公开(公告)号：US4451679A

公开(公告)日：1984-05-29

申请号：US435812

申请日：1982-10-21

Applicant: John F. Knifton ,  Jiang-Jen Lin ,  Robert A. Grigsby, Jr. ,  Walter H. Brader, Jr.

Inventor： John F. Knifton ,  Jiang-Jen Lin ,  Robert A. Grigsby, Jr. ,  Walter H. Brader, Jr.

IPC: C07C27/20 ,  B01J31/00 ,  B01J31/28 ,  C07B61/00 ,  C07C27/00 ,  C07C27/22 ,  C07C29/157 ,  C07C29/16 ,  C07C31/125 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00

CPC classification number: B01J31/0268 ,  B01J31/0239 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/04 ,  B01J31/20 ,  B01J31/2208 ,  B01J31/28 ,  B01J31/30 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/0211 ,  B01J2531/821 ,  B01J31/2234

Abstract: This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50.degree. C. for a sufficient time to produce said alcohols and aldehydes.

Abstract translation: 本发明涉及一种制备醇和醛的方法，其包括以下步骤：使末端和/或内部烯烃和合成气的混合物与包含分散在低熔点季铵或铵碱或盐中的含钌化合物的催化剂体系相接触 并在100psi或更大的压力下在至少50℃的温度下加热所得的反应混合物足够的时间以产生所述的醇和醛。

公开(公告)号：US4533756A

公开(公告)日：1985-08-06

申请号：US548909

申请日：1983-11-07

Applicant: Jiang-Jen Lin ,  Walter H. Brader, Jr.

Inventor： Jiang-Jen Lin ,  Walter H. Brader, Jr.

IPC: C07C45/49 ,  C07C51/377 ,  C07C45/50

CPC classification number: C07C45/49 ,  C07C51/377

Abstract: A process is disclosed for the preparation of acrylic acid precursors by a hydroformylation process which comprises reacting a vinyl ether with carbon monoxide and hydrogen in the presence of a catalyst comprising a rhodium carbonyl compound and a phosphine ligand at a mild temperature and pressure until there is substantial formation of the intermediate 2- and 3-ethoxypropanals, followed by oxidation of said aldehydes and pyrolysis to said acrylic acid.

Abstract translation: 公开了通过加氢甲酰化方法制备丙烯酸前体的方法，该方法包括在温和的温度和压力下，在包含羰基铑化合物和膦配体的催化剂的存在下使乙烯基醚与一氧化碳和氢气反应直至存在 大量形成中间体2-和3-乙氧基丙醛，随后氧化所述醛并热解成所述丙烯酸。

公开(公告)号：US08952087B2

公开(公告)日：2015-02-10

申请号：US12258402

申请日：2008-10-25

Applicant: Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

IPC: C08K3/08 ,  B22F9/00 ,  B22F1/00 ,  B22F9/24 ,  B82Y30/00

CPC classification number: B22F9/24 ,  B22F1/0022 ,  B22F2999/00 ,  B82Y30/00 ,  B22F1/0059

Abstract: The present invention provides a method for reducing metal ions (for example, silver ions) and stably dispersing metal nanoparticles by nanosilicate platelets. An organic dispersant, nanosilicate platelets and a metal ionic solution are mixed to perform a reductive reaction, wherein the organic dispersant is tri-sodium citrate dihydrate (SCD), chitosan or polyvinyl pyrrolidone (PVP), to produce a mixture of stably dispersed metal nanoparticles.

Abstract translation: 本发明提供了还原金属离子（例如银离子）并通过纳米硅酸盐片稳定分散金属纳米粒子的方法。 将有机分散剂，纳米硅酸盐片和金属离子溶液混合以进行还原反应，其中有机分散剂是柠檬酸三钠二水合物（SCD），壳聚糖或聚乙烯吡咯烷酮（PVP）），以产生稳定分散的金属纳米颗粒 。

公开(公告)号：US20130172447A1

公开(公告)日：2013-07-04

申请号：US13561072

申请日：2012-07-29

Applicant: Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

Inventor： Jiang-Jen Lin ,  Ying-Nan Chan ,  Jau-Yu Chiou

IPC: C09K21/12 ,  C08K3/36 ,  C08L63/02 ,  B82Y30/00

CPC classification number: C08K5/5399 ,  B82Y30/00 ,  C07F9/65815 ,  C08K9/04 ,  C08L63/00 ,  C09K21/12

Abstract: A phosphorous flame retardant including nanosilicate platelets (NSP) is made by first reacting hexachlorotriphosphazene (HCP) with poly(oxyalkylene)amine, then mixing the HCP product with nano silicate platelets (NSP) to obtain the phosphorous flame retardant including NSP. The phosphorous flame retardant can be further applied to an epoxy resin as a curing agent.

Abstract translation: 通过首先使六氯三磷腈（HCP）与聚（氧化烯）胺反应，然后将HCP产物与纳米硅酸盐血小板（NSP）混合以获得包括NSP的磷阻燃剂，制备包括纳米硅酸盐血小板（NSP）的磷阻燃剂。 磷阻燃剂可以进一步用作环氧树脂作为固化剂。

公开(公告)号：US20130005918A1

公开(公告)日：2013-01-03

申请号：US13612052

申请日：2012-09-12

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

IPC: C07C231/02 ,  C08F8/32

CPC classification number: C08F26/00

Abstract: Polymeric polyamine is produced by polymerizing polyoxyalkylene-amine and a linker. The polyoxyalkylene-amine has a structural formula H2N—R—NH2, wherein R is selected from the group consisting of dianhydride, diacid, epoxy, diisocyanate and poly(styrene-co-maleic anhydride) copolymers (SMA). The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The polymeric polyamine so produced can be used as a stabilizer or dispersant of the Ag nanoparticles.

Abstract translation: 聚合多胺通过聚合聚氧亚烷基 - 胺和接头来制备。 聚氧化烯胺具有结构式H2N-R-NH2，其中R选自二酐，二酸，环氧，二异氰酸酯和聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 接头可以是酐，羧酸，环氧，异氰酸酯或聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 如此生产的聚合多胺可用作Ag纳米颗粒的稳定剂或分散剂。

公开(公告)号：US20120279352A1

公开(公告)日：2012-11-08

申请号：US13549417

申请日：2012-07-14

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

IPC: B22F9/16 ,  B82Y40/00

CPC classification number: B22F9/24 ,  B22F1/0018 ,  B82Y30/00 ,  Y10S977/896

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract translation: 本发明提供使用乙醇胺制造银纳米粒子的方法。 本发明的方法可以容易地操作，不需要有机溶剂。 乙醇胺首先与聚（苯乙烯 - 共 - 马来酸酐）（缩写为SMA）的共聚物反应生成聚合物聚合物。 聚合物聚合物然后将银离子还原成以银纳米颗粒形式分散的银原子。 聚合物聚合物的官能团可以与银离子螯合并与水或有机溶剂稳定地相容，由此可以稳定地分散银纳米颗粒而不会聚集，并且所制备的银纳米颗粒。

公开(公告)号：US20120031846A1

公开(公告)日：2012-02-09

申请号：US13039335

申请日：2011-03-03

Applicant: Jiang-Jen Lin ,  Ru-Siou Hsu

Inventor： Jiang-Jen Lin ,  Ru-Siou Hsu

IPC: B01D59/30

CPC classification number: C02F1/281 ,  B01D17/0202 ,  B01J20/10 ,  B01J20/12 ,  B01J20/3204 ,  B01J20/3272 ,  C02F1/285 ,  C02F1/288 ,  C02F1/681 ,  C02F2001/425 ,  C02F2101/32 ,  C10G25/003 ,  C10G33/04

Abstract: The present invention provides a method for collecting oil with a modified clay. By mixing the modified clay and oil, the oil can be adsorbed to the clay. The modified clay is obtained by intercalating a hydrophobic polymer such as acidified poly(oxyalkylene)-amine into layered silicate clay, mica or talc to enlarge the interlayer space. The modified clay thus becomes hydrophobic and adsorption to the oil is promoted.

Abstract translation: 本发明提供一种用改性粘土收集油的方法。 通过混合改性粘土和油，油可以吸附到粘土上。 改性粘土是通过将层状硅酸盐粘土，云母或滑石中的疏水性聚合物如酸化的聚（氧化烯） - 胺嵌入而获得的，以扩大层间空间。 因此，改性粘土变得疏水，促进了对油的吸附。

公开(公告)号：US20100274036A1

公开(公告)日：2010-10-28

申请号：US12765853

申请日：2010-04-22

Applicant: Jiang-Jen Lin ,  Wei-Ting Chen ,  Yen-Chi Hsu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Wei-Ting Chen ,  Yen-Chi Hsu ,  Chih-Wei Chiu

IPC: C07F7/02

CPC classification number: C08K13/02 ,  B01F17/0007 ,  B01F17/0021 ,  B01F17/0042 ,  B01F17/0085

Abstract: The present invention provides an organic/inorganic compositive dispersant and a method for producing the same. The compositive dispersant comprises a complex of inorganic clay and an organic surfactant. The compositive dispersant is produced by reacting inorganic clay with the organic surfactant in a solvent to generate a complex. The inorganic clay is layered or platelet. The organic surfactant is an anionic surfactant such as alkyl sulfates, a nonionic surfactant such as octylphenol polyethoxylate and polyoxyethylene alkyl ether, or a cationic surfactant such as fatty (C12˜C32) quaternary ammonium salts and fatty (C12˜C32) quaternary ammonium chlorides.

Abstract translation: 本发明提供一种有机/无机复合分散剂及其制造方法。 复合分散剂包括无机粘土和有机表面活性剂的复合物。 复合分散剂通过无机粘土与有机表面活性剂在溶剂中反应生成复合物。 无机粘土是分层的或血小板的。 有机表面活性剂是阴离子表面活性剂，如烷基硫酸盐，非离子表面活性剂如辛基苯酚聚乙氧基化物和聚氧乙烯烷基醚，或阳离子表面活性剂如脂肪（C12〜C32）季铵盐和脂肪（C12〜C32）季铵氯化物。

公开(公告)号：US07022299B2

公开(公告)日：2006-04-04

申请号：US10270209

申请日：2002-10-15

Applicant: Jiang-Jen Lin ,  Chin-Cheng Chou ,  Tzong-Yuan Juang

Inventor： Jiang-Jen Lin ,  Chin-Cheng Chou ,  Tzong-Yuan Juang

IPC: C01B33/12

CPC classification number: C01B33/44

Abstract: The present invention discloses an exfoliative clay and a derivative thereof and a method for producing the same. The exfoliative clay is formed by emulsion exfoliating an inorganic layered silicate clay with an amphibious intercalating agent by powerfully stirring at 60–180° C. and not less than 14.7 psig. The amphibious intercalating agent is obtained by copolymerizing polyoxyalkylene amine having molecular weight over 1,800 and polypropylene-grafting-maleic anhydride (PP-g-MA). Before emulsion exfoliation, the intercalating agent is acidified with an inorganic acid. The acidification is the key step for obtaining nanoscale of emulsifying particles less than 100 nm for the exfoliation. The exfoliative clay can be further extracted with a hydroxide or a chloride of alkali metal or alkaline-earth metal to obtain a derivative in the form of nanosilica plates which is free of organic portions.

Abstract translation: 本发明公开了一种剥离性粘土及其衍生物及其制造方法。 通过在60-180℃和不低于14.7psig的强力搅拌下将无机层状硅酸盐粘土与两栖嵌入剂乳化成剥离形成剥离性粘土。 通过共聚分子量超过1800的聚氧亚烷基胺和聚丙烯接枝 - 马来酸酐（PP-g-MA）获得两栖嵌入剂。 在乳液脱落之前，插入剂用无机酸酸化。 酸化是获得纳米级乳化颗粒小于100nm的剥落的关键步骤。 剥离性粘土可以用碱金属或碱土金属的氢氧化物或氯化物进一步提取，得到无机部分的纳米二氧化硅板形式的衍生物。

公开(公告)号：US06458292B1

公开(公告)日：2002-10-01

申请号：US09686937

申请日：2000-10-12

Applicant: Jiang-Jen Lin ,  Jann-Chen Lin ,  Wen-Hen L{dot over (o)} ,  Wen-Shwong Hwang ,  Kun-Hai Lin

Inventor： Jiang-Jen Lin ,  Jann-Chen Lin ,  Wen-Hen L{dot over (o)} ,  Wen-Shwong Hwang ,  Kun-Hai Lin

IPC: C02F514

CPC classification number: C10G75/04 ,  C02F5/12 ,  C02F5/14 ,  C07F9/224 ,  Y10S585/95

Abstract: A composition for an anti-scale-forming agent includes oil-based polyalkylenes, amines phosphorous and oxygen in a polymer for providing dispersivity and anti-oxidation and having the following formula: By integrating both characteristics into a single polymer, the anti-scale-forming agent in accordance with the present invention can be used as an anti-scale-forming agent for a manufacturing process in a petroleum refinery plant or the like chemistry factory. R1, R2 and x are defined herein.

Abstract translation: 用于防垢剂的组合物包括用于提供分散性和抗氧化性的聚合物中的油基聚亚烷基，亚磷酸和氧，并具有以下结构式：通过将两种特性整合到单一聚合物中， 根据本发明的成型剂可以用作炼油厂等化学工厂中的制造方法的防垢剂。 R1，R2和x在本文中定义。