公开(公告)号：US06890994B2

公开(公告)日：2005-05-10

申请号：US10305284

申请日：2002-11-26

Applicant: Walter H. Ohrbom ,  Craig S. Schang ,  Donald Campbell ,  Donald L. St. Aubin

Inventor： Walter H. Ohrbom ,  Craig S. Schang ,  Donald Campbell ,  Donald L. St. Aubin

IPC: C07C217/12 ,  C07C271/16 ,  C08F20/36 ,  C08G18/28 ,  C08G18/38 ,  C08G71/04 ,  C09D175/04 ,  C09D201/02 ,  C08F2/00

CPC classification number: C07C217/12 ,  C07C271/16 ,  C08F20/36 ,  C08G18/285 ,  C08G18/3831 ,  C08G71/04 ,  C09D175/04 ,  C09D201/025 ,  Y10T428/31529 ,  Y10T428/31663 ,  C08L2666/16 ,  C08L2666/02 ,  C08L2666/28

Abstract: The invention provides an acrylic polymer or oligomer comprising random repeating units of the formula: a method of making said polymers and curable coating compositions comprising the same.

Abstract translation: 本发明提供了包含下式的无规重复单元的丙烯酸聚合物或低聚物：制备所述聚合物的方法和包含该聚合物的可固化涂料组合物。

公开(公告)号：US20050079362A1

公开(公告)日：2005-04-14

申请号：US10957568

申请日：2004-10-01

Applicant: Walter Ohrbom ,  Donald Campbell ,  Donald St. Aubin ,  Swaminathan Ramesh ,  Paul Harris ,  Ulrike Rockrath

Inventor： Walter Ohrbom ,  Donald Campbell ,  Donald St. Aubin ,  Swaminathan Ramesh ,  Paul Harris ,  Ulrike Rockrath

IPC: C08F8/14 ,  C08F8/30 ,  C08F222/20 ,  C08F222/22 ,  C09D201/02 ,  B32B27/38

CPC classification number: C08F222/20 ,  C08F8/14 ,  C08F220/06 ,  C08F220/08 ,  C08F222/22 ,  C08G18/00 ,  C09D201/025 ,  Y10T428/31511 ,  C08F265/06

Abstract: Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C═C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.

Abstract translation: 公开了一种从线性不饱和酸酐制造非功能性加成聚合物的方法。 该方法使线性不饱和酸酐化合物，活性氢化合物和环氧化合物进行反应，使得发生以下三个反应中的每一个：（i）可聚合的C = C键的聚合，（ii）酸酐的开环 通过活性氢化合物的线性不饱和酸酐化合物的官能团，以产生酸官能团，和（iii）由酸酐开环产生的酸官能团与环氧化合物的反应。 在反应（iii）时，由酸酐开环产生的酸官能团可以选自烯属不饱和单体，聚合物或两者。 在一个实施方案中，该方法不包括物理去除任何酸官能单体或聚合产物。 还公开了可固化涂料组合物和涂布的基材。

公开(公告)号：US06878841B2

公开(公告)日：2005-04-12

申请号：US10182528

申请日：2001-01-24

Applicant: Heinz-Peter Rink ,  Jochem Henkelmann ,  Werner-Alfons Jung ,  Paul J. Harris ,  Swaminathan Ramesh

Inventor： Heinz-Peter Rink ,  Jochem Henkelmann ,  Werner-Alfons Jung ,  Paul J. Harris ,  Swaminathan Ramesh

IPC: C07C269/04 ,  C07C271/12 ,  C07C275/60 ,  C08K5/205 ,  C08K5/21 ,  C09D179/00 ,  C09D201/02 ,  C09J7/02 ,  C09J179/00 ,  C09J201/02 ,  C07C261/00

CPC classification number: C08K5/21 ,  C07C271/12 ,  C07C275/60 ,  C08K5/205

Abstract: Positionally isomeric diethyloctanediol dicarbamates and diethyloctanediol diallophanates, processes for preparing them, and their use as synthesis building blocks and constituents of adhesives, sealing compounds, and coating materials.

Abstract translation: 位置异构的二乙基辛二醇二氨基甲酸酯和二乙二醇二环戊二酸酯，它们的制备方法，以及它们作为粘合剂，密封化合物和涂料的合成结构单元和成分的用途。

公开(公告)号：US06861149B2

公开(公告)日：2005-03-01

申请号：US10447802

申请日：2003-05-29

Applicant: Mark J. Pellerite ,  Michael S. Terrazas ,  Rudolf J. Dams

Inventor： Mark J. Pellerite ,  Michael S. Terrazas ,  Rudolf J. Dams

IPC: B05D7/24 ,  C03C17/30 ,  C03C17/32 ,  C04B41/49 ,  C04B41/52 ,  C04B41/84 ,  C08G65/00 ,  C08G65/336 ,  C08G65/337 ,  C08J3/09 ,  C09D183/08 ,  C09D183/12 ,  C09D201/02 ,  C09K3/18 ,  B32B17/06

CPC classification number: C08G65/337 ,  C03C17/32 ,  C03C17/328 ,  C04B41/009 ,  C04B41/4933 ,  C04B41/52 ,  C08G65/007 ,  C08G65/336 ,  C08J3/09 ,  C08J2383/12 ,  C09D183/12 ,  Y10S528/901 ,  Y10T428/31663 ,  C04B41/0072 ,  C04B41/4535 ,  C04B41/502 ,  C04B2103/40 ,  C04B41/5022 ,  C04B33/00

Abstract: The invention relates to compositions used for aqueous delivery of self-emulsifying fluorinated alkoxysilanes to substrates to provide oil and water resistive coatings for the substrates, a method of treating a substrate to render it oil and water repellent, and articles having coatings made from the compositions.

Abstract translation: 本发明涉及用于将自乳化氟化烷氧基硅烷水性输送到基材以提供用于基材的油和水电阻涂层的组合物，一种处理基材以使其具有防油和防水性的方法，以及具有由组合物制成的涂层的制品 。

公开(公告)号：US06858693B2

公开(公告)日：2005-02-22

申请号：US10602852

申请日：2003-06-24

Applicant: Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce E. Oermann

Inventor： Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce E. Oermann

IPC: C09D5/00 ,  C08F8/00 ,  C08F8/30 ,  C08F220/00 ,  C08G18/38 ,  C08G18/81 ,  C09D133/00 ,  C09D157/06 ,  C09D183/04 ,  C09D201/02 ,  C09J5/00 ,  C08F126/02

CPC classification number: C08G18/8116 ,  C08F8/00 ,  C08F2800/20 ,  C08F2810/50 ,  C08G18/3823 ,  C09D201/025 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31645 ,  C08F2220/325 ,  C08F220/34 ,  C08F220/20 ,  C08F212/08

Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

Abstract translation: 本发明提供氨基甲酸酯官能树脂和包含所述树脂的涂料组合物，其相对于随后施加的膜或涂层具有改善的粘合性。 更具体地说，本发明涉及具有每个氨基甲酸酯基团至少250克聚合物的氨基甲酸酯官能加成聚合物，它们以小于35重量％的非官能单体，优选小于20重量％，最优选0至 小于10重量％，基于聚合物的总重量。 本发明还提供一种制备通过所要求保护的方法制备的氨基甲酸酯官能聚合物和氨基甲酸酯官能聚合物的方法。 最后，本发明提供了一种用于改善第一涂料组合物与随后施加的材料的粘附性的方法，以及制备包含涂覆的基材，粘合剂组合物和具有至少一个表面的玻璃的复合材料的方法。

公开(公告)号：US06855789B2

公开(公告)日：2005-02-15

申请号：US10348484

申请日：2003-03-25

Applicant: Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce E. Oermann

Inventor： Donald H. Campbell ,  Walter H. Ohrbom ,  Joseph Borst ,  Michael A. Gessner ,  Donald L. St. Aubin ,  Marvin L. Green ,  Bruce E. Oermann

IPC: C09D5/00 ,  C08F8/00 ,  C08F8/30 ,  C08F220/00 ,  C08G18/38 ,  C08G18/81 ,  C09D133/00 ,  C09D157/06 ,  C09D183/04 ,  C09D201/02 ,  C09J5/00 ,  C08F126/02

CPC classification number: C08G18/8116 ,  C08F8/00 ,  C08F2800/20 ,  C08F2810/50 ,  C08G18/3823 ,  C09D201/025 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31645 ,  C08F2220/325 ,  C08F220/34 ,  C08F220/20 ,  C08F212/08

Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

公开(公告)号：US6143363A

公开(公告)日：2000-11-07

申请号：US178584

申请日：1998-10-26

Applicant: Hiromichi Noguchi ,  Masami Ikeda ,  Makiko Kimura ,  Masato Katayama ,  Akio Kashiwazaki ,  Yoshie Nakata ,  Yuko Nishioka

Inventor： Hiromichi Noguchi ,  Masami Ikeda ,  Makiko Kimura ,  Masato Katayama ,  Akio Kashiwazaki ,  Yoshie Nakata ,  Yuko Nishioka

IPC: B41M5/00 ,  B32B27/00 ,  B41M5/50 ,  B41M5/52 ,  C08G59/10 ,  C08G59/50 ,  C08G65/24 ,  C08G73/02 ,  C08L63/00 ,  C08L79/02 ,  C08L101/00 ,  C08L101/02 ,  C09D163/00 ,  C09D179/02 ,  C09D201/02 ,  B05D1/36 ,  B05D3/06 ,  B05D5/04 ,  C08K3/20 ,  C08K63/00

CPC classification number: B41M5/52 ,  B41M5/0011 ,  C08G59/10 ,  C08G59/50 ,  C08G65/24 ,  C08L101/02 ,  C08L63/00 ,  C09D163/00 ,  C09D201/02 ,  B41M2205/12 ,  B41M5/5209 ,  B41M5/5245 ,  B41M5/5254 ,  B41M5/5272 ,  B41M5/5281 ,  B41M5/529

Abstract: A composition comprising a water-soluble cationic group-containing high-molecular compound (P1) derived from the reaction of (A) epichlorohydrin and a dialkyl or dialkanol amine, or (B) a glycidyl group-terminated hydrophilic oligomer and a diamine, dialkylamine or dialkanolamine; optionally, a high-molecular compound (P2) having a condensable functional group in a side chain such as alkylolacrylamide-bearing high-molecular compound (E) or hydrolyzable trialkylsilyl group-containing acrylic ester high-molecular compound (F); and a poly(meth)acrylate (P3) is coated onto a substrate and cured by ultraviolet radiation to form a printing medium.

Abstract translation: 由（A）表氯醇与二烷基或二烷醇胺的反应衍生的含水溶性阳离子基团的高分子化合物（P1）或（B）缩水甘油基末端亲水性低聚物和二胺，二烷基胺 或二烷醇胺; 任选地，在侧链中具有可缩合官能团的高分子化合物（P2），例如含有羟烷基丙烯酰胺的高分子化合物（E）或可水解的含三烷基甲硅烷基的丙烯酸酯高分子化合物（F）; 并将聚（甲基）丙烯酸酯（P3）涂覆在基材上并通过紫外线辐照固化形成印刷介质。

公开(公告)号：US6133380A

公开(公告)日：2000-10-17

申请号：US22543

申请日：1998-02-12

Applicant: Koji Yamada ,  Nobushige Numa

Inventor： Koji Yamada ,  Nobushige Numa

IPC: C08G63/91 ,  C09D5/16 ,  C09D167/00 ,  C09D191/06 ,  C09D191/08 ,  C09D201/02 ,  C09D201/06 ,  C08F8/42 ,  C08F8/14 ,  C08A20/10

CPC classification number: C09D191/08 ,  C08G63/914 ,  C09D167/00 ,  C09D191/06 ,  C09D201/06 ,  C09D5/165

Abstract: An antifouling resinous composition comprising as an active component thereof one or more resins represented by the formulasFormula (1)R.sub.p --COO--M--(--o--M--).sub.m --OHFormula (2)R.sub.p --COO--M--(--O--M--).sub.n --OOC--R.sub.pFormula (3) ##STR1## wherein R.sub.p represents a basal resin, M represents in each occurrence the same or different divalent metallic atom, m represents an integer in the range of 1-10, n represents an integer in the range of 0-10, and k represents an integer in the range of 0-10, and contains a metal carboxylate in the molecular unit.

Abstract translation: 一种防污树脂组合物，其包含作为活性组分的一种或多种由式（1）表示的树脂Rp-COO-M - （ - oM-）m-OHFormula（2）Rp-COO-M - （ - OM-） n-OOC-RpFormula（3）其中Rp表示基础树脂，M表示每次出现相同或不同的二价金属原子，m表示1-10的整数，n表示0〜 10，k表示0〜10的整数，在分子单元中含有金属羧酸盐。

公开(公告)号：US6114444A

公开(公告)日：2000-09-05

申请号：US287351

申请日：1994-08-08

Applicant: John W. Rehfuss ,  Walter H. Ohrbom ,  Robert J. Taylor

Inventor： John W. Rehfuss ,  Walter H. Ohrbom ,  Robert J. Taylor

IPC: C08L61/20 ,  C08G18/10 ,  C08G18/28 ,  C08G18/30 ,  C08G18/80 ,  C08L75/00 ,  C08L75/04 ,  C09D161/20 ,  C09D175/00 ,  C09D175/02 ,  C09D175/04 ,  C09D201/02 ,  C08G18/71

CPC classification number: C09D201/025 ,  C08G18/10 ,  C08G18/2865 ,  C08G18/302 ,  C08G18/8077 ,  C09D161/20 ,  C09D175/02

Abstract: Coating compositions are described comprising:(A) a polyurea reaction product of a mixture comprising:(1) a polyisocyanate, and(2) ammonia, ammonium hydroxide, an aliphatic or cycloaliphatic primary amine, a hydrazide, aziridine, or water, and(B) a compound having a plurality of functional groups that are reactive with urea groups on said polyurea.

Abstract translation: 描述了涂料组合物，其包括：（A）混合物的聚脲反应产物，其包含：（1）多异氰酸酯和（2）氨，氢氧化铵，脂族或脂环族伯胺，酰肼，氮丙啶或水，和 B）具有多个与所述聚脲上的脲基反应的官能团的化合物。

公开(公告)号：US6107418A

公开(公告)日：2000-08-22

申请号：US568071

申请日：1995-12-06

Applicant: Johann Mueller

Inventor： Johann Mueller

IPC: C08J7/04 ,  C08K5/5415 ,  C08K5/5419 ,  C08L83/04 ,  C08L101/02 ,  C09D7/12 ,  C09D143/04 ,  C09D183/04 ,  C09D201/02 ,  C08F283/00

CPC classification number: C08K5/5415 ,  C09D143/04 ,  C09D183/04

Abstract: The invention relates to a composition, to a process for its preparation and to a method of coating shaped articles or elastomeric materials, where the composition can be prepared using(1) polymer components selected from the group consisting of(A1) polyorganosiloxanes comprising units (T units) of the formula (R.sub.1 Si--O.sub.3/2) and optionally, units (M units) of the formula (R.sub.3 Si--O.sub.1/2)(A2) polyorganosiloxanes comprising units (Q units) of the formula (Si--O.sub.4/2) and, optionally, units (M units) of the formula (R.sub.3 Si--O.sub.1/2) in whichR is identical or different and represents unhalogenated or halogenated hydrocarbon radicals having 1 to 18 carbon atom(s) per radical or OR.sup.1, whereR.sup.1 is identical or different and represents hydrogen or a monovalent, unsubstituted or substituted hydrocarbon radical having 1 to 8 carbon atom(s),with the proviso that there are from 0.01% to 3.0% by weight, preferably from 0.01% to 1% by weight, of Si-bonded radicals OR.sup.1(B) vinyl chloride-hydroxypropyl acrylate copolymers,(C) vinyl acetate-ethylene copolymer,(D) polyvinyl chloride,(E) polyamide,(F) polyester,(G) acrylate-polyester copolymers,(H) polyamide-polyester copolymers,(I) vinyl acetate-polyester copolymers, and(J) Monomeric (meth)acrylates, with the proviso that they are copolymerized with Si-bonded (meth)acrylate group-containing silanes,(2) a silane of the formula R.sup.3.sub.x Si(OR.sup.2).sub.4-x, whereR.sup.2 is a monovalent, unsubstituted or substituted hydrocarbon radical,R.sup.3 is a monovalent organic radical,x represents 0 or 1,(3) optionally, a solvent,(4) optionally, a catalyst and(5) optionally, water.

Abstract translation: 本发明涉及一种组合物，其制备方法和涂覆成型制品或弹性体材料的方法，其中组合物可以使用（1）聚合物组分制备，所述组分选自（A1）包含单元的聚有机硅氧烷（ （R1Si-O3 / 2）的单元（M单元）和式（R3Si-O1 / 2）（A2）的单元（M单元）（A2）的聚有机硅氧烷，其包含式（Si-O4 / 2 ）和任选地，其中R相同或不同并且表示每个基团具有1至18个碳原子的不卤代或卤代烃基或OR 1的式（R3Si-O1 / 2）的单元（M单元），其中R1 是相同或不同的，表示氢或具有1至8个碳原子的单价，未取代或取代的烃基，条件是含有0.01重量％至3.0重量％，优选0.01重量％至1重量％ 的Si键合基OR1（B）氯乙烯 - 丙烯酸羟丙酯共聚物 聚合物，（C）乙酸乙烯酯 - 乙烯共聚物，（D）聚氯乙烯，（E）聚酰胺，（F）聚酯，（G）丙烯酸酯 - 聚酯共聚物，（H）聚酰胺 - 聚酯共聚物，（I）乙酸乙烯酯 - 聚酯 共聚物和（J）单体（甲基）丙烯酸酯，条件是它们与含硅键合的（甲基）丙烯酸酯基团的硅烷共聚，（2）式R 3 x Si（OR 2）4-x的硅烷，其中R 2 是单价，未取代或取代的烃基，R 3是一价有机基团，x代表0或1，（3）任选的溶剂，（4）任选的催化剂和（5）任选的水。