公开(公告)号：US20160272814A1

公开(公告)日：2016-09-22

申请号：US15032214

申请日：2014-10-24

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kentaro Sano ,  Keisuke Inose ,  Naokichi Imai ,  Atsuki Tsuchiya

IPC: C08L81/04 ,  C08L69/00 ,  C08J3/22

CPC classification number: C08L81/04 ,  C08J3/22 ,  C08J5/06 ,  C08L69/00 ,  C08L79/08

Abstract: A molding material includes 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50° C., and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C).

Abstract translation: 成型材料包括5〜50质量份的具有上浆剂的增强纤维（A），1〜20质量份含有作为液体的聚碳二亚胺化合物（B-1）的成分（B） 相对于主链的重复单元结构中含有除碳以外的元素的热塑性树脂（C），相对于100质量份的组分（A ）至（C），其中，所述成型材料为复合纤维束（D）与组分（B）浸渍的组分（A）被组分（C）覆盖的组合物。

公开(公告)号：US20160251498A1

公开(公告)日：2016-09-01

申请号：US15030641

申请日：2014-10-24

Applicant: TORAY INDUSTRIES, INC.

Inventor： Naokichi Imai ,  Kentaro Sano ,  Keisuke Inose

IPC: C08K9/04 ,  C08K7/06 ,  C08L81/00 ,  B29C45/00

CPC classification number: C08K9/04 ,  B29C45/0001 ,  B29C70/14 ,  C08K7/06 ,  C08K2201/004 ,  C08L81/00 ,  C08L81/04

Abstract: A molded article includes 10 to 40% by mass of reinforcing fibers (A); and 60 to 90% by mass of a matrix resin (B) mainly including a polyarylene sulfide, the molded article satisfying conditions (I) to (IV) and having a tensile strength of 240 MPa or more in a main orientation direction of the reinforcing fibers (A) in the molded article, wherein (I) strand tensile strength of the reinforcing fibers (A) is 1.5 to 5.5 GPa, (II) number average fiber length of the reinforcing fibers (A) is 0.4 to 10 mm, (III) tensile elongation of the matrix resin (B) is 1.5 to 10%, and (IV) interfacial shear strength between the reinforcing fibers (A) and the matrix resin (B) is 20 MPa or more.

Abstract translation: 成型体包含10〜40质量％的增强纤维（A）; 和主要包含聚芳硫醚的基质树脂（B）60〜90质量％，满足条件（I）〜（IV），并且在强化剂的主取向方向上的拉伸强度为240MPa以上的成型体 纤维（A），其中（I）增强纤维（A）的线股抗拉强度为1.5〜5.5GPa，（II）增强纤维（A）的数均纤维长度为0.4〜10mm， III）基体树脂（B）的拉伸伸长率为1.5〜10％，（IV）增强纤维（A）与基体树脂（B）的界面剪切强度为20MPa以上。

公开(公告)号：US12076943B2

公开(公告)日：2024-09-03

申请号：US17778073

申请日：2020-11-16

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Kotaro Shinohara ,  Masato Honma

IPC: B29C70/14 ,  B29C53/24 ,  B29C65/00 ,  B29C70/40 ,  B29D99/00 ,  B32B3/28 ,  B29K105/00 ,  B29K307/04 ,  B29L7/00

CPC classification number: B29C70/14 ,  B29C53/24 ,  B29C66/721 ,  B29C70/40 ,  B29D99/0089 ,  B32B3/28 ,  B29K2105/256 ,  B29K2307/04 ,  B29K2995/0096 ,  B29L2007/002 ,  B32B2250/20 ,  B32B2260/021 ,  B32B2260/046 ,  B32B2305/026 ,  B32B2305/076

Abstract: An object of the present invention is to obtain a fiber-reinforced composite material achieving both lightweight properties and mechanical properties at a high level. The present invention is a fiber-reinforced composite material including: a resin (A); and a reinforcing fiber (B), and including: a fiber-reinforced structure portion including an in-plane orientation portion having an average fiber orientation angle of the reinforcing fiber (B) of 0° or more and 45° or less and an out-of-plane orientation portion having an average fiber orientation angle of the reinforcing fiber (B) of more than 45° and 90° or less; and a cavity portion defined by the in-plane orientation portion and the out-of-plane orientation portion of the fiber-reinforced structure portion.

公开(公告)号：US20220212426A1

公开(公告)日：2022-07-07

申请号：US17604489

申请日：2020-05-15

Applicant: Toray Industries, Inc.

Inventor： Takashi Fujioka ,  Naokichi Imai ,  Masato Honma ,  Yoshiki Takebe ,  Kotaro Shinohara

IPC: B29C70/88 ,  B29C70/20

Abstract: A fiber-reinforced plastic substrate is described in which a plurality of resins having different properties are firmly compounded and that includes components [A], [B], and [C]: [A] reinforcing fibers; [B] thermoplastic resin (b); and [C] thermoplastic resin (c), wherein the component [A] is arranged in one direction, in the fiber-reinforced plastic substrate, a resin area including the component [B] and a resin area including the component [C] are present, the resin area including the component [B] is present on a surface of one side of the fiber-reinforced plastic substrate, and a distance Ra(bc) between Hansen solubility parameters of the component [B] and the component [C] satisfies formula (1): Ra(bc)={4(δDB−δDC)2+(δPB−δPC)2+(δHB−δHC)2}1/2≥8 wherein Ra(bc), δDB, δDC, δPB, δPC, δHB and δHC are as defined.

公开(公告)号：US10017613B2

公开(公告)日：2018-07-10

申请号：US15032145

申请日：2014-10-24

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Kentaro Sano ,  Keisuke Inose

IPC: B29C70/48 ,  C08J5/04 ,  C08J5/06 ,  B29B7/48 ,  B29B7/82 ,  B29B7/86 ,  B29B7/90 ,  B29B9/02 ,  B29C43/22 ,  B29C45/00 ,  C08K7/06 ,  B29K81/00 ,  B29K105/08

CPC classification number: C08J5/042 ,  B29B7/002 ,  B29B7/482 ,  B29B7/489 ,  B29B7/82 ,  B29B7/86 ,  B29B7/90 ,  B29B9/02 ,  B29C43/22 ,  B29C45/0005 ,  B29K2081/04 ,  B29K2105/08 ,  C08J5/06 ,  C08J2381/02 ,  C08J2381/04 ,  C08J2479/00 ,  C08K7/06 ,  C08K5/29 ,  C08L81/02

Abstract: A carbon fiber-reinforced polyarylene sulfide has both dynamic characteristics and molding cycle characteristics and can be produced with high productivity by preparing a polycarbodiimide-modified polyarylene sulfide using a polyarylene sulfide and a polycarbodiimide as raw materials, then melting the resulting polycarbodiimide-modified polyarylene sulfide, and combining the polycarbodiimide-modified polyarylene sulfide with carbon fibers at a specific ratio to produce a composite.

公开(公告)号：US20180142083A1

公开(公告)日：2018-05-24

申请号：US15873031

申请日：2018-01-17

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Kentaro Sano ,  Keisuke Inose

IPC: C08K9/04 ,  B29C70/14 ,  C08K7/06 ,  C08L81/00 ,  B29C45/00

CPC classification number: C08K9/04 ,  B29C45/0001 ,  B29C70/14 ,  C08K7/06 ,  C08K2201/004 ,  C08L81/00 ,  C08L81/04

Abstract: A molded article includes 10 to 40% by mass of reinforcing fibers (A); and 60 to 90% by mass of a matrix resin (B) mainly including a polyarylene sulfide, the molded article satisfying conditions (I) to (IV) and having a tensile strength of 240 MPa or more in a main orientation direction of the reinforcing fibers (A) in the molded article: (I) strand tensile strength of the reinforcing fibers (A) is 1.5 to 5.5 OPa; (II) number average fiber length of the reinforcing fibers (A) in the molded article is 0.4 mm or more and less than 0.6 mm; (III) tensile elongation of the matrix resin (B) is 1.5 to 10%; and (IV) interfacial shear strength between the reinforcing fibers (A) and the matrix resin (B) is 20 MPa or more.

公开(公告)号：US20160264740A1

公开(公告)日：2016-09-15

申请号：US15032713

申请日：2014-10-24

Applicant: TORAY INDUSTRIES INC.

Inventor： Naokichi Imai ,  Keisuke Inose ,  Kentaro Sano ,  Atsuki Tsuchiya

IPC: C08J5/06

CPC classification number: C08J5/06 ,  C08J2381/02 ,  C08J2381/04 ,  C08K5/29 ,  C08K7/06 ,  C08K9/04 ,  C08L81/02

Abstract: A fiber-reinforced resin composition includes a polyarylene sulfide (A), a carbodiimide compound (B) and carbon fibers (C) in specific blending amounts and in which the carbon fibers (C) are surface-treated with a sizing agent (D), the carbodiimide compound (B) is an aliphatic carbodiimide compound, and the sizing agent (D) is a compound having three or more specific functional groups in one molecule; and a fiber-reinforced composite material includes a thermoplastic resin (A′), an adhesive compound (B′) and reinforcing fibers (C′) and in which the adhesive compound (B′) is a compound having two or more specific structures in one molecule, the thermoplastic resin (A′) is a thermoplastic resin containing an element other than carbon in a repeating unit structure of a main chain, and an abundance ratio Rb of the adhesive compound (B′) is 1.2 or more.

Abstract translation: 纤维增强树脂组合物包括特定配合量的聚芳硫醚（A），碳二亚胺化合物（B）和碳纤维（C），其中碳纤维（C）用施胶剂（D）进行表面处理， ，碳二亚胺化合物（B）为脂肪族碳二亚胺化合物，上浆剂（D）为1分子中具有3个以上特定官能团的化合物; 纤维增强复合材料包括热塑性树脂（A'），粘合剂化合物（B'）和增强纤维（C'），并且其中粘合剂化合物（B'）是具有两个或多个特定结构的化合物 一个分子，热塑性树脂（A'）是在主链的重复单元结构中含有碳以外的元素的热塑性树脂，粘合剂（B'）的丰度比Rb为1.2以上。