Abstract:
The present invention provides an additive comprising A) a copolymer of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) a comb polymer containing structural units of B1) at least one olefin as monomer 1, which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2, which bears at least one C8-C16-alkyl radical bonded via an amide and/or imide moiety, wherein the sum Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the amide and/or imide groups of monomer 2 on the other hand is from 23 to 27, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2.
Abstract:
The invention provides a fuel oil composition comprising a fuel oil of animal or vegetable origin and an additive comprising A) at least one copolymer of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units having C8-C16-alkyl radicals, the structural units being selected from C8-C16-alkyl (meth)acrylates, C8-C16-alkyl vinyl esters, C8-C16-alkyl vinyl ethers, C8-C16-alkyl (meth)acrylamides, C8-C16-alkyl allyl ethers and C8-C16-diketenes, where the sum R R = m 1 · ∑ i w 1 i · n 1 i + m 2 · ∑ j w 2 j · n 2 j + … + m g · ∑ p w gp · n gp is the molar average of the carbon chain length distributions in the alkyl radicals of the monomers B) is from 11.0 to 14.0, where m1, m2, . . . mg are the molar fractions of the abovementioned monomers B) in the polymer and the sum of the molar fractions m1 to mg=1, w1i, w1j . . . w2i, w2j . . . wgp are the proportions by weight of the individual chain lengths i, j, . . . p of the alkyl radicals of the different monomers B) 1 to g, and n1i, n1j . . . n2i, n2j . . . ngp are the chain lengths of the alkyl radicals i, j, . . . p of the monomers B) 1 to g.
Abstract:
The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units having C8-C16-alkyl radicals, the structural units being selected from C8-C16-alkyl (meth)acrylates, C8-C16-alkyl vinyl esters, C8-C16-alkyl vinyl ethers, C8-C16-alkyl(meth)acrylamides, C8-C16-alkyl allyl ethers and C8-C16-diketenes, where the sum R R = m 1 · ∑ i w 1 i · n 1 i + m 2 · ∑ j w 2 j · n 2 j + … + m g · ∑ p w gp · n gp of the molar averages of the carbon chain length distributions in the alkyl radicals of the monomers B) is from 11.0 to 14.0, where m1, m2, . . . mg are the molar fractions of the abovementioned monomers B) in the polymer, and the sum of the molar fractions m1 to mg=1, w1i, w1j . . . w2i, w2j . . . wgp are the proportions by weight of the individual chain lengths i, j, p of the alkyl radicals of the different monomers B) 1 to g, and n1i, n1j . . . n2i, n2j . . . ngp are the chain lengths of the alkyl radicals i, j, . . . p of the monomers B) 1 to g.
Abstract:
The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (I) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.
Abstract:
An additive for low-sulfur mineral oil distillates having improved cold flowability and paraffin dispersancy, comprising at least one ester of an alkoxylated polyol and at least one polar nitrogen-containing paraffin dispersant.
Abstract:
The present invention relates to a fuel oil additive comprising A) a copolymer of ethylene and from 18 to 35 mol % of at least one acrylic ester or vinyl ester having a C1-C18-alkyl radical and a degree of branching of less than 5 CH3/100 CH2 groups, and B) a comb polymer comprising structural units formed from B1) at least one olefin as monomer 1, which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2, which bears at least one C8-C16-alkyl radical bonded via an amide and/or imide group, in which the parameter Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j in which w1 is the molar proportion of the individual chain lengths n, in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths n2 in the alkyl radicals of the amide and/or imide groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, i is the serial variable for the chain lengths in the alkyl radicals of monomer 1, and is the serial variable for the chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2 assumes values of from 23 to 27.
Abstract:
The invention provides graft copolymers obtainable by grafting an ester (a) of a C8- to C22-alcohol and acrylic acid onto a copolymer (b) containing, in addition to ethylene, from 0.5 to 16 mol % of at least one vinyl ester of the formula 1 CH2═CH—OCOR1 (1) where R1 is a branched C5- to C15-alkyl radical, with the proviso that the copolymer b) contains less than 3.5 mol % of vinyl acetate.
Abstract:
The present invention relates to alkylphenol-aldehyde resins containing oligo- or polymmers having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula —(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radicals or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or-alkenyl, n is from 1 to 100 and k is 1 or 2.
Abstract:
The invention provides an additive for fuel oils, comprising at least one copolymer of ethylene and an unsaturated ester, at least one oil-soluble polar nitrogen compound which is a reaction product of amines of the formula NR6R7R8 in which R6, R7 and R8 may be the same or different, and at least one of these groups is C8-C36-alkyl, C6-C36-cycloalkyl, C8-C36-alkenyl, especially C12-C24-alkyl, C12-C24-alkenyl or cyclohexyl, and the remaining groups are hydrogen, C1-C36-alkyl, C2-C36-alkenyl, cyclohexyl or a group of the formulae -(A-O)x-E or —(CH2)n—NYZ in which A is an ethyl or propyl group, x is from 1 to 50, E=H, C1-C30-alkyl, C5-C12-cycloalkyl or C6-C30-aryl, and n=2, 3 or 4, and Y and Z are each independently H, C1-C30-alkyl or -(A-O)x with compounds which contain at least one acyl group, and at least one aromatic compound of the formula 1, in which R is H or C1- to C4-alkyl.
Abstract:
The invention provides an emulsified water in oil composition comprising: A) a fuel; B) a water; C) a high molecular weight emulsifier; D) a surfactant having a molecular weight of about less than or equal to about 950 g/mol wherein the surfactant comprises: i) natural fats; ii) non-ionic and ionic surfactants; iii) co-surfactant; iv) fatty acids and their amine salts; or v) combinations thereof; and E) optionally ammonium nitrate.