公开(公告)号：US4533756A

公开(公告)日：1985-08-06

申请号：US548909

申请日：1983-11-07

Applicant: Jiang-Jen Lin ,  Walter H. Brader, Jr.

Inventor： Jiang-Jen Lin ,  Walter H. Brader, Jr.

IPC: C07C45/49 ,  C07C51/377 ,  C07C45/50

CPC classification number: C07C45/49 ,  C07C51/377

Abstract: A process is disclosed for the preparation of acrylic acid precursors by a hydroformylation process which comprises reacting a vinyl ether with carbon monoxide and hydrogen in the presence of a catalyst comprising a rhodium carbonyl compound and a phosphine ligand at a mild temperature and pressure until there is substantial formation of the intermediate 2- and 3-ethoxypropanals, followed by oxidation of said aldehydes and pyrolysis to said acrylic acid.

Abstract translation: 公开了通过加氢甲酰化方法制备丙烯酸前体的方法，该方法包括在温和的温度和压力下，在包含羰基铑化合物和膦配体的催化剂的存在下使乙烯基醚与一氧化碳和氢气反应直至存在 大量形成中间体2-和3-乙氧基丙醛，随后氧化所述醛并热解成所述丙烯酸。

公开(公告)号：US4519956A

公开(公告)日：1985-05-28

申请号：US515748

申请日：1983-07-21

Applicant: Jiang-Jen Lin ,  Roger G. Duranleau

Inventor： Jiang-Jen Lin ,  Roger G. Duranleau

IPC: C07C51/56 ,  C07C51/12

CPC classification number: C07C51/56

Abstract: A process for producing acetic anhydride is disclosed which comprises reacting methyl acetate with carbon monoxide at an elevated temperature and pressure in the presence of an iodine-free catalyst system wherein the catalyst consists of ruthenium compound, quaternary phosphonium salt and cobalt-compound. A further embodiment comprises recycling product acetic anhydride with methanol to produce acetic acid.

Abstract translation: 公开了一种生产乙酸酐的方法，其包括在无碘催化剂体系的存在下，在升高的温度和压力下使乙酸甲酯与一氧化碳反应，其中催化剂由钌化合物，季鏻盐和钴化合物组成。 另一个实施方案包括将乙酸酐与甲醇一起再生产生乙酸。

公开(公告)号：US4434248A

公开(公告)日：1984-02-28

申请号：US426317

申请日：1982-09-29

Applicant: Jiang-Jen Lin

Inventor： Jiang-Jen Lin

IPC: C07C29/157 ,  C07C29/15 ,  C07C27/06

CPC classification number: C07C29/157

Abstract: This invention concerns a process of making alkanols which comprises reacting a mixture of CO and H.sub.2 at a pressure of about 500 psig or greater and at a temperature of at least 150.degree. C. in the presence of a catalyst system comprising a ruthenium-containing compound, a nickel or iron containing compound and a quaternary phosphonium salt, in the presence of an inert, oxygenated solvent.

Abstract translation: 本发明涉及制备链烷醇的方法，其包括在约500psig或更高的压力和至少150℃的温度下，在包含含钌化合物的催化剂体系存在下使CO和H 2的混合物反应 ，含镍或铁的化合物和季鏻盐，在惰性的含氧溶剂的存在下。

公开(公告)号：US4433178A

公开(公告)日：1984-02-21

申请号：US344430

申请日：1982-02-01

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/32 ,  C07C45/49 ,  C07C47/06

CPC classification number: C07C29/32 ,  C07C45/49

Abstract: Acetaldehyde is prepared in good yield from methanol and synthesis gas by contacting the mixture of methanol, carbon monoxide and hydrogen with an iodide or iodine-free catalyst composition comprising ruthenium powder, a cobalt-containing compound and an onium salt or base, and heating the resulting mixture to an elevated temperature and pressure for sufficient time to produce the acetaldehyde, and then recovering the same from the reaction mixture.

Abstract translation: 通过使甲醇，一氧化碳和氢气的混合物与含有钌粉末，含钴化合物和鎓盐或碱的碘化物或无碘催化剂组合物接触，从甲醇和合成气制备乙醛，并加热 得到的混合物升高温度和压力足以产生乙醛，然后从反应混合物中回收。

公开(公告)号：US4433177A

公开(公告)日：1984-02-21

申请号：US344260

申请日：1982-02-01

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/32 ,  C07C45/49 ,  C07C47/06

CPC classification number: C07C29/32 ,  C07C45/49

Abstract: Acetaldehyde is prepared from methanol and synthesis gas with good selectivity and yield by contacting a mixture of methanol, carbon monoxide and hydrogen with an iodide or iodine free catalyst composition comprising (1) ruthenium powder, (2) a cobalt-containing compound, (3) an amine, and (4) an onium salt or base, and heating the resulting mixture to an elevated temperature and pressure for sufficient time to produce the desired acetaldehyde, and recovering the same from the reaction mixture.

Abstract translation: 通过使甲醇，一氧化碳和氢气的混合物与碘化物或碘游离催化剂组合物接触，由甲醇和合成气以良好的选择性和产率制备乙醛，其包含（1）钌粉末，（2）含钴化合物，（3 ）胺，和（4）鎓盐或碱，并将所得混合物加热至高温和高压足够的时间以产生所需的乙醛，并从反应混合物中回收。

公开(公告)号：US4424384A

公开(公告)日：1984-01-03

申请号：US378531

申请日：1982-05-17

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/32 ,  C07C29/00 ,  C07C31/08

CPC classification number: C07C29/32

Abstract: Ethanol is prepared by contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising an iodide-free ruthenium-containing compound, an iodide-free quaternary phosphonium or ammonium base or salt and a halide-free cobalt-containing compound, such as cobalt(III) acetylacetone or dicobalt octacarbonyl, in the presence of a substantially inert solvent.

Abstract translation: 通过使甲醇，氢气和一氧化碳与包含不含碘化物的含钌化合物，不含碘化物的季鏻或铵碱或盐和不含卤化物的钴化合物（例如钴）的催化剂体系 III）乙酰丙酮或八羰基二钴，在基本惰性的溶剂存在下进行。

公开(公告)号：US4414410A

公开(公告)日：1983-11-08

申请号：US339232

申请日：1982-01-13

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C67/36 ,  C07C69/003 ,  C07C69/14

CPC classification number: C07C67/293

Abstract: Alkyl esters, such as ethyl acetate, are prepared by contacting the corresponding next lower carbon number alkyl ester, such as methyl acetate, with carbon monoxide and hydrogen in the presence of an iodine or iodide-free catalyst composition comprising a ruthenium-containing compound, a cobalt containing compound and a quaternary phosphonium salt or base, and heating the mixture to an elevated temperature and pressure for sufficient time to produce the desired higher alkyl ester, and then recovering the same from the reaction mixture.

Abstract translation: 烷基酯，例如乙酸乙酯，是通过使相应的下一个较低碳数的烷基酯如乙酸甲酯与一氧化碳和氢气在含有含钌化合物的碘或无碘化物催化剂组合物存在下接触来制备的， 含钴化合物和季鏻盐或碱，并将混合物加热至高温和高压足够的时间以产生所需的高级烷基酯，然后从反应混合物中回收。

公开(公告)号：US20130165562A1

公开(公告)日：2013-06-27

申请号：US13561054

申请日：2012-07-29

Applicant: Jiang-Jen Lin ,  Ting-Kai Huang

Inventor： Jiang-Jen Lin ,  Ting-Kai Huang

IPC: C09K21/12 ,  C08L21/00 ,  C08L75/04 ,  C08K3/34 ,  C08K5/5399

CPC classification number: C08L75/04 ,  C08K5/5399 ,  C08K9/04 ,  C09K21/12 ,  C08L21/00 ,  C08K3/346

Abstract: A phosphorous flame retardant containing clay is made in two steps. First, chlorines of hexachlorocyclotriphosphazene (HCP) are substituted with poly(oxyalkylene)-amines in the replacement reaction. Layered or exfoliated clay are then added to perform the intercalation, exfoliation or adsorption reaction to produce the phosphorous flame retardant. The phosphorous flame retardant can be further mixed with a polymer to promote the flame-retarding effect of the polymer.

Abstract translation: 含有粘土的磷阻燃剂分两步制成。 首先，在替代反应中六氯环三磷腈（HCP）的氯被聚（氧化烯） - 胺取代。 然后加入层状或剥离的粘土进行插层，剥离或吸附反应以产生磷阻燃剂。 可以将磷阻燃剂与聚合物进一步混合以促进聚合物的阻燃效果。

公开(公告)号：US08455594B2

公开(公告)日：2013-06-04

申请号：US13567936

申请日：2012-08-06

Applicant: Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

Inventor： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

IPC: C08F230/02 ,  C08G8/28 ,  C08L61/00 ,  C08L63/00 ,  C08L79/02

CPC classification number: C09K21/12 ,  C07F9/067 ,  C08K5/5399 ,  C08L63/00

Abstract: A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

Abstract translation: 磷阻燃剂主要包括具有聚（氧化烯）胺替代物的六氯三磷腈（HCP）。 聚（氧化烯）胺包括至少两个端基。 磷阻燃剂还可以包括层状硅酸盐粘土。 层状硅酸盐粘土可以用HCP的聚（氧化烯）胺替代物插层和改性，以有效地促进热稳定性。 阻燃剂，磷腈 - 聚（氧化烯）胺加合物可以应用于聚合物。 通过它们之间的交联，可以提高聚合物的阻燃性能。 还提供了制备磷腈 - 聚（氧化烯）胺加合物的阻燃剂的方法及其在聚合物中的应用。

公开(公告)号：US08362092B2

公开(公告)日：2013-01-29

申请号：US12765853

申请日：2010-04-22

Applicant: Jiang-Jen Lin ,  Wei-Ting Chen ,  Yen-Chi Hsu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Wei-Ting Chen ,  Yen-Chi Hsu ,  Chih-Wei Chiu

IPC: B01F17/00 ,  B01F17/42 ,  C04B14/10 ,  C07F7/02 ,  C09D17/00 ,  B01F17/16 ,  B01F17/02 ,  H01L31/04

CPC classification number: C08K13/02 ,  B01F17/0007 ,  B01F17/0021 ,  B01F17/0042 ,  B01F17/0085

Abstract: The present invention provides an organic/inorganic compositive dispersant and a method for producing the same. The compositive dispersant comprises a complex of inorganic clay and an organic surfactant. The compositive dispersant is produced by reacting inorganic clay with the organic surfactant in a solvent to generate a complex. The inorganic clay is layered or platelet. The organic surfactant is an anionic surfactant such as alkyl sulfates, a nonionic surfactant such as octylphenol polyethoxylate and polyoxyethylene alkyl ether, or a cationic surfactant such as fatty (C12˜C32) quaternary ammonium salts and fatty (C12˜C32) quaternary ammonium chlorides.

Abstract translation: 本发明提供一种有机/无机复合分散剂及其制造方法。 复合分散剂包括无机粘土和有机表面活性剂的复合物。 复合分散剂通过无机粘土与有机表面活性剂在溶剂中反应生成复合物。 无机粘土是分层的或血小板的。 有机表面活性剂是阴离子表面活性剂，如烷基硫酸盐，非离子表面活性剂如辛基苯酚聚乙氧基化物和聚氧乙烯烷基醚，或阳离子表面活性剂如脂肪（C12〜C32）季铵盐和脂肪（C12〜C32）季铵氯化物。