公开(公告)号：US20150218294A1

公开(公告)日：2015-08-06

申请号：US14419303

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C08F130/08 ,  C09D143/04

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi) (meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

Abstract translation: 通过具有异氰酸酯官能团的（甲基）丙烯酸酯化物质与氨基硅烷化合物反应合成的尿素（多） - （甲基）丙烯酸酯（多） - 硅烷前体化合物，无论是在溶剂中还是在溶剂中，以及任选地与催化剂如锡 化合物，加速反应。 还描述了包括基底，在基底的主表面上的基底（共）聚合物层），基底（共）聚合物层上的氧化物层的物品; 和氧化物层上的保护（共）聚合物层，所述保护（共）聚合物层包括通过（甲基）丙烯酸酯反应合成的至少一种脲（多）（甲基）丙烯酸酯（多） - 硅烷前体化合物的反应产物， 具有氨基硅烷化合物的异氰酸酯官能团的丙烯酸酯化材料。 衬底可以是（共）聚合物膜或诸如有机发光器件，电泳发光器件，液晶显示器，薄膜晶体管或其组合的电子器件。 描述了制备尿素（多） - （甲基）丙烯酸酯（多）硅烷的方法及其在复合膜和电子器件中的应用。

公开(公告)号：US20150214405A1

公开(公告)日：2015-07-30

申请号：US14421035

申请日：2013-08-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Alan K. Nachtigal ,  Andrew T. Ruff ,  Christopher S. Lyons ,  Guy D. Joly ,  Joseph C. Spagnola ,  Mark D. Weigel ,  Michael D. Delmore ,  Samuel Kidane ,  Thomas P. Klun

IPC: H01L31/048 ,  B32B27/08 ,  B32B27/36 ,  H01L51/52

CPC classification number: H01L31/048 ,  B32B27/08 ,  B32B27/36 ,  B32B2250/42 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2255/26 ,  B32B2255/28 ,  B32B2307/412 ,  B32B2307/71 ,  B32B2457/12 ,  C08J7/045 ,  C08J7/18 ,  C08J2367/02 ,  C08J2433/00 ,  H01L51/524 ,  Y10T428/2848

Abstract: The present disclosure generally relates to methods of forming barrier assemblies. Some embodiments include application of an adhesive layer and/or a topsheet to protect the exposed uppermost layer of the barrier stack during roll-to-roll processing. Some embodiments include application of an adhesive layer and/or a topsheet before the exposed, uppermost layer of the barrier film contacts a solid surface or processing roll. Inclusion of an adhesive layer and/or a topsheet protects the oxide layer during processing, which creates an excellent barrier assembly that can be manufactured using roll-to-roll processing.

Abstract translation: 本公开一般涉及形成屏障组件的方法。 一些实施例包括在卷对卷处理期间施加粘合剂层和/或顶片以保护暴露的阻挡层的最上层。 一些实施方案包括在暴露的最上层的阻挡膜接触固体表面或加工辊之前施加粘合剂层和/或顶片。 粘合剂层和/或顶片的包含在加工过程中保护氧化物层，这产生可以使用卷对卷加工制造的优异的阻挡组件。

公开(公告)号：US20150203707A1

公开(公告)日：2015-07-23

申请号：US14417831

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Alan K. Nachtigal ,  Joseph C. Spagnola ,  Mark A. Roehrig ,  Jennifer K. Schnobrich ,  Guy D. Joly ,  Christopher S. Lyons

IPC: C09D133/14

CPC classification number: C09D143/04 ,  B05D1/60 ,  B05D3/067 ,  B05D3/068 ,  B05D3/101 ,  B32B27/308 ,  B32B2250/04 ,  B32B2307/7242 ,  B32B2307/7244 ,  C07F7/1804 ,  C08F130/08 ,  C08J7/045 ,  C08J2333/12 ,  C08K3/34 ,  C09D133/14 ,  C09D135/02 ,  C09J133/14 ,  C23C14/08 ,  C23C14/34 ,  C23C16/40 ,  C23C16/44 ,  H01L51/004 ,  H01L51/107 ,  H01L51/448 ,  H01L51/5253 ,  Y10T428/1064 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31609 ,  Y10T428/31663

Abstract: Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula RA—NH—C(O)—N(R4)—R11—[O—C(O)NH—RS]n, or RS—NH—C(O)—N(R4)—R11—[O—C(O)NH—RA]n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi) urethane(meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane(meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.

Abstract translation: 描述为具有通式RA-NH-C（O）-N（R4）-R11- [O-C（O）NH-RS] n的尿素（多） - 氨基甲酸酯（甲基）丙烯酸酯 - 或RS-NH-C（O）-N（R4）-R11- [O-C（O）NH-RA] n。 还描述了包括基底，在基底的主表面上的基底（共）聚合物层），基底（共）聚合物层上的氧化物层的物品; 和氧化物层上的保护（共）聚合物层，所述保护（共）聚合物层包括至少一种尿素（多）氨基甲酸酯（甲基）丙烯酸酯 - 硅烷前体化合物的反应产物。 衬底可以是（共）聚合物膜或诸如有机发光器件，电泳发光器件，液晶显示器，薄膜晶体管或其组合的电子器件。 还描述了制备这种尿素（多） - 氨基甲酸酯（甲基）丙烯酸酯 - 硅烷前体化合物的方法及其在复合膜和电子器件中的应用。 还描述了在选自固态照明装置，显示装置和光伏装置的制品中使用多层复合膜作为阻挡膜的方法。

公开(公告)号：US08882945B2

公开(公告)日：2014-11-11

申请号：US14182741

申请日：2014-02-18

Applicant: 3M Innovative Properties Company

Inventor： Guy D. Joly ,  Leon Levitt ,  Vivek Bharti

IPC: B29C65/00 ,  B32B27/00 ,  C08L33/00 ,  C08L33/02 ,  C09J123/22 ,  C09J7/02 ,  C08L23/36 ,  C08L33/06 ,  C08K5/00

CPC classification number: C09J7/021 ,  C08K5/0016 ,  C08L23/36 ,  C08L33/064 ,  C08L2666/02 ,  C09J7/381 ,  C09J123/22 ,  Y10T156/10 ,  Y10T428/249983 ,  Y10T428/2839 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T442/2754

Abstract: Adhesive compositions are described comprising a) a non-functional isobutylene (co)polymer, b) an amine-functional poly(isobutylene) polymer, optionally an acid-functional (meth)acrylate copolymer, and optionally a tackifier.

Abstract translation: 描述的粘合剂组合物包括a）非功能异丁烯（共）聚合物，b）胺官能聚（异丁烯）聚合物，任选的酸官能（甲基）丙烯酸酯共聚物，以及任选的增粘剂。

公开(公告)号：US20250011633A1

公开(公告)日：2025-01-09

申请号：US18706151

申请日：2022-11-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Amanda K. Leone ,  Jonathan j. Anderson ,  Guy D. Joly ,  Ahmed S. Abuelyaman ,  Michael A. Kropp ,  Claire Hartmann-Thompson ,  Wayne S. Mahoney

IPC: C09J133/12 ,  C09J163/08

Abstract: An adhesive composition is described comprising at least one cyclic imide monomer comprising an unsaturated carbonyl. The adhesive composition is a polymerizable composition or a polymerized composition. The polymerizable adhesive composition may comprise at least one monomer, oligomer, polymer, or a combination thereof comprising ethylenically unsaturated groups and/or an epoxy resin. The cyclic imide monomer may comprise an imide group with an α, β-unsaturated carbonyl in a heterocyclic ring wherein the ring comprises at least 6 covalently bonded atoms. Also described are methods of forming an adhesive coated substrate and articles.

公开(公告)号：US20230323151A1

公开(公告)日：2023-10-12

申请号：US18248897

申请日：2021-10-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Ahmed S. Abuelyaman ,  Joel D. Oxman

IPC: C09D139/04 ,  C08F226/06 ,  C09D7/61 ,  C09D7/40 ,  C09D7/63 ,  C09D7/20

CPC classification number: C09D139/04 ,  C08F226/06 ,  C09D7/61 ,  C09D7/68 ,  C09D7/63 ,  C09D7/20

Abstract: A polymerizable composition is described comprising at least one monomer, oligomer, polymer, or a combination thereof comprising ethylenically unsaturated groups; and at least one cyclic imide monomer comprising an α, β-unsaturated carbonyl. The cyclic imide monomer comprises an imide group and the α, β-unsaturated carbonyl in a heterocyclic ring wherein the ring comprises at least 6 covalently bonded atoms. Also described are cyclic imide monomers, (e.g. hardcoat) compositions, methods of making a coated substrate, cyclic imide monomers, and methods of making cyclic imide monomers.

公开(公告)号：US11505653B2

公开(公告)日：2022-11-22

申请号：US16632501

申请日：2018-07-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Wayne S. Mahoney ,  Saswata Chakraborty ,  Guy D. Joly ,  Jonathan A. Anim-Addo

IPC: C08G75/045 ,  C08F2/48 ,  C08L81/02 ,  G02B1/04

Abstract: A composition comprising at least one terminally-unsaturated diarylsulfide compound represented by the formula: wherein each R represents an allyl group or a propargyl group. The composition may further comprise an organic polythiol, and optionally a free-radical initiator, and may be formulated as a two-part polymerizable composition. Methods of polymerizing the compositions are also disclosed.

公开(公告)号：US11149194B2

公开(公告)日：2021-10-19

申请号：US16318884

申请日：2017-07-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Carl A. Laskowski ,  Saswata Chakraborty ,  Wayne S. Mahoney ,  Guy D. Joly ,  Michael C. Palazzotto

IPC: C09K11/02 ,  C08F230/02 ,  C08F297/02 ,  C08G77/04 ,  C08L83/10 ,  C09K11/70 ,  G02F1/133 ,  C08G77/442 ,  G02F1/13357 ,  C08G77/14 ,  C08F212/14 ,  G02F1/1335

Abstract: The present disclosure provides a composite particle that includes: a fluorescent semiconductor core/shell nanoparticle (preferably, nanocrystal); and a stabilizing homo- or copolymer combined with the core/shell nanoparticle, the stabilizing (co)polymer comprising styrene monomer units and functionalized with phosphine, arsine or stibine groups.

公开(公告)号：US10829686B2

公开(公告)日：2020-11-10

申请号：US16090514

申请日：2017-03-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Paul B. Armstrong ,  Saswata Chakraborty ,  Michael C. Palazzotto ,  Guy D. Joly

IPC: C09K11/02 ,  C07C43/12 ,  C07F9/50 ,  C09K11/70 ,  B82Y20/00

Abstract: Disclosed are quantum dots and quantum dot articles stabilized by a stabilizing agent of the formula: wherein each R1 is a hydrocarbyl group including alkyl, aryl, alkaryl and aralkyl; R2 is a divalent hydrocarbyl group selected from alkylene, arylene, alkarylene and aralkylene; Z is P, As or Sb; Q is —CH2—S—, —CH2—O—, —CO2—, —CH2—O—CO—, —CONR3—, —NH—CO—NR3—, and —NR3, where R3 is H or C1-C4 alkyl, subscript x is 1, R6 is a divalent hydrocarbyl group selected from alkylene, arylene, alkarylene and aralkylene, subscript y is 0 or 1, Rf is a perfluoroether group.

公开(公告)号：US10513583B2

公开(公告)日：2019-12-24

申请号：US15129331

申请日：2015-03-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Robert S. Clough ,  Gregory P. Karp ,  Zachary J. Thompson ,  Guy D. Joly

IPC: C08G75/045 ,  C08G75/12 ,  C08G77/28 ,  C08F4/54 ,  C09D183/08 ,  C08L83/08 ,  C09J183/08 ,  C08G77/08 ,  C08F236/20 ,  C08F222/10

Abstract: A polymerizable composition that includes: an organoborane-base complex, wherein the base is a complexing agent selected from a compound having one or more amine groups, amidine groups, hydroxide groups, alkoxide groups, or combinations thereof; a decomplexing agent that liberates the organoborane from the organoborane-base complex; a polymerizable thiol-containing component that includes at least one polymerizable thiol-containing compound having a plurality of thiol groups in which the sulfur atom of the thiol group is covalently bonded to carbon; and a polymerizable ethylenically unsaturated component that includes at least one polymerizable ethylenically unsaturated compound having a plurality of ethylenically unsaturated groups; wherein the total amount of the thiol-containing and ethylenically unsaturated compounds total at least 50% by weight of all polymerizable material in the composition.