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    METHOD FOR CONVERTING CARBOXYLIC ACIDS AND ESTERS INTO BASE OIL HYDROCARBONS
    14.
    发明申请
    METHOD FOR CONVERTING CARBOXYLIC ACIDS AND ESTERS INTO BASE OIL HYDROCARBONS 有权

    公开(公告)号：US20210139787A1

    公开(公告)日：2021-05-13

    申请号：US16623210

    申请日：2018-06-15

    Applicant: Neste Oyj

    Inventor： Jukka MYLLYOJA ,  Mika KETTUNEN ,  Rami PIILOLA

    IPC: C10G3/00 ,  B01J21/06

    Abstract: A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.

    METHOD FOR CATALYTIC CONVERSION OF KETOACIDS AND HYDROTREAMENT TO HYDROCARBONS
    18.
    发明申请
    METHOD FOR CATALYTIC CONVERSION OF KETOACIDS AND HYDROTREAMENT TO HYDROCARBONS 审中-公开
    酮酸乙酯和水合物的催化转化方法

    公开(公告)号：US20170073294A1

    公开(公告)日：2017-03-16

    申请号：US15276065

    申请日：2016-09-26

    Applicant: NESTE OYJ

    Inventor： Jukka MYLLYOJA ,  Rami PIILOLA

    IPC: C07C51/353 ,  C10L1/04 ,  B01J23/883 ,  B01J21/04 ,  B01J23/04 ,  C10G3/00 ,  B01J21/06

    Abstract: The present disclosure relates to catalytic conversion of ketoacids, including methods for increasing the molecular weight of ketoacids, the method including the steps of providing in a reactor a feedstock comprising at least one ketoacid. The feedstock is then subjected to one or more C—C-coupling reaction(s) in the presence of hydrogen, and in the presence of a catalyst system having both hydrogenation activity and C—C-coupling activity.

    Abstract translation: 本公开涉及酮酸的催化转化，包括增加酮酸的分子量的方法，所述方法包括以下步骤：在反应器中提供包含至少一种酮酸的原料。 然后在氢存在下，在具有氢化活性和C-C偶联活性的催化剂体系的存在下，将原料进行一种或多种C-C偶联反应。

    RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
    19.
    发明申请
    RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS 有权

    公开(公告)号：US20220340835A1

    公开(公告)日：2022-10-27

    申请号：US17762894

    申请日：2020-09-25

    Applicant: Neste Oyj

    Inventor： Jukka MYLLYOJA ,  Jukka HIETALA

    IPC: C10M177/00 ,  C10M105/04 ,  C10M107/10 ,  C07C67/333 ,  C07C67/03 ,  C07C6/04 ,  C07C45/45 ,  C10G3/00

    Abstract: A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.

    METHOD FOR PRODUCING RENEWABLE BASE OIL AND RENEWABLE FUEL COMPONENTS
    20.
    发明申请
    METHOD FOR PRODUCING RENEWABLE BASE OIL AND RENEWABLE FUEL COMPONENTS 有权

    公开(公告)号：US20220081626A1

    公开(公告)日：2022-03-17

    申请号：US17419958

    申请日：2019-12-20

    Applicant: Neste Oyj

    Inventor： Jukka MYLLYOJA ,  Jaana KANERVO ,  Jaana MAKKONEN ,  Marja TIITTA

    IPC: C10G45/02 ,  C10G3/00

    Abstract: The present disclosure relates to methods for producing renewable base oil and other valuable renewable fuel components from a feedstock of biological origin comprising free fatty acids and glycerides. The feedstock is first separated to two or more effluent streams containing a fatty acid fraction and glyceride fraction. The glycerides are hydrolyzed to free fatty acids and glycerol, and the fatty acids thus obtained are recycled to the separating. The fatty acids are then converted to the base oil by ketonisation, hydrodeoxygenation and hydroisomerisation. The glycerol is converted to propanols by selective hydrogenolysis.

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