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公开(公告)号:US10815438B2
公开(公告)日:2020-10-27
申请号:US16364799
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Maziar Sardashti , Steven E. Lusk , Robert M. Walston
IPC: C10G69/12 , C10G5/06 , C10G11/05 , C07C5/32 , C07C5/333 , C07C5/327 , C07C6/08 , C07C6/12 , C07C6/10 , C07C4/06 , C07C2/42 , C07C2/58 , C07C2/74 , C07C4/10 , C07C4/02 , C07C2/54 , C07C2/56 , C07C9/14 , C07C9/16 , C07C9/15 , C07C9/18 , C07C2/66 , C07C2/64
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an alkylation catalyst to provide enhanced yields of mono-alkylated aromatics that are suitable for use as a blend component of liquid transportation fuels or other value-added chemical products.
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公开(公告)号:US10811121B2
公开(公告)日:2020-10-20
申请号:US15891680
申请日:2018-02-08
Applicant: PHILLIPS 66 COMPANY
Inventor: Alexandru Platon , Edgar Lotero Alegria
Abstract: The present disclosure relates generally to methods and systems for achieving enhanced catalytic performance via the strategic arrangement of multiple catalyst beds in series, where each catalyst bed comprises a compositionally-distinct catalyst, and each catalyst facilitates the conversion of the same structural moieties on the reactant to form the same product. Arranging multiple catalyst beds according to the methods and systems disclosed herein allows a predictable enhancement of conversion of the reactant to product without the need for time-consuming experimentation to test all possible catalysts configurations.
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143.
公开(公告)号:US10804468B2
公开(公告)日:2020-10-13
申请号:US15644230
申请日:2017-07-07
Applicant: PHILLIPS 66 COMPANY
Inventor: Hualong Pan , Kathy Woody , Brian Worfolk , Taeshik Earmme
Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; and wherein the thiophene groups are unsymmetrical.
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公开(公告)号:US10774017B2
公开(公告)日:2020-09-15
申请号:US16364737
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Maziar Sardashti , Steven E. Lusk , Robert M. Walston, Jr.
IPC: C07C5/333 , C10L1/04 , C07C5/32 , C07C2/76 , C10G59/06 , C07C6/10 , C07C6/12 , C07C4/06 , C07C4/10 , C07C4/02 , C07C2/74 , C07C2/54 , C07C2/56 , C07C2/58 , C07C2/42 , C07C9/16 , C07C9/18 , C07C9/14 , C07C9/15
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. The process provides increased yields of upgraded hydrocarbon products that possess the characteristics of a liquid transportation fuel or a blend component thereof.
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公开(公告)号:US10745328B2
公开(公告)日:2020-08-18
申请号:US16364764
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Maziar Sardashti , Steven E. Lusk , Robert M. Walston, Jr.
IPC: C07C5/333 , C10L1/04 , C07C5/32 , C07C2/42 , C10G59/06 , C07C9/14 , C07C6/08 , C07C4/10 , C07C9/16 , C07C9/18 , C07C9/15 , C07C5/327 , C07C6/12 , C07C4/02 , C07C4/06 , C07C6/10 , C07C2/56 , C07C2/58 , C07C2/54 , C07C2/74 , C07C2/08 , C07C2/02 , C07C2/04 , C07C2/06
Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an oligomerization catalyst to provide enhanced yields of aliphatic hydrocarbons that possess the characteristics of a blend component of a liquid transportation fuel or other value-added chemical products.
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公开(公告)号:US20200181511A1
公开(公告)日:2020-06-11
申请号:US16710213
申请日:2019-12-11
Applicant: PHILLIPS 66 COMPANY
Inventor: Xiangxin Yang
Abstract: The invention relates to a catalytic hydrocracker with two different catalyst beds within the reactor where each is loaded with a catalyst that has different hydrocracking properties. A first catalyst bed preferably cracks heavy oil more aggressively than the catalyst in the second bed. The catalytic hydrocracker includes further two recycle lines such that one directs unconverted oil through both hydrocracker beds and a bypass inlet is positioned between the first and second catalyst beds to admit unconverted oil to pass only through the second less aggressive hydrocracker catalyst bed. When gasoline prices favor the production of gasoline, less unconverted oil is recycled through the bypass therefore making more gasoline, but when prices favor the production of jet and diesel, more recycle is directed through the bypass recycle thus making less gasoline and more diesel and jet fuel.
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公开(公告)号:US20200172402A1
公开(公告)日:2020-06-04
申请号:US16209609
申请日:2018-12-04
Applicant: PHILLIPS 66 COMPANY
Inventor: Zhenhua Mao
IPC: C01B32/205 , C01B32/215 , C01B32/23 , H01M4/1393
Abstract: Carbon particles are coated with a water-soluble carbon residue material by oxidizing the carbon residue in water and forming a solid coating on the particles. The coated particles may be heated to graphite forming temperatures to prepare the coated particles for use an anode powder for a battery.
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公开(公告)号:US20200099081A1
公开(公告)日:2020-03-26
申请号:US16578124
申请日:2019-09-20
Applicant: PHILLIPS 66 COMPANY
Inventor: James Anthony Suttil , Hongjin Tan , Neal McDaniel , Sharmila Samaroo , Jeffrey H. Drese
Abstract: A redox flow battery is described that does not include an ion exchange resin such as a proton exchange membrane but rather uses a generally stationary separator liquid that separates the anolyte from the catholyte at immiscible liquid-liquid interfaces. Solvents and electrochemically active components of the anolyte and catholyte would not cross the liquid-liquid interfaces between the separator liquid and the anolyte and catholyte, but certain ions in each of the anolyte and catholyte would cross the interface during charging and discharging of the redox flow battery. The separator liquid comprises a relatively small total volume of liquid in such a flow battery arrangement as compared to the anolyte and catholyte. Suitable chemical options are described along with system options for utilizing immiscible phases.
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公开(公告)号:US10553082B2
公开(公告)日:2020-02-04
申请号:US15078573
申请日:2016-03-23
Applicant: Phillips 66 Company
Inventor: Gary S. Brush
Abstract: The invention relates to blocking fraudulent gathering of credit card and debit card information during a legitimate payment transaction at a credit/debit card reader. The invention includes the installation, preferably in a non-uniform manner, of blockers onto one or more faces or surfaces of the card reader. Properly installed blockers will tend to prevent the easy installation of a flush mounted skimmer device that is designed to overlay the legitimate card reader at a store or point of sale location such as a gasoline pump.
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公开(公告)号:US20190300805A1
公开(公告)日:2019-10-03
申请号:US16364836
申请日:2019-03-26
Applicant: PHILLIPS 66 COMPANY
Inventor: Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Soumen Kundu , Jianhua Yao , Bruce B. Randolph , Mazi Sardashti , Steven E. Lusk , Robert M. Walston
Abstract: The present disclosure relates generally to systems operable to produce liquid transportation fuels by converting a hydrocarbon feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. The system separates the hydrocarbon feed stream to form a first fraction comprising isopentane and smaller hydrocarbons, and a second fraction comprising n-pentane and larger components of the hydrocarbon feeds stream. Each fraction is then catalytically-activated in a separate activation reactor containing a separate activation catalyst, where the conditions maintained in each reactor are selected to maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first activation reactor is maintained at a lower temperature than the second activation reactor. Certain embodiments of the system mix at least a portion of the effluents from the first and second activation reactor and convert the resulting mixed effluent in either an oligomerization reactor containing an oligomerization catalyst or an oligomerization reactor containing an alkylation catalyst to provide enhanced yields of upgraded hydrocarbon products that are characterized as a liquid transportation fuel or a blend component thereof.
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