公开(公告)号：US20160346815A1

公开(公告)日：2016-12-01

申请号：US14723130

申请日：2015-05-27

Applicant: Chevron U.S.A. Inc.

Inventor： Jeff Jeff Johns ,  Steven Alden Souers ,  Douglas Gayle McDaniel ,  David Lawrence Cooke ,  David Michael Bosi

IPC: B08B9/08 ,  B08B5/04 ,  B01J38/10

CPC classification number: B08B9/08 ,  B01J8/003 ,  B01J8/0035 ,  B01J8/0285 ,  B01J19/0013 ,  B01J38/10 ,  B01J2208/00256 ,  B01J2208/00761 ,  B01J2208/00769 ,  B08B5/04 ,  B08B9/093 ,  B08B9/283 ,  B08B9/34 ,  C10G49/00 ,  C10G2300/4031 ,  C10G2300/701

Abstract: Processes for shutting down a hydroprocessing reactor and for removing catalyst from the reactor may comprise shutting off hydrocarbon feed to the reactor, stripping hydrocarbons from the catalyst, cooling the reactor to a first threshold reactor temperature, purging the reactor with N2 gas, introducing water into the reactor, and dumping the catalyst from the reactor, wherein the first threshold reactor temperature may be substantially greater than 200° F. In an embodiment, the water may be introduced into the reactor via a quench gas distribution system when the reactor is at a second threshold reactor temperature not greater than 200° F. to cool the reactor to a third threshold reactor temperature not greater than 120° F.

Abstract translation: 关闭加氢处理反应器和从反应器中除去催化剂的方法可包括：将烃进料切断至反应器，从催化剂中汽提烃，将反应器冷却至第一阈值反应器温度，用N 2气体吹扫反应器，将水引入 反应器和从反应器中倾倒催化剂，其中第一阈值反应器温度可以基本上大于200°F。在一个实施方案中，当反应器处于一个或多个反应器时，可以通过骤冷气体分配系统将水引入反应器 第二阈值反应器温度不大于200°F，以将反应器冷却至不大于120°F的第三阈值反应器温度。

公开(公告)号：US09492813B2

公开(公告)日：2016-11-15

申请号：US13958243

申请日：2013-08-02

Applicant: LG CHEM, LTD.

Inventor： Dae Chul Kim ,  Sung Shik Eom ,  Dong-Hyun Ko ,  Moo Ho Hong ,  O Hak Kwon

IPC: B01J23/96 ,  B01J23/94 ,  B01J38/10 ,  B01J23/46 ,  B01J23/755 ,  C10G3/00

CPC classification number: B01J23/96 ,  B01J23/464 ,  B01J23/755 ,  B01J23/94 ,  B01J38/10 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G3/62 ,  Y02P30/20

Abstract: Disclosed is a method for regenerating a hydrogenation catalyst. More specifically, disclosed is a method for regenerating a hydrogenation catalyst poisoned during hydrogenation of a hydroformylation product for preparation of alcohol by stopping hydrogenation in a hydrogenation stationary phase reactor in which the hydrogenation catalyst is set and flowing hydrogen gas under a high temperature normal pressure. The method has an effect in that the poisoned hydrogenation catalyst can be efficiently recovered through a simple process.

Abstract translation: 公开了一种再生氢化催化剂的方法。 更具体地说，公开了一种氢化催化剂的再生方法，该加氢催化剂在加氢甲酰化产物的氢化过程中，通过在加氢氢化催化剂设定并在高温常压下流动氢气的氢化固定相反应器停止氢化而制备醇。 该方法具有通过简单的方法有效地回收有毒氢化催化剂的作用。

公开(公告)号：US20160289141A1

公开(公告)日：2016-10-06

申请号：US15038205

申请日：2014-11-20

Applicant: BASF SE

Inventor： Kati BACHMANN ,  Friedrich GLENK ,  Grigorios KOLIOS

IPC: C07C2/76 ,  C01B3/38 ,  B01J7/00 ,  B01J19/00 ,  B01J29/48 ,  B01J23/62 ,  B01J21/04 ,  B01J21/06 ,  B01J23/26 ,  B01J23/08 ,  B01J29/18 ,  B01J29/70 ,  B01J29/85 ,  B01J27/232 ,  B01J23/745 ,  B01J23/755 ,  B01J23/02 ,  B01J23/00 ,  C07C5/333 ,  C07C5/03 ,  C07C5/10 ,  C01B3/40

CPC classification number: C07C2/76 ,  B01J7/00 ,  B01J8/062 ,  B01J8/065 ,  B01J8/1809 ,  B01J8/1827 ,  B01J8/1836 ,  B01J8/1872 ,  B01J8/26 ,  B01J19/0046 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/005 ,  B01J23/02 ,  B01J23/08 ,  B01J23/26 ,  B01J23/626 ,  B01J23/745 ,  B01J23/755 ,  B01J27/232 ,  B01J29/18 ,  B01J29/48 ,  B01J29/70 ,  B01J29/85 ,  B01J29/90 ,  B01J38/10 ,  B01J2208/00238 ,  B01J2208/00504 ,  B01J2208/00557 ,  B01J2208/06 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/00594 ,  B01J2219/0072 ,  B01J2219/00756 ,  B01J2219/185 ,  C01B3/384 ,  C01B3/40 ,  C01B3/44 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0833 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/141 ,  C07C5/03 ,  C07C5/10 ,  C07C5/3332 ,  C07C5/35 ,  C07C5/367 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2523/86 ,  C07C2529/18 ,  C07C2529/46 ,  C07C2529/48 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/04 ,  C07C15/46 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/22

Abstract: The present invention relates to a method for carrying out endothermic reactions comprising the method steps of:a) externally heating at least two reaction tubes (5), wherein the reaction tubes (5) have been arranged vertically in a heating chamber (3) and each of the reaction tubes (5) has been at least partially packed with a fluidizable material,b) introducing at least one gaseous reactant (R) into the reaction tubes (5),c) forming a fluidized bed (7) in the reaction tubes (5), d) carrying out the endothermic reaction in the reaction tubes (5) at a first temperature (T1) and a first pressure (P1), wherein the reaction volume has been distributed over at least two of the reaction tubes (5), and e) discharging the reaction product (P) from the reaction tubes (5).The present invention further relates to an apparatus (1) for carrying out endothermic reactions comprising at least one heating chamber (3), at least two reaction tubes (5), wherein the reaction tubes (5) have been arranged vertically in the heating chamber (3) and each of the reaction tubes (5) comprises an at least partial packing of a fluidizable material, at least one entry point (9) for gaseous reactants (R) for each reaction tube (5), at least one exit point (11) for reaction products (P) for each reaction tube (5) and at least one heating apparatus (13) for externally heating the reaction tubes (5).The present invention further provides for the use of the apparatus (1) according to the invention for the non-oxidative dehydroaromatization of C1 to C4 aliphatics.

Abstract translation: 本发明还提供了根据本发明的装置（1）用于C1至C4脂族体的非氧化脱氢芳化作用的用途。

公开(公告)号：US09446399B2

公开(公告)日：2016-09-20

申请号：US14522946

申请日：2014-10-24

Applicant: UOP LLC

Inventor： Daniel N. Myers ,  Paolo Palmas ,  David N. Myers

IPC: B01J38/12 ,  B01J29/80 ,  B01J29/90 ,  B01J38/02 ,  B01J38/10 ,  B01J38/72 ,  C10G11/05 ,  C10G11/18

CPC classification number: B01J38/12 ,  B01J29/80 ,  B01J29/90 ,  B01J38/02 ,  B01J38/10 ,  B01J38/72 ,  C10G11/05 ,  C10G11/182 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/70

Abstract: One exemplary embodiment can be a process for regenerating catalyst in a fluid catalytic cracking unit. Generally, the process includes providing a feed to a riser of a reaction vessel, and providing a stream to a distributor positioned within a void proximate to an inlet receiving unregenerated catalyst in a regenerator. The feed can include at least one of a gas oil, a vacuum gas oil, an atmospheric gas oil, a coker gas oil, a hydrotreated gas oil, a hydrocracker unconverted oil, and an atmospheric residue.

公开(公告)号：US20150182956A1

公开(公告)日：2015-07-02

申请号：US14415960

申请日：2013-07-23

Applicant: BADGER LICENSING LLC

Inventor： Ronald Birkhoff ,  Shyh-Yuan H. Hwang

IPC: B01J29/90 ,  C07C37/08 ,  C07C407/00 ,  B01J38/10 ,  C07C29/145 ,  B01J29/70 ,  B01J38/04 ,  C07C2/86 ,  C07C45/00

CPC classification number: B01J29/90 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/703 ,  B01J29/7034 ,  B01J29/7038 ,  B01J29/7042 ,  B01J29/7046 ,  B01J38/04 ,  B01J38/10 ,  C07C2/864 ,  C07C29/145 ,  C07C37/08 ,  C07C45/00 ,  C07C407/00 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/085

Abstract: In a process for producing cumene, benzene and a C3 alkylating agent comprising isopropanol are supplied to an alkylation zone comprising a molecular sieve alkylation catalyst under alkylation conditions such that the isopropanol reacts with the benzene to produce a reaction product comprising cumene. Subsequently, the supply of benzene and C3 alkylating agent to the alkylation zone is ceased and a gaseous stripping agent is supplied to the molecular sieve alkylation catalyst under conditions effective to remove nitrogenous impurities deposited on the catalyst during the preceding alkylation reaction. The supply of benzene and C3 alkylating agent to the alkylation zone is then reinitiated.

Abstract translation: 在生产异丙基苯的方法中，将苯和含有异丙醇的C3烷基化剂在烷基化条件下供给到包含分子筛烷基化催化剂的烷基化区，使得异丙醇与苯反应产生包含枯烯的反应产物。 随后，在烷基化反应期间，停止向烷基化区供应苯和C3烷基化剂，并在有效去除沉积在催化剂上的含氮杂质的条件下，向分子筛烷基化催化剂提供气态汽提剂。 然后重新开始向烷基化区供应苯和C3烷基化剂。

公开(公告)号：US08999250B2

公开(公告)日：2015-04-07

申请号：US14465110

申请日：2014-08-21

Applicant: UOP LLC

Inventor： Charles L. Hemler, Jr.

IPC: F27B15/08 ,  B01J29/90 ,  B01J8/08

CPC classification number: B01J29/90 ,  B01J8/003 ,  B01J8/0055 ,  B01J8/08 ,  B01J8/1845 ,  B01J8/26 ,  B01J38/10 ,  B01J38/12 ,  B01J2208/00752 ,  B01J2208/0084 ,  B01J2208/00849 ,  B01J2208/025

Abstract: One exemplary embodiment can be a process for mixing catalyst in a regenerator. The process can include providing a first stream of catalyst, a second stream of catalyst mixed with the first stream of catalyst, and an oxygen-containing gas to a chamber via a distributor of the regenerator. Generally, the chamber imparts a swirl to at least one of the oxygen-containing gas, the first catalyst, and the second catalyst for regenerating the catalyst.

Abstract translation: 一个示例性实施方案可以是在再生器中混合催化剂的方法。 该方法可以包括提供第一催化剂流，与第一催化剂流混合的第二催化剂流，以及通过再生器的分配器向室内提供含氧气体。 通常，室向至少一种含氧气体，第一催化剂和第二催化剂施加涡流以再生催化剂。

公开(公告)号：US20140213839A1

公开(公告)日：2014-07-31

申请号：US14230373

申请日：2014-03-31

Applicant: Chevron Phillips Chemical Company LP

Inventor： An-Hsiang Wu

IPC: B01J29/90 ,  C07C5/32 ,  C07C5/367

CPC classification number: B01J29/90 ,  B01J23/42 ,  B01J23/96 ,  B01J29/126 ,  B01J29/22 ,  B01J29/62 ,  B01J29/7415 ,  B01J37/18 ,  B01J37/24 ,  B01J37/26 ,  B01J38/10 ,  B01J38/12 ,  B01J38/42 ,  B01J38/46 ,  C07C5/325 ,  C07C5/367 ,  C10G11/05 ,  C10G35/085

Abstract: Methods for treating or rejuvenating a spent catalyst are disclosed. Such methods can employ a step of halogenating the spent catalyst, followed by decoking the halogenated spent catalyst.

Abstract translation: 公开了用于处理或再生废催化剂的方法。 这样的方法可以采用卤​​化废催化剂的步骤，然后除去卤化的废催化剂。

公开(公告)号：US08790579B2

公开(公告)日：2014-07-29

申请号：US13710903

申请日：2012-12-11

Applicant: Chevron Phillips Chemical Company LP

Inventor： Elizabeth A. Benham ,  Max P. McDaniel ,  Ted H. Cymbaluk ,  Charles K. Newsome ,  Charles R. Nease ,  H. Kenneth Staffin ,  Thomas R. Parr

IPC: B01J19/00 ,  G05D23/00 ,  G05D7/00 ,  B01J8/18 ,  F27B15/00 ,  B01J8/02 ,  B01J35/02 ,  G05D21/00 ,  C08F2/00 ,  C08F4/00 ,  B01J23/00 ,  B01J23/90

CPC classification number: B01J19/0033 ,  B01J8/006 ,  B01J8/26 ,  B01J8/36 ,  B01J23/26 ,  B01J23/92 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/08 ,  B01J37/16 ,  B01J38/10 ,  B01J38/30 ,  B01J2208/0084 ,  C08F10/00 ,  C08F210/16 ,  Y02P20/584 ,  C08F210/14 ,  C08F2500/12 ,  C08F4/24

Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.

Abstract translation: 提供了制备催化剂如铬催化剂的方法和系统。 送到活化剂的催化剂的至少一部分的化合价从Cr（III）变为Cr（VI）。 使用流化床催化剂活化剂连续制备或活化催化剂。

公开(公告)号：US20130331628A1

公开(公告)日：2013-12-12

申请号：US13964813

申请日：2013-08-12

Applicant: FINA TECHNOLOGY, INC.

Inventor： James Butler ,  Olga Khabashesku ,  Darek Wachowicz ,  Callum Bailey

IPC: C07C6/06

CPC classification number: B01J29/85 ,  B01J29/076 ,  B01J29/16 ,  B01J29/26 ,  B01J29/83 ,  B01J29/90 ,  B01J37/0203 ,  B01J38/10 ,  B01J38/12 ,  B01J38/14 ,  B01J2229/20 ,  C07C6/06 ,  C07C6/12 ,  C07C2523/20 ,  C07C2523/36 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/18 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P20/588 ,  C07C15/04 ,  C07C15/08

Abstract: A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %.

Abstract translation: V族金属/铼改性分子筛催化剂可用于烃转化反应。 实施方案可以提供至少30重量％的甲苯转化率，对苯高于40重量％的选择性和高于40重量％的二甲苯和小于2.0重量％的非芳族选择性。

公开(公告)号：US08557725B2

公开(公告)日：2013-10-15

申请号：US13581948

申请日：2011-02-14

Applicant: Hideki Ono ,  Yoshiyuki Nagayasu ,  Kazuaki Hayasaka

Inventor： Hideki Ono ,  Yoshiyuki Nagayasu ,  Kazuaki Hayasaka

IPC: B01J20/34 ,  C07C27/00

CPC classification number: B01J37/18 ,  B01J23/462 ,  B01J23/75 ,  B01J23/8913 ,  B01J23/94 ,  B01J23/96 ,  B01J35/1061 ,  B01J37/10 ,  B01J38/02 ,  B01J38/06 ,  B01J38/10 ,  C10G2/332 ,  C10G2/333

Abstract: A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.

Abstract translation: 一种生产通过再生费 - 托合成反应中使用的废催化剂而获得的再生费 - 托合成催化剂的方法，包括使上述废催化剂与含有1〜30体积％ 蒸汽和惰性气体，在大气压至5MPa的压力和150至350℃的温度下，上述废催化剂是废催化剂，其中钴和/或钌负载在包含二氧化硅的载体上，平均 基于相应的未使用的催化剂的活性，通过4〜25nm的氮吸附法测定的孔径，其初始一氧化碳转化率表示的活性为40〜95％。