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11.
公开(公告)号:US20220153757A1
公开(公告)日:2022-05-19
申请号:US17310622
申请日:2020-03-30
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph M. Falkowski , Carter W. Abney , Mary S. Abdulkarim , Aaron Sattler , Michele Paccagnini , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Crystallization may be problematic in some instances when secondary binding sites are present in the multidentate organic ligand. Multidentate organic ligands comprising first and second binding sites bridged together with a third binding site comprising a diimine moiety may alleviate these issues, particularly when using a preformed metal cluster as a metal source to form a MOF. Such MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. Particular MOFs may comprise N,N′-di(1H-pyrazol-4-yl)ethane-1,2-diimine as a multidentate organic ligand.
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公开(公告)号:US20220145188A1
公开(公告)日:2022-05-12
申请号:US17453191
申请日:2021-11-02
Applicant: ExxonMobil Research and Engineering Company
Inventor: Hyung R. Kim , Jihad M. Dakka , Xiaochun Xu
Abstract: Systems and methods are provided for co-processing of biomass oil in a fluid catalytic cracking (FCC) system that include recovering an additional source of H2 or synthesis gas from the overhead product gas stream. The additional H2 can be used to partially hydrogenate biomass oil prior to co-processing the biomass oil in the fluid catalytic cracking system. Additionally or alternately, the additional synthesis gas can represent an additional yield of products from the process, such as an additional yield that can be used for synthesis of further liquid products.
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公开(公告)号:US20220134317A1
公开(公告)日:2022-05-05
申请号:US17574924
申请日:2022-01-13
Applicant: ExxonMobil Research and Engineering Company
IPC: B01J23/889 , B01J35/04 , B01J37/12 , B01J37/14 , B01J37/16 , C01B3/40 , B01J37/18 , B01J23/888 , B01J29/04
Abstract: Processes for transforming an inert metal component into an active metal catalyst are provided. Apparatus and methods using active metal catalyst prepared according the process described herein are also provided.
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公开(公告)号:US11225611B1
公开(公告)日:2022-01-18
申请号:US16946823
申请日:2020-07-08
Applicant: ExxonMobil Research and Engineering Company
Inventor: Chengrong Wang , Anding Zhang , Xiaochun Xu , Samuel J. Cady , Shifang Luo , Michael H. Ring , Maria Vanessa C. Aguinaldo , John Della Mora , Kegun L. Ream
Abstract: Disclose is an online analyzer to monitor conversion of a biofeedstock in a first hydrotreating stage to avoid catalyst poisoning in a subsequent stage. An example method of processing a biofeedstock may comprise hydrotreating the biofeedstock by reaction with hydrogen to form a hydrotreated biofeedstock. The method may further comprise monitoring conversion of the biofeedstock in the hydrotreating with an online analyzer.
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公开(公告)号:US20220010230A1
公开(公告)日:2022-01-13
申请号:US17341816
申请日:2021-06-08
Applicant: ExxonMobil Research and Engineering Company
Inventor: Haris Junuzovic , Douglas E. Deckman , Benjamin D. Eirich
IPC: C10M145/28 , C10M169/04 , C10M129/74
Abstract: Provided is an engine oil lubricant composition with improved fuel efficiency and engine wear protection. The lubricant composition may include a major amount of an oil basestock from any one or more Group I, Group II, Group III, Group IV or Group V base oils. The resulting engine oil lubricant composition may have a kinematic viscosity at 100° C. of 6 cSt or less, and a corrosion protection of at least 90, as measured according the ASTM D6557 Ball Rust Test. The resulting engine oil lubricant composition may also have a kinematic viscosity at 100° C. of 6 cSt or less, an HTHS (ASTM D4683) of less than or equal to 2.2 cP at 150° C. and a FZG failure load stage of at least 6, as measured by the FZG A10/16.6R/130 test procedure.
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公开(公告)号:US11211621B2
公开(公告)日:2021-12-28
申请号:US16695335
申请日:2019-11-26
Inventor: Timothy A. Barckholtz , Jonathan Rosen , Carla S. Pereira , Rodrigo F. Blanco Gutierrez , Frank Hershkowitz , Carl A. Willman , Timothy C. Geary
IPC: H01M8/04537 , H01M8/0438 , H01M8/14
Abstract: Systems and methods are provided for operating molten carbonate fuel cells to allow for periodic regeneration of the fuel cells while performing elevated CO2 capture. In some aspects, periodic regeneration can be achieved by shifting the location within the fuel cells where the highest density of alternative ion transport is occurring. Such a shift can result in a new location having a highest density of alternative ion transport, while the previous location can primarily transport carbonate ions. Additionally or alternately, periodic regeneration can be performed by modifying the input flows to the fuel cell and/or relaxing the operating conditions of the fuel cell to reduce or minimize the amount of alternative ion transport.
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公开(公告)号:US11207651B2
公开(公告)日:2021-12-28
申请号:US16909970
申请日:2020-06-23
Applicant: ExxonMobil Research and Engineering Company
Inventor: Anjaneya S. Kovvali , Michael F. Raterman , Arsam Behkish
Abstract: A moving bed reactor is provided that can allow facilitate performing a reaction involving a three-phase flow under co-axial flow conditions for the solid and liquid portions of the three phase flow, while the gas portion of the three-phase flow is exposed to the solids under radial flow conditions. Methods for using such a moving bed reactor to perform a reaction, such as upgrading of a feed to distillate products, are also provided.
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公开(公告)号:US20210383160A1
公开(公告)日:2021-12-09
申请号:US17287821
申请日:2019-11-15
Applicant: ExxonMobil Research and Engineering Company
Inventor: Christopher J. Vander Neut , Matthew L. Dinslage , Thomas A. Schiff
Abstract: Aspects of the technology described herein describe a system for detecting and reducing wear in industrial equipment. Aspects of the technology use 3D image data from a field inspection of industrial equipment to identify and quantify wear. The wear can be detected by providing the images from the field inspection to a computer classifier for recognition. Aspects of the technology also use machine learning to recommend a change to the operation of the equipment to minimize wear. Such a change could include load shedding, lube oil feed rate changes, prompts for maintenance, etc. Through incorporation of the wear data into the control system, the equipment can automatically change operation to improve wear performance and increase the durability and lifetime of the equipment.
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公开(公告)号:US11186788B2
公开(公告)日:2021-11-30
申请号:US16448117
申请日:2019-06-21
Applicant: ExxonMobil Research and Engineering Company
Inventor: Benjamin A. McCool , Yogesh V. Joshi , Dhaval A. Bhandari , Roberto Garcia , Randall D. Partridge
Abstract: Disclosed are methods and apparatuses for separating a wax product from a hydrocarbon feedstream by a) conducting a hydrocarbon feedstream to a membrane separation zone; b) retrieving at least one retentate product stream from the first side of the membrane element; c) retrieving at least one permeate product stream having a wax phase and an oil phase from a second side of the membrane element, wherein a pour point of the wax phase of the permeate product stream is higher than a pour point of the oil phase of permeate product stream; and d) separating a wax product from the wax phase of the permeate product stream.
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公开(公告)号:US20210363449A1
公开(公告)日:2021-11-25
申请号:US17325944
申请日:2021-05-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Sheryl B. Rubin-Pitel , Timothy J. Anderson , Kenneth C.H. Kar , Marcia E. Dierolf , Shifang Luo , Ian J. Laurenzi , Xinrui Yu , Yi Xu
Abstract: Distillate boiling range and/or diesel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. This unexpected combination of properties is characteristic of crude oils that can be fractionated to form distillate/diesel boiling range compositions that can be used as fuels/fuel blending products with reduced or minimized processing. The resulting distillate boiling range fractions and/or diesel boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight and/or volume ratio, a low but substantial aromatics content, and a low sulfur content. By reducing, minimizing, or avoiding the amount of hydroprocessing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.
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