公开(公告)号：US08969643B2

公开(公告)日：2015-03-03

申请号：US13900633

申请日：2013-05-23

Applicant: Ashim Kumar Ghosh ,  Pamela Harvey ,  Neeta Kulkarni ,  Manuel Castelan

Inventor： Ashim Kumar Ghosh ,  Pamela Harvey ,  Neeta Kulkarni ,  Manuel Castelan

IPC: C07C4/18 ,  C07C5/22

CPC classification number: C07C4/18 ,  B01J29/40 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/42 ,  C07C2/864 ,  C07C6/123 ,  C07C2529/40 ,  C10G35/095 ,  C10G59/02 ,  Y02P20/52 ,  C07C15/08 ,  C07C15/04

Abstract: A method of converting hydrocarbons requires contacting a hydrocarbon stream containing alkylated aromatic hydrocarbons with a catalyst of a phosphorus-containing pentasil zeolite in a reactor. The phosphorus-containing pentasil zeolite having a phosphorus content of 7.5% or less by weight of zeolite, a pore volume of at least 0.2 ml/g, and a 27Al MAS NMR spectrum characterized by a peak at or near 50 ppm that is greater than any other peak in said spectrum. A benzene-enriched output stream is recovered from the reactor.

Abstract translation: 转化烃的方法需要在反应器中使包含烷基化芳烃的烃物流与含磷五硅沸石催化剂接触。 磷含量为沸石重量的7.5％以下，含孔体积为0.2ml / g以上的含磷pentasil沸石和27Al MAS NMR光谱，其特征在于在50ppm附近或接近50ppm的峰，其大于 所有频谱中的任何其他峰。 从反应器回收富含苯的输出流。

公开(公告)号：US08969242B2

公开(公告)日：2015-03-03

申请号：US13822340

申请日：2012-08-03

Applicant: Darryl P. Klein ,  Nan Chen ,  Matthew P. Woods ,  Bruno Nesci

Inventor： Darryl P. Klein ,  Nan Chen ,  Matthew P. Woods ,  Bruno Nesci

IPC: B01J21/04 ,  B01J23/02 ,  B01J27/24 ,  B01J23/00 ,  B01J37/28 ,  B01J23/85 ,  B01J23/883 ,  B01J35/10 ,  C10G45/10 ,  C10G47/14 ,  C10G65/12 ,  B01J37/03 ,  B01J37/02

CPC classification number: B01J21/04 ,  B01J23/00 ,  B01J23/85 ,  B01J23/883 ,  B01J27/24 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/08 ,  B01J37/28 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G47/10 ,  C10G47/12 ,  C10G47/14 ,  C10G65/00 ,  C10G65/12 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/208 ,  C10G2300/301

Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.

Abstract translation: 用于化学提炼烃原料的方法中的负载催化剂，该催化剂包含第6族金属，第8族金属和任选的磷，其中载体或载体包含多孔氧化铝，其包含：（a）等于或大于 在直径小于约200埃（A）的孔中约78％至约95％的TPV; （b）直径约200至小于约1000的孔中TPV大于约2％至小于约19％; （c）等于或大于直径等于或大于约1000的孔中的TPV的3％至小于12％。

公开(公告)号：US08940652B2

公开(公告)日：2015-01-27

申请号：US13668429

申请日：2012-11-05

Applicant: Qi Fu ,  Chandrashekhar Pandurang Kelkar ,  Gary Smith ,  Bilge Yilmaz

Inventor： Qi Fu ,  Chandrashekhar Pandurang Kelkar ,  Gary Smith ,  Bilge Yilmaz

IPC: B01J29/08 ,  B01J29/06 ,  B01J27/24 ,  B01J37/04 ,  B01J37/16 ,  B01J29/10 ,  B01J35/10 ,  C01B39/24 ,  C10G11/05 ,  C10G11/18 ,  B01J37/28

CPC classification number: B01J27/24 ,  B01J29/06 ,  B01J29/084 ,  B01J29/106 ,  B01J35/1019 ,  B01J37/04 ,  B01J37/16 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/42 ,  C01B39/24 ,  C10G11/05 ,  C10G11/18

Abstract: A phosphorus modification of an FCC catalyst is provided by reducing the sodium content of the as formed catalyst, a first treatment with a phosphate solution, a second ammonium exchange to further reduce the sodium content of the phosphorus solution treated catalyst and a second treatment with a phosphate solution.

Abstract translation: FCC催化剂的磷改性通过降低形成的催化剂的钠含量，用磷酸盐溶液进行第一次处理，进行第二次铵交换以进一步降低磷溶液处理的催化剂的钠含量和第二次处理 磷酸盐溶液。

公开(公告)号：US20140371059A1

公开(公告)日：2014-12-18

申请号：US14307031

申请日：2014-06-17

Applicant: The Curators of the University of Missouri

Inventor： Matthew J. O'KEEFE ,  Carlos E. CASTANO LONDONO ,  William G. FAHRENHOLTZ

IPC: B01J23/10

CPC classification number: B01J23/10 ,  B01J27/1804 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/004 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/035 ,  B01J37/06 ,  B01J37/28 ,  B01J37/345 ,  C22C21/10 ,  C22C21/12 ,  C22C23/02 ,  C23C22/48 ,  C23C22/56 ,  C23C22/57 ,  C23C22/73 ,  C23C22/78 ,  C23C22/83 ,  C25B1/003

Abstract: Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

Abstract translation: 实施方案涉及含铈纳米涂料组合物，所述组合物包括包含一种或多种氧化铈，氢氧化铈和磷酸铈的无定形基质; 以及包括一种或多种结晶氧化铈，结晶铈氢氧化物和结晶性铈磷酸盐的结晶区域。 每个结晶区域的直径小于约50纳米。

公开(公告)号：US08894842B2

公开(公告)日：2014-11-25

申请号：US13274509

申请日：2011-10-17

Applicant: Sylvie Lacombe ,  Malika Boualleg ,  Eric Sanchez

Inventor： Sylvie Lacombe ,  Malika Boualleg ,  Eric Sanchez

IPC: C10G35/06 ,  C10G35/085 ,  C10G35/09 ,  B01J27/13 ,  B01J27/053 ,  B01J37/02 ,  B01J21/04 ,  B01J37/00 ,  B01J37/20 ,  B01J23/46 ,  B01J37/28 ,  B01J23/656 ,  B01J23/42 ,  B01J23/62

CPC classification number: C10G35/09 ,  B01J21/04 ,  B01J23/42 ,  B01J23/468 ,  B01J23/626 ,  B01J23/6567 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/20 ,  B01J37/28 ,  C10G2300/1096 ,  C10G2300/305

Abstract: The present invention concerns an optimized reforming catalyst comprising at least platinum, at least one promoter metal selected from the group formed by rhenium and iridium, at least one halogen, and at least one alumina support with a low sulphur and phosphorus content.

Abstract translation: 本发明涉及一种优化的重整催化剂，其包含至少一种铂，至少一种选自由铼和铱形成的助催化剂金属，至少一种卤素和至少一种具有低硫和磷含量的氧化铝载体。

公开(公告)号：US20140243570A1

公开(公告)日：2014-08-28

申请号：US14236726

申请日：2012-07-25

Applicant: Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

Inventor： Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

IPC: C07C1/24

CPC classification number: C07C1/24 ,  B01J29/40 ,  B01J29/85 ,  B01J37/10 ,  B01J37/28 ,  C07C2527/14 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04

Abstract: A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.

Abstract translation: 催化剂可用于将脱水过程中的醇转化为具有与醇相同数目的碳原子的烯烃。 催化剂可以包括通过在结构中提供具有至少一个十元环的沸石而制成的磷改性沸石，蒸煮沸石，将沸石与粘合剂和成型添加剂混合，以及成型沸石。 可以进行离子交换步骤，并且可以蒸成型催化剂。 磷可以以至少0.1重量％的量引入催化剂上，例如通过干浸渍或化学气相沉积。 可以引入金属。 可以将催化剂洗涤和/或煅烧，并在平衡步骤中蒸煮。 蒸汽浓度（X）可以至少约为2.催化剂可以在高于625℃的温度下蒸煮，例如700-800℃的温度。

公开(公告)号：US08795619B2

公开(公告)日：2014-08-05

申请号：US12599057

申请日：2008-05-08

Applicant: Tadashi Suzuki ,  Satoru Kato ,  Naoki Takahashi ,  Takaaki Kanazawa ,  Masanori Yamato ,  Kazuhiro Yoshimoto ,  Michihiko Takeuchi ,  Yuuji Matsuhisa

Inventor： Tadashi Suzuki ,  Satoru Kato ,  Naoki Takahashi ,  Takaaki Kanazawa ,  Masanori Yamato ,  Kazuhiro Yoshimoto ,  Michihiko Takeuchi ,  Yuuji Matsuhisa

IPC: B01D50/00 ,  B01D53/34 ,  B01D53/04 ,  B01D53/56 ,  C01B17/16 ,  C01B31/20 ,  B01J27/00 ,  B01J27/185 ,  B01J21/00 ,  B01J21/04 ,  B01J25/00 ,  B01J23/00 ,  B01J23/02 ,  B01J23/04 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J20/00

CPC classification number: B01D53/9445 ,  B01D2255/20707 ,  B01D2255/20738 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/9207 ,  B01D2257/304 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/702 ,  B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/63 ,  B01J23/6525 ,  B01J23/6527 ,  B01J23/8906 ,  B01J35/002 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0242 ,  B01J37/08 ,  B01J37/28 ,  F01N2570/24 ,  Y02T10/22

Abstract: A catalyst for purification of exhaust gas, in which a noble metal is supported on a metal oxide support, has a basic site content of 1 mmol/L-cat or less, as determined on the basis of an amount of CO2 desorbed per liter of the catalyst as measured by a CO2 temperature-programmed desorption method.

Abstract translation: 用于净化贵金属负载在金属氧化物载体上的废气的催化剂的碱性位置含量为1mmol / L-cat以下，其基于每升脱附的二氧化碳的量 催化剂通过CO 2温度程序解吸法测量。

公开(公告)号：US20140193327A1

公开(公告)日：2014-07-10

申请号：US14236734

申请日：2012-07-26

Applicant: John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett

Inventor： John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett

IPC: B01J29/88 ,  B01D53/86 ,  B01J29/85

CPC classification number: B01J29/763 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/707 ,  B01J29/7015 ,  B01J29/85 ,  B01J29/88 ,  B01J35/04 ,  B01J37/0246 ,  B01J37/28 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/04 ,  C01B39/10 ,  C01B39/54 ,  Y02T10/24

Abstract: A catalyst composition is provided having a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The catalyst composition is capable of NOx conversion at elevated temperatures. A catalytically active washcoat includes such catalyst compositions and one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article. Methods of reducing NOx employing the catalyst compositions are also provided.

Abstract translation: 提供了具有CHA晶体结构的催化剂组合物; 约0.5至约5.0mol％的磷; 和摩尔比为约5至约40的SiO 2和Al 2 O 3。催化剂组合物能够在升高的温度下进行NOx转化。 催化活性的修补基面涂料包括这样的催化剂组合物和一种或多种促进剂或稳定剂，并且可以应用于整料基材以产生催化活性制品。 还提供了使用催化剂组合物还原NOx的方法。

公开(公告)号：US20140116924A1

公开(公告)日：2014-05-01

申请号：US13660879

申请日：2012-10-25

Applicant: SHELL OIL COMPANY

Inventor： Opinder Kishan BHAN

IPC: B01J23/883 ,  C10G45/08

CPC classification number: B01J23/883 ,  B01J27/19 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/28 ,  B01J38/68 ,  B01J38/72 ,  C10G45/08 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206

Abstract: A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The calcined particle comprises from 1 to 10 weight percent molybdenum and nickel that is present in an amount such that the weight ratio of said nickel-to-molybdenum is less than 0.4. The calcined particle has a pore size distribution that contributes to the unique properties of the catalyst. The calcined particle and catalyst also exhibits a unique Raman spectrum. The self activating catalyst is activated when contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations.

Abstract translation: 一种用于处理重烃原料的自活化催化剂，其包含煅烧颗粒，该煅烧颗粒包含通过共研磨无机氧化物粉末，三氧化钼粉末和镍化合物制成的共研磨混合物，然后将共研磨混合物形成为 煅烧，从而提供煅烧颗粒。 煅烧颗粒包含1至10重量％的钼和镍，其存在量使得所述镍 - 钼的重量比小于0.4。 煅烧颗粒具有有助于催化剂独特性质的孔径分布。 煅烧颗粒和催化剂也表现出独特的拉曼光谱。 当在合适的工艺条件下与具有高镍，钒和硫浓度的重残余原料接触时，自活化催化剂被活化。

公开(公告)号：US08633127B2

公开(公告)日：2014-01-21

申请号：US12710781

申请日：2010-02-23

Applicant: Tin-Tack Peter Cheung ,  Zongxuan Hong

Inventor： Tin-Tack Peter Cheung ,  Zongxuan Hong

IPC: B01J31/00 ,  B01J23/00 ,  B01J21/00

CPC classification number: C07C5/09 ,  B01J23/44 ,  B01J23/66 ,  B01J27/13 ,  B01J31/0271 ,  B01J31/1616 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/24 ,  B01J31/2404 ,  B01J35/008 ,  B01J35/023 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0203 ,  B01J37/024 ,  B01J37/28 ,  B01J2231/645 ,  B01J2531/824 ,  C07C5/05 ,  C07C2521/04 ,  C07C2531/26 ,  C10G45/40 ,  C10G2300/703

Abstract: A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

Abstract translation: 一种包含负载氢化催化剂的组合物，其包含钯和有机磷化合物，所述负载氢化催化剂能够将高度不饱和烃选择性氢化为不饱和烃。 一种制备选择性氢化催化剂的方法，包括使载体与含钯​​化合物接触以形成负载钯的组合物，使钯负载的组合物与有机磷化合物接触以形成催化剂前体，还原催化剂前体以形成催化剂。 将高度不饱和烃选择性氢化为不饱和烃富集组合物的方法，包括在适于氢化至少一部分高度不饱和烃进料的条件下使包含钯和有机磷化合物的负载催化剂与包含高度不饱和烃的进料接触以形成 不饱和烃富集组合物。