ANALYTICAL METHOD FOR DETECTING FUEL MARKERS
    11.
    发明申请
    ANALYTICAL METHOD FOR DETECTING FUEL MARKERS 有权
    用于检测燃油标记的分析方法

    公开(公告)号:US20160077066A1

    公开(公告)日:2016-03-17

    申请号:US14787520

    申请日:2014-05-02

    Abstract: A gas chromatographic method for detecting a marker compound in a fuel by (a) introducing a sample of fuel into a first capillary column coated with a stationary phase based on polydimethylsiloxane and allowing the sample to flow through the first column to produce a first effluent; (b) allowing the first effluent to pass through a detector and identifying a retention time range in it which includes a retention time of the marker compound; (c) introducing only a portion of the first effluent stream which is within the retention time range into a second capillary column coated with either (i) an ionic sorbent or (ii) a polyethylene glycol, and allowing said portion to flow through the second capillary column to produce a second effluent stream; and (d) allowing the second effluent to pass through a detector; wherein the marker compound has formula Ar(R2)m(OR1)n and is present in the fuel at a level from 0.01 ppm to 100 ppm.

    Abstract translation: 一种用于通过以下步骤来检测燃料中的标记化合物的气相色谱方法:(a)基于聚二甲基硅氧烷将样品引入到具有固定相的第一毛细管柱中并使样品流过第一塔以产生第一流出物; (b)允许第一流出物通过检测器并鉴定其中包含标记化合物的保留时间的保留时间范围; (c)将仅在保留时间范围内的第一流出物流的一部分引入涂覆有(i)离子吸附剂或(ii)聚乙二醇的第二毛细管柱中,并允许所述部分流过第二流出物流 毛细管柱以产生第二流出物流; 和(d)允许第二流出物通过检测器; 其中标记化合物具有式Ar(R 2)m(OR 1)n,并且以0.01ppm至100ppm的水平存在于燃料中。

    DISTILLABLE FUEL MARKERS
    13.
    发明申请
    DISTILLABLE FUEL MARKERS 有权
    可燃燃料标志

    公开(公告)号:US20150307795A1

    公开(公告)日:2015-10-29

    申请号:US14441202

    申请日:2013-11-05

    Abstract: A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel by adding to the petroleum hydrocarbon or liquid biologically derived fuel at least one compound having formula Ar(R2)m(OR1)n, wherein Ar is an aromatic ring system having from six to twenty carbon atoms, R1 is C1-C12 alkyl or C2-C12 alkenyl, R2 is C1-C12 alkyl or C3-C12 alkenyl, m is an integer from zero to five and n is an integer from one to three; wherein each compound of formula Ar(R2)m(OR1)n is present at a level from 0.01 ppm to 100 ppm.

    Abstract translation: 一种通过向石油烃或液体生物衍生的燃料中加入至少一种具有式Ar(R 2)m(OR 1)n的化合物来标记石油烃或液体生物衍生的燃料的方法,其中Ar是具有6个 至20个碳原子,R 1为C 1 -C 12烷基或C 2 -C 12烯基,R 2为C 1 -C 12烷基或C 3 -C 12烯基,m为0至5的整数,n为1至3的整数; 其中每个式Ar(R 2)m(OR 1)n的化合物以0.01ppm至100ppm的水平存在。

    Ortho-phenylphenol compounds
    14.
    发明授权
    Ortho-phenylphenol compounds 有权
    邻苯基苯酚化合物

    公开(公告)号:US09079838B2

    公开(公告)日:2015-07-14

    申请号:US14115480

    申请日:2012-05-07

    CPC classification number: C07C43/2055 C07C69/78 C10L1/003 C10L1/1852

    Abstract: A compound having formula (I), wherein G1 represents a C4-C22 alkyl or alkenyl group, a C8-C20 aralkyl group or formula (II) wherein G3 is a difunctional C2-C18 alkyl or alkenyl group, a difunctional C6-C20 aryl group or G3 is absent; provided that G1 is not 2-butyl, n-hexyl, n-octyl, n-dodecyl, n-hexadecyl or 2-phenylethyl.

    Abstract translation: 具有式(I)的化合物,其中G 1表示C 4 -C 22烷基或烯基,C 8 -C 20芳烷基或式(II),其中G 3是双官能的C 2 -C 18烷基或烯基,双官能的C 6 -C 20芳基 组或G3不存在; 如果G1不是2-丁基,正己基,正辛基,正十二烷基,正十六烷基或2-苯基乙基。

    SYSTEM FOR PRE-TREATING A FILTER USED IN A SMALL-SCALE WATER SEPAROMETER
    16.
    发明申请
    SYSTEM FOR PRE-TREATING A FILTER USED IN A SMALL-SCALE WATER SEPAROMETER 有权
    用于预处理小型水分离器中使用的过滤器的系统

    公开(公告)号:US20150090012A1

    公开(公告)日:2015-04-02

    申请号:US14499550

    申请日:2014-09-29

    CPC classification number: G01N33/2847 C10L1/003 G01N33/22

    Abstract: The safety and proper performance of jet aircraft engines requires that any contamination of jet fuel, for example by water or by improper contaminants, be filtered (removed) before delivery of the fuel, through hoses, to the fuel tanks of the aircraft. Coalescing devices and filters in the fuel delivery system are used to attain this result. A typical problem is that filter materials chemically react with surfactants, and this causes the filter subsequently to “disarm” or fail to perform its function of removing water, which can lead to delivery of fuel containing excessive water. A solution to this problem is to pre-test the fuel for such surfactants by feeding a small fuel sample that has been mixed with “challenge water” through a smaller ‘representative’ test filter and monitor the performance. Using a fluorescent dye in the “challenge water,” the amount of water that passes the test filter is detected, compared with a baseline data and fuel quality determination is made. From the result of the small-scale test, the fuel condition can be inferred and, based thereon; action can be taken to treat the fuel, prior to further distribution, such that it will not disarm field filter-coalescers in a typical fuel distribution system. The use of a fluorescent dye enhances the ability to make this determination of very small representative fuel filters. The fuel evaluation process is fully automated, thereby avoiding human-factor variables and assuring repeatable results.

    Abstract translation: 喷气式飞机发动机的安全性和适当性能要求,在通过软管将燃料运送到飞机的燃料箱之前,必须过滤(除去)喷射燃料的任何污染,例如水或不适当的污染物。 使用燃料输送系统中的聚结装置和过滤器来实现该结果。 一个典型的问题是过滤材料与表面活性剂发生化学反应,这导致过滤器随后“解除”或不能执行去除水的功能,这可能导致含有过量水的燃料的输送。 这个问题的解决方案是通过将一个与“挑战水”混合的小型燃料样品通过较小的“代表性”测试过滤器进行供给,并对其性能进行监测,来对这些表面活性剂的燃料进行预测试。 在“挑战水”中使用荧光染料,与基线数据相比,检测到通过测试过滤器的水量,并进行燃料质量确定。 从小规模试验的结果可以推断燃料条件,并基于此; 在进一步分配之前,可以采取行动来处理燃料,使得其不会在典型的燃料分配系统中解除现场过滤器 - 聚结器的装备。 荧光染料的使用增强了对非常小的代表性燃料过滤器的这种测定的能力。 燃油评估过程完全自动化,从而避免人为因素变量并确保可重复的结果。

    TRACERS AND METHOD OF MARKING LIQUIDS
    17.
    发明申请
    TRACERS AND METHOD OF MARKING LIQUIDS 有权
    追踪器和标记液体的方法

    公开(公告)号:US20140331547A1

    公开(公告)日:2014-11-13

    申请号:US14370229

    申请日:2013-01-04

    Abstract: Method of marking a hydrocarbon liquid includes: adding thereto, a tracer compound of Formula I:wherein,each A is independently selected from the group consisting of (i) a phenyl group, (ii) a phenyl group substituted with one or more halogen atoms, an aliphatic group or a halogenated aliphatic group, (iii) a partially or fully halogenated alkyl group or (iv) a linear branched or cyclic C1-C20 alkyl group, and each B is independently selected from the group consisting of a (i) phenyl, (ii) phenylmethyl group, (iii) a cyclohexyl group, (iv) a cyclohexylmethyl group, (v) a substituted phenyl or phenylmethyl group in which the benzene ring is substituted by at least one substituent selected from the group consisting of a fluorine atom, a partially or fully halogenated alkyl group and a linear, branched or cyclic C1-C20 alkyl group or (vi) a linear, branched or cyclic C1-C20 alkyl group.

    Abstract translation: 标记烃液体的方法包括:向其中加入式I示踪剂化合物:其中每个A独立地选自(i)苯基,(ii)被一个或多个卤素原子取代的苯基 ,脂族基团或卤代脂族基团,(iii)部分或完全卤化的烷基或(iv)直链支链或环状C 1 -C 20烷基,并且每个B独立地选自由以下组成的组:(i) 苯基,(ⅱ)苯基甲基,(ⅲ)环己基,(ⅳ)环己基甲基,(ⅴ)取代的苯基或苯基甲基,其中苯环被至少一个选自以下的取代基取代: 氟原子,部分或完全卤化的烷基和直链,支链或环状的C 1 -C 20烷基或(vi)直链,支链或环状的C 1 -C 20烷基。

    METHOD OF MARKING HYDROCARBON LIQUIDS
    19.
    发明申请
    METHOD OF MARKING HYDROCARBON LIQUIDS 有权
    标记液体液体的方法

    公开(公告)号:US20140120626A1

    公开(公告)日:2014-05-01

    申请号:US14116668

    申请日:2012-05-09

    Abstract: Method of marking a hydrocarbon liquid includes adding to the liquid, a tracer compound of Formula I or II: wherein at least one of R1-R6 in Formula I and at least one of R7-R14 in Formula II is selected from: i. a bromine or fluorine atom; ii. a partially or fully halogenated alkyl group; iii. a branched or cyclic C4-C20 alkyl group; iv. an aliphatic substituent linking two positions selected from R1-R6 in Formula I to one another or two positions selected from R7-R14 in Formula II to one another; or v. a phenyl group substituted with a halogen atom, an aliphatic group or halogenated aliphatic group and none of R1-R6 and none of R7-R14 being a sulphonate group or COOR15, where R15 represents H, C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, C3-C15 cycloalkyl or aryl.

    Abstract translation: 标记烃液体的方法包括向液体中加入式I或II的示踪化合物:其中式I中的R 1 -R 6和式II中的至少一个R 7 -R 14选自: 溴或氟原子; ii。 部分或完全卤化的烷基; iii。 支链或环状C 4 -C 20烷基; iv。 将选自式I中的R 1 -R 6的两个位置彼此或在式II中的R7-R14中的两个位置彼此连接的脂肪族取代基; 或者是被卤素原子,脂肪族基团或卤代脂族基团取代的苯基,R1-R6和R7-R14都不是磺酸酯基或COOR15,其中R15表示H,C1-C20烷基,C2- C20烯基,C2-C20炔基,C3-C15环烷基或芳基。

    Highly fluorescent markers for fluids or articles
    20.
    发明授权
    Highly fluorescent markers for fluids or articles 有权
    用于流体或物品的高度荧光标记物

    公开(公告)号:US08486711B2

    公开(公告)日:2013-07-16

    申请号:US10971825

    申请日:2004-10-22

    Inventor: George G. Combs

    Abstract: The present invention provides highly fluorescent markers, made from a reactive polymer and an isocyanate, that fluoresce in the ultraviolet or near infrared region without being visible to the human eye at low concentrations in the fluid or article being marked. The molecular weight and fluorescence emission wavelength of these highly fluorescent marker compounds can be adjusted to provide a multitude of markers with unique fluorescence signatures.

    Abstract translation: 本发明提供由反应性聚合物和异氰酸酯制成的高度荧光标记,其在紫外线或近红外区域发荧光,而在被标记的流体或制品中以低浓度在人眼中不可见。 可以调节这些高度荧光标记化合物的分子量和荧光发射波长,以提供许多具有独特荧光标记的标记。

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