Abstract:
Provided are a method of treating coal ash by mixing it with water, in which the coal ash and water undergo a temperature difference therebetween while they are mixed; and a method of desulfurization in a coal combustion boiler system, which comprises mixing coal ash that has been separated from a ash collector in the system, with water on the condition that the two undergo a temperature difference therebetween while they are mixed, and circulating the resulting mixture that serves as a desulfurizing agent into the coal combustor in the system. The desulfurization capability of the desulfurizing agent used in the desulfurization method is higher than that of the desulfurizing agent obtained through hydration of coal ash with water or steam.
Abstract:
A process for treating a waste or treatable material containing noxious component(s), comprising the following steps: (1) carrying out a first step for the treatable material, the first step including (a) mixing a treatment agent with the treatable material to form a mixture, the treatment agent containing alkali metal compound, and (b) heating the mixture in a first furnace at a first temperature in a low oxygen atmosphere to thermally decompose the treatable material to generate a substance containing the noxious component, the substance contacting and reacting with the treatment agent to form a harmless salt; and (2) carrying out a second step for the treatable material, the second step including heating the treatable material in a second furnace separate from the first furnace, at a second temperature higher than the first temperature so as to reduce volume of the treatable material.
Abstract:
A process for treating a waste or treatable material containing noxious component(s), comprising the following steps: (1) carrying out a first step for the treatable material, the first step including (a) mixing a treatment agent with the treatable material to form a mixture, the treatment agent containing alkali metal compound, and (b) heating the mixture in a first furnace at a first temperature in a low oxygen atmosphere to thermally decompose the treatable material to generate a substance containing the noxious component, the substance contacting and reacting with the treatment agent to form a harmless salt; and (2) carrying out a second step for the treatable material, the second step including heating the treatable material in a second furnace separate from the first furnace, at a second temperature higher than the first temperature so as to reduce volume of the treatable material.
Abstract:
The process is by injection of calcium chloride into the combustor and lowering the flue gas temperature in sufficient time to enhance oxidation of mercury and nitrogen oxides into more soluble products prior to their absorption in a wet scrubber. The additive also increases the alkalinity and the pH of the scrubber water, therefore, favorably increasing the absorption of the pollutants. The flue gas is then cooled to ambient temperature or less to enhance the removal of mercury.
Abstract:
Non-hazardous organic waste material is introduced into a slagging combustor where it is burned. The burning produces exhaust gases and a slag of molten, inorganic ash which is removed from the combustor. The exhaust gases are treated to cool and dry the gases and to remove a major portion of particulate matter contained therein. A portion of the treated exhaust gases is mixed with a source of concentrated oxygen in a proportion that results in mixed gases having an oxygen concentration of at least 30% by volume. The mixed gases are introduced into the combustor to support the burning of the waste material. Another portion of the treated exhaust gases is further treated to recover the carbon dioxide therefrom.
Abstract:
A low-cost volume-reducing treatment method for waste which thermally decomposes or burns chlorine-containing waste while the generation of hydrogen chloride and dioxin is completely or considerably suppressed. According to the method, volume of the waste can be greatly reduced. Shredder dust and other waste which contains chlorine derived from, for example, chlorine-containing polymers is thermally decomposed or burned at a temperature of 300.degree. to 1000.degree. C. in a reducing atmosphere where unburned carbon remains. Preferably, a basic material like red mud which contains alkali metal oxides or alkaline earth metal oxides is added before treatment.
Abstract:
The disclosure describes a method of incinerating combustible wastes comprising the step of incinerating said combustible wastes in the presence of a calcium compound and particles selected from the group consisting of iron oxide particles, ferric oxide hydroxide particles and mixed particles thereof.
Abstract:
Virtually complete bonding of salt-forming agents to solids during the combustion of fossil fuels, waste or the like by adding basic solids, in particular CaCO.sub.3 or MgCO.sub.3, can be achieved by the following process steps:the moisture content of the fossil fuels, the waste or the like is adjusted to 10 to 35% by weight;the basic substances are added to the fossil fuels, the waste or the like in the most uniform distribution possible, the stoichiometric ratio of basic substances to salt-forming agents being less than 5:1;after the basic substances have been added, the fossil fuels, waste or the like remain in an essentially sealed container, so that a state of water vapor saturation is obtained;the mixture is then burnt at a fuel bed temperature below the thermal dissociation temperature of the compounds resulting from the basic substances and the halogens.
Abstract:
In the conventional incineration of solid waste materials, flyash present in the combustion products gas stream catalyzes the formation of toxic dioxins from chlorinated organic materials. By providing a catalyst poison, such as carbon disulphide, in association with the flyash, typically by spraying onto the solid wastes prior to incineration, the catalytic effect is decreased, resulting in decreased dioxin formation.
Abstract:
Mineral additives and a method for operating a waste-to-energy furnace are provided in order to improve its operational performance and availability, increase the lifetime of the combustor building materials (refractory walls and heat-exchanger metallic tubes) and flue gas treatment equipment, improve ash quality, reduce emissions and avoid combustion problems such as agglomeration, slagging, deposition, and corrosion. A method for operating a waste-to-energy furnace, such as a fluidized bed reactor, pulverized-fuel combustor, grate combustor includes introducing mineral additive into the furnace. The method further includes heating at least a portion of the mineral additive either intimately in contact with the fuel, such that the ability of mineral additive to induce crystallization of the surface of forming ashes is enhanced, or minimizing the contact of the mineral additive with the fuel and the forming ashes, such that the solid-gas reactions between the mineral additive and the volatile compounds in the flue gas are favored and the mineral additive power to capture at least a portion of the inorganic volatile compounds present in the furnace is enhanced.