Imaging member containing heat sensitive thiosulfate polymer and methods
of use
    162.
    发明授权
    Imaging member containing heat sensitive thiosulfate polymer and methods of use 有权
    含有热敏硫代硫酸盐聚合物的成像构件及其使用方法

    公开(公告)号:US5985514A

    公开(公告)日:1999-11-16

    申请号:US156833

    申请日:1998-09-18

    Abstract: An imaging member is composed of a hydrophilic imaging layer having a hydrophilic heat-sensitive polymer containing heat-activatable thiosulfate groups, and optionally a photothermal conversion material. Upon application of energy that generates heat, such as from IR irradiation, the polymer is crosslinked and rendered more hydrophobic. The exposed imaging member can be contacted with a lithographic printing ink and a fountain solution and used for printing with or without post-imaging wet processing. This imaging member is particularly useful for direct write imaging using IR lasers or thermal printing heads.

    Abstract translation: 成像构件由具有亲水性热敏性聚合物的亲水性成像层组成,该亲水性热敏性聚合物含有可热激活的硫代硫酸盐基团,以及任选的光热转化材料。 在施加产生热量的能量(例如从IR照射)时,聚合物交联并变得更疏水。 曝光的成像构件可以与平版印刷油墨和润版液接触,并且用于具有或不具有后成像湿法处理的印刷。 该成像构件对于使用IR激光器或热敏打印头的直接写入成像特别有用。

    Plasticized aqueous coating compositions
    163.
    发明授权
    Plasticized aqueous coating compositions 失效
    增塑水性涂料组合物

    公开(公告)号:US5977228A

    公开(公告)日:1999-11-02

    申请号:US882902

    申请日:1997-06-26

    Applicant: David H. Mauer

    Inventor: David H. Mauer

    CPC classification number: C09G1/16 C09G1/04

    Abstract: This invention provides an aqueous coating composition, more particularly an aqueous floor finish composition, comprising water, at least one polymeric film forming agent, and a plasticizing agent, wherein the improvement comprises at least a portion of the plasticizing agent being at least one tertiary alkyl monocarboxylic acid having an average of from about 6 to 30 carbon atoms per molecule. Such compositions have one or more improved properties such as increased hardness as compared with the same compositions using only conventional plasticizers such as tributoxyethyl phosphate, improved wetting of the substrate by the composition during application, improved coating film leveling, improved multiple coat gloss development, and improved resistance to wear, black heel marking and scuffing.

    Abstract translation: 本发明提供一种水性涂料组合物,更具体地说是含有水,至少一种聚合物成膜剂和增塑剂的水性地板涂料组合物,其中改进包括至少一部分增塑剂是至少一种叔烷基 每分子平均具有约6至30个碳原子的单羧酸。 与仅使用常规增塑剂如磷酸三丁氧基乙酯的相同组合物相比,这样的组合物具有一个或多个改进的性能,例如增加的硬度,通过涂布期间的组合物改善衬底的润湿性,改进的涂膜调平,改进的多涂层光泽显影,以及 改善耐磨性,黑色脚跟标记和磨损。

    Urethane/acrylate bead bond for retroreflective articles
    165.
    发明授权
    Urethane/acrylate bead bond for retroreflective articles 失效
    用于回射制品的聚氨酯/丙烯酸酯珠键

    公开(公告)号:US5959775A

    公开(公告)日:1999-09-28

    申请号:US996950

    申请日:1997-12-23

    Abstract: A retroreflective article utilizing a solventless bead bond composition wherein the bead bond composition includes a urethane/acrylate interpenetrating polymer network in which the urethane polymer is a thermoplastic and the acrylate component is a thermoset. The solventless bead bond is applied as a mixture of diisocyanates, diols, multifunctional acrylates and additives and thermally cured to a rubbery, thermoplastic solid. At this point the bead bond can be softened or molded with the application of heat or stored for a period of time without loss of thermoplasticity. Final retroreflective sheeting constructions which possess superior adhesion to acrylics, toughness and high retroreflectance are achieved by curing the multifunctional acrylates with radiation.

    Abstract translation: 一种使用无溶剂珠粘合组合物的回射制品,其中珠粒粘合组合物包括聚氨酯/丙烯酸酯互穿聚合物网络,其中聚氨酯聚合物是热塑性的,丙烯酸酯组分是热固性的。 无溶剂珠粘合作为二异氰酸酯,二醇,多官能丙烯酸酯和添加剂的混合物施加,并热固化成橡胶状的热塑性固体。 此时,胎圈接合可以通过加热而软化或模制或储存一段时间而不损失热塑性。 通过用辐射固化多官能丙烯酸酯来实现具有优异的丙烯酸粘合性,韧性和高回归率的最终后向反射片材结构。

    Ultraviolet radiation curable compositions
    166.
    发明授权
    Ultraviolet radiation curable compositions 失效
    紫外线辐射固化组合物

    公开(公告)号:US5959020A

    公开(公告)日:1999-09-28

    申请号:US906707

    申请日:1997-08-06

    CPC classification number: C08J3/095 C09D4/06 C08J2391/06

    Abstract: The present invention provides ultraviolet radiation (UV)-curable compositions and a method for making a UV-curable composition comprising: mixing at least one wax, at least one radiation-polymerizable compound, and at least one inhibitor of polymerization; dissolving the wax in the radiation-polymerizable compound by heating to provide a mixture of radiation-polymerizable compound, wax and inhibitor; cooling said mixture to provide a dispersion of the wax in the radiation-polymerizable compound; and micronizing the dispersion to provide a UV-curable composition. The invention further provides a method for coating a substrate with a UV-curable coating, and a coating, paint, varnish or ink comprising a UV-curable composition. Manufactured articles formed using the coatings, paints, varnishes and inks comprising a UV-curable composition are also provided.

    Abstract translation: 本发明提供紫外线辐射(UV)可固化组合物和一种制备紫外光固化组合物的方法,包括:将至少一种蜡,至少一种可辐射聚合的化合物和至少一种聚合抑制剂混合; 通过加热将蜡溶解在可放射线聚合的化合物中,以提供可辐射聚合的化合物,蜡和抑制剂的混合物; 冷却所述混合物以提供蜡在可辐射聚合化合物中的分散体; 并将分散体微粉化以提供可UV固化的组合物。 本发明还提供了一种用UV可固化涂层涂覆基材的方法,以及包含UV可固化组合物的涂料,油漆,清漆或油墨。 还提供了使用包含UV可固化组合物的涂料,油漆,清漆和油墨制成的制品。

    Bifluorophoric perylene colourants
    168.
    发明授权
    Bifluorophoric perylene colourants 失效
    双歧色苝着色剂

    公开(公告)号:US5929239A

    公开(公告)日:1999-07-27

    申请号:US13658

    申请日:1998-01-26

    Abstract: Perylene-3,4:9,10-tetracarboxylic acid imides of the general formula I, including their optical antipodes and their mixtures, in particular their racemates ##STR1## wherein R.sup.1 to R.sup.14 are identical or different and are hydrogen or a radical selected from the group consisting of an unsubstituted or substituted carbocyclic aromatic radical, an unsubstituted or substituted heterocyclic aromatic radical, halogen, unsubstituted or substituted C.sub.1 -C.sub.18 alkyl, --OR.sup.15, --CN, --NR.sup.16 R.sup.17, --COR.sup.18, --NR.sup.19 COR.sup.18, --NR.sup.15 COOR.sup.18, --NR.sup.15 CONR.sup.16 R.sup.17, --NHSO.sub.2 R.sup.18, --SO.sub.2 R.sup.18, --SOR.sup.18, --SO.sub.2 OR.sup.18, --CONR.sup.16 R.sup.17 --N.dbd.NR.sup.20, --OCOR.sup.18 and --OCONHR.sup.18, where pairs of adjacent radicals can form a carbocyclic or heterocyclic ring,wherein R.sup.18 is C.sub.1 14 C.sub.18 alkyl, C.sub.6 -C.sub.10 aryl, or benzyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, or a 5- to 7-membered heterocyclic radical,R.sup.16 and R.sup.17 are each independently of the other hydrogen; C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl,C.sub.6 -C.sub.10 aryl or 5- to 7-membered heteroaryl, each of which is unsubstituted or substituted by cyano groups or hydroxyl groups, or wherein R.sup.16 and R.sup.17, together with at least one of the other radicals R.sup.1 to R.sup.14, are a 5- or 6-membered carbocyclic or heterocyclic ring,R.sup.15 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl, C.sub.6 -C.sub.10 aryl or 5- to 7-membered heteroaryl,R.sup.19 is hydrogen; C.sub.1 -C.sub.18 alkyl, C.sub.3 - to C.sub.24 cycloalkyl, C.sub.1 -C.sub.4 alkylaryl, each of which is unsubstituted or substituted by cyano groups, hydroxyl groups or C.sub.1 -C.sub.4 alkoxycarbonyl groups; C.sub.6 -C.sub.10 -aryl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl groups or by C.sub.1 -C.sub.4 alkoxy groups, or a 5- to 7-membered heterocycle, and R.sup.20 is the radical of a coupling component, or C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl groups or by C.sub.1 -C.sub.4 alkoxy groups, as well as a process for their preparation and use.

    Abstract translation: 包括其通式I的苝-3,4:9,10-四羧酸酰亚胺,包括其光学对映体及其混合物,特别是其外消旋体,其中R 1至R 14相同或不同,为氢或选自 未取代或取代的杂环芳族基团,卤素,未取代或取代的C1-C18烷基,-OR15,-CN,-NR16R17,-COR18,-NR19COR18,-NR15COOR18,-NR15CONR16R17,-NHSO2R18, -SO2R18,-SOR18,-SO2OR18,-CONR16R17-N = NR20,-OCOR18和-OCONHR18,其中相邻基团可以形成碳环或杂环,其中R18是C114 C18烷基,C6-C10芳基或未取代的 或被卤素,C 1 -C 4烷基或C 1 -C 4烷氧基或5至7元杂环基取代,R 16和R 17各自独立地为氢; C 1 -C 18烷基,C 3至C 24环烷基,C 6 -C 10芳基或5-至7-元杂芳基,其各自为未取代的或被氰基或羟基取代,或其中R 16和R 17与至少一个其它基团 R 1至R 14为5或6元碳环或杂环,R 15为氢,C 1 -C 18烷基,C 3至C 24环烷基,C 6 -C 10芳基或5-至7-元杂芳基,R 19为氢; C 1 -C 18烷基,C 3至C 24环烷基,C 1 -C 4烷基芳基,其各自未被取代或被氰基,羟基或C 1 -C 4烷氧基羰基取代; 未被取代或被卤素,C 1 -C 4烷基或C 1 -C 4烷氧基或5-至7-元杂环取代的C 6 -C 10 - 芳基,R 20是偶合组分的基团,或C 6 -C 10芳基 未取代或被卤素,C 1 -C 4烷基或C 1 -C 4烷氧基取代的化合物,以及它们的制备和使用方法。

    Fusible printable coating for durable images
    169.
    发明授权
    Fusible printable coating for durable images 失效
    用于耐用图像的易熔可印刷涂层

    公开(公告)号:US5925712A

    公开(公告)日:1999-07-20

    申请号:US954440

    申请日:1997-10-20

    Abstract: A coating composition which encompasses an aqueous dispersion of from about 2 to about 40 percent by dry weight, based on the dry weight of the coating composition, of a cationic polymer; and from about 60 to about 98 percent by dry weight, based on the dry weight of the coating composition, of a nonionic or cationic binder. The coating composition is thermally fusible and adapted to be receptive to ink jet inks and to retain the ink jet inks after being thermally fused. Alternatively, the coating composition may encompass an aqueous dispersion of a powdered thermoplastic polymer and from about 10 to about 150 dry parts by weight of a binder, based on 100 dry parts by weight of the powdered thermoplastic polymer. Desirably, the coating composition will encompass an aqueous dispersion of a powdered thermoplastic polymer; from about 2 to about 50 dry parts by weight, based on 100 dry parts by weight of the powdered thermoplastic polymer, of a cationic polymer; and from about 10 to about 150 dry parts by weight, based on 100 dry parts by weight of the powdered thermoplastic polymer, of a nonionic or cationic binder. The coating composition also may contain from about 1 to about 5 parts by weight, based on the weight of the coating composition, of a surfactant. When applied to a substrate, the coating composition permits printing on the substrate with ink jet inks to give a printed image which is durable, especially in the presence of water.

    Abstract translation: 一种涂料组合物,其包含基于涂料组合物的干重约2至约40重量%的水分散体阳离子聚合物; 和约60至约98%的干重,基于涂料组合物的干重,非离子或阳离子粘合剂。 涂料组合物是热熔性的并且适于接受喷墨油墨并且在热熔融之后保持喷墨油墨。 或者,涂料组合物可以包含粉末状热塑性聚合物的水分散体和约10至约150干重份的粘合剂,基于100重量份粉末状热塑性聚合物。 期望地,涂料组合物将包括粉末状热塑性聚合物的水分散体; 约2至约50干重份,基于100重量份粉末状热塑性聚合物,阳离子聚合物; 和约10至约150干重份,基于100重量份粉末状热塑性聚合物,非离子或阳离子粘合剂。 涂料组合物还可以含有约1至约5重量份,基于涂料组合物的重量,表面活性剂。 当施加到基底上时,涂料组合物允许用喷墨油墨在基材上印刷,以得到耐久的印刷图像,特别是在水的存在下。

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