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    ETHANE OXIDATIVE DEHYDROGENATION
    13.
    发明申请
    ETHANE OXIDATIVE DEHYDROGENATION 审中-公开

    公开(公告)号：US20200223768A1

    公开(公告)日：2020-07-16

    申请号：US16638944

    申请日：2018-08-02

    Applicant: SHELL OIL COMPANY

    Inventor： Guus VAN ROSSUM ,  Ronald Jan SCHOONEBEEK ,  Laura Mariel CALVO ,  Ivana Daniela ESPOSITO CASSIBBA ,  Georgios MITKIDIS ,  Pejman PAJAND ,  Maria SAN ROMAN MACIA ,  Peter Anton August KLUSENER

    IPC: C07C5/48

    Abstract: The invention relates to a process for oxidative dehydrogenation of ethane, comprising the steps of: (a) subjecting a stream comprising ethane to oxidative dehydrogenation conditions; (b) removing water from at least part of the effluent resulting from step (a); (c) optionally removing unconverted oxygen and/or carbon monoxide and/or ycetylene from at least part of the stream comprising ethylene, unconverted ethane, carbon dioxide, optionally unconverted oxygen, optionally carbon monoxide and optionally acetylene resulting from step (b); (d) removing ethylene from at least part of the stream comprising ethylene, unconverted ethane and carbon dioxide resulting from step (b) or (c) by a complexation separation method; (e) partially and selectively removing carbon dioxide from at least part of the stream comprising unconverted ethane and carbon dioxide resulting from step (d); (f) recycling at least part of the stream comprising unconverted ethane and carbon dioxide resulting from step (e) to step (a).

    OXIDATIVE DEHYDROGENATION (ODH) OF ETHANE
    14.
    发明申请
    OXIDATIVE DEHYDROGENATION (ODH) OF ETHANE 审中-公开

    公开(公告)号：US20190248716A1

    公开(公告)日：2019-08-15

    申请号：US16319933

    申请日：2017-07-24

    Applicant: SHELL OIL COMPANY

    Inventor： Ronald Jan SCHOONEBEEK ,  Guss VAN ROSSUM ,  Alouisius Nicolaas Renée BOS

    IPC: C07C5/48 ,  B01J8/06

    Abstract: Processes and associated reaction systems for the oxidative dehydrogenation of ethane are provided. In particular, a process is provided that comprises supplying a feed gas comprising ethane and oxygen to a multitubular fixed-bed reactor, allowing the ethane and oxygen to react in the presence of an oxidative dehydrogenation catalyst to yield a reactor effluent comprising ethylene; supplying a coolant to an upstream region of an interior shell space of the reactor in a flow pattern that is counter-current with the flow of the feed gas; and withdrawing the coolant from the upstream region and supplying at least a portion of the coolant withdrawn from the upstream region to the downstream region in a flow pattern that is co-current with the flow of the feed gas.

    PROCESS FOR THE PRODUCTION OF ETHYLENE OXIDE
    18.
    发明申请
    PROCESS FOR THE PRODUCTION OF ETHYLENE OXIDE 有权

    公开(公告)号：US20210130309A1

    公开(公告)日：2021-05-06

    申请号：US17045807

    申请日：2019-04-04

    Applicant: SHELL OIL COMPANY

    Inventor： Guus VAN ROSSUM ,  Ivana Daniela ESPOSITO CASSIBBA ,  Ronald Jan SCHOONEBEEK ,  Alouisius Nicolaas Renée BOS ,  Peter Alexander SCHUT ,  Laura Mariel CALVO

    IPC: C07D301/06 ,  C07C5/48 ,  C07C29/10

    Abstract: The invention relates to a Process for the production of ethylene oxide, comprising the steps of: (a) producing ethylene by subjecting a stream comprising ethane to oxidative dehydrogenation conditions, resulting in a stream comprising ethylene, ethane, water and acetic acid; (b) separating at least part of the stream resulting from step (a) into a stream comprising ethylene and ethane and a stream comprising water and acetic acid; (c) producing ethylene oxide by subjecting ethylene and ethane from the stream comprising ethylene and ethane resulting from step (b) to oxidation conditions, resulting in a stream comprising ethylene oxide, ethylene, ethane and water; (d) separating at least part of the stream resulting from step (c) into a stream comprising ethylene and ethane and a stream comprising ethylene oxide and water; (e) recycling ethylene and ethane from the stream comprising ethylene and ethane resulting from step (d) to step (a), wherein carbon dioxide is produced in steps (a) and (c) and is removed in an additional step between steps (b) and (c) and/or between steps (d) and (e).

    ETHANE OXIDATIVE DEHYDROGENATION
    19.
    发明申请
    ETHANE OXIDATIVE DEHYDROGENATION 审中-公开

    公开(公告)号：US20200223769A1

    公开(公告)日：2020-07-16

    申请号：US16638955

    申请日：2018-08-02

    Applicant: SHELL OIL COMPANY

    Inventor： Laura Mariel CALVO ,  Ivana Daniela ESPOSITO CASSIBBA ,  Georgios MITKIDIS ,  Pejman PAJAND ,  Guus VAN ROSSUM ,  Maria SAN ROMAN MACIA ,  Ronald Jan SCHOONEBEEK ,  Peter Anton August KLUSENER

    IPC: C07C5/48

    Abstract: The invention relates to a process for oxidative dehydrogenation of ethane, comprising the steps of: (a) subjecting a stream comprising ethane to oxidative dehydrogenation conditions; (b) removing water from at least part of the effluent resulting from step (a); (c) optionally removing unconverted oxygen and/or carbon monoxide and/or acetylene from at least part of the stream comprising ethylene, unconverted ethane, carbon dioxide, optionally unconverted oxygen, optionally carbon monoxide and optionally acetylene resulting from step (b); (d) removing ethylene from at least part of the stream comprising ethylene, unconverted ethane and carbon dioxide resulting from step (b) or (c) by a complexation separation method; (e) partially and selectively removing carbon dioxide from at least part of the stream comprising unconverted ethane and carbon dioxide resulting from step (d); (f) recycling at least part of the stream comprising unconverted ethane and carbon dioxided resulting from step (e) to step (a).

    GAS CLEAN-UP FOR ALKANE OXIDATIVE DEHYDROGENATION EFFLUENT
    20.
    发明申请
    GAS CLEAN-UP FOR ALKANE OXIDATIVE DEHYDROGENATION EFFLUENT 审中-公开

    公开(公告)号：US20200002251A1

    公开(公告)日：2020-01-02

    申请号：US16486535

    申请日：2018-02-20

    Applicant: SHELL OIL COMPANY

    Inventor： Georgios MITKIDIS ,  Guus VAN ROSSUM ,  Maria SAN ROMAN MACIA ,  Ronald Jan SCHOONEBEEK ,  Michael Johannes Franciscus Maria VERHAAK

    IPC: C07C5/48 ,  B01J23/80 ,  B01J23/00 ,  B01J35/02 ,  B01J35/00

    Abstract: The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane in and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a).

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