursor ink onto a substrate, drying the germanium halide precursor ink to form a thin film, annealing the thin film, and rinsing the thin film with a second solvent and a salt.

公开(公告)号：US11300870B2

公开(公告)日：2022-04-12

申请号：US16859545

申请日：2020-04-27

Applicant: CUBICPV INC.

Inventor： Michael D. Irwin ,  Kamil Mielczarek ,  Vivek V. Dhas

IPC: B05D1/38 ,  G03C8/36 ,  H01L51/00 ,  C01G21/16 ,  C01D3/12 ,  C07C19/00 ,  B05D3/10 ,  H01L51/42 ,  C09D11/52 ,  H01G9/20 ,  C07C233/03 ,  C07C317/04 ,  G03C1/035

Abstract: A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.