公开(公告)号：US20120048775A1

公开(公告)日：2012-03-01

申请号：US13262681

申请日：2010-03-24

Applicant: Aurelie Dandeu ,  Vincent Coupard

Inventor： Aurelie Dandeu ,  Vincent Coupard

IPC: C10G69/02 ,  C10G69/04

CPC classification number: C10G47/16 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/88 ,  B01J31/08 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J39/04 ,  C10G2/30 ,  C10G7/00 ,  C10G25/02 ,  C10G25/05 ,  C10G45/32 ,  C10G45/34 ,  C10G45/58 ,  C10G45/60 ,  C10G47/00 ,  C10G65/12 ,  C10G67/06 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/1025 ,  C10G2300/201 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

Abstract: The present invention describes a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis and divided into two fractions, a light fraction, termed the cold condensate, and a heavy fraction, termed the waxes, comprising a) fractionating said cold condensate fraction into a gaseous C4− fraction and an intermediate fraction with an initial boiling point in the range 15° C. to 40° C. and an end point in the range 300° C. to 450° C.; b) passing the intermediate fraction over at least one ion exchange resin; eliminating at least a portion of the water from the effluent derived from step b); decontaminating said heavy fraction termed the waxes by passage over a guard bed; recombining the purified intermediate fraction and the effluent derived from step d) to obtain a purified C5+ fraction; f) hydrogenating the unsaturated compounds of the purified C5+ fraction; g) hydroisomerization/hydrocracking of the effluent derived from step f); h) separating and recycling unreacted hydrogen and light gases to the hydroisomerization/hydrocracking step; and distilling the effluent derived from step h).

Abstract translation: 本发明描述了一种由费 - 托合成生产的石蜡饲料生产中间馏分的方法，分为两部分，称为冷凝液的轻馏分，称为蜡的重质馏分，其包括a）将所述冷分馏 冷凝物馏分进入气态C 4馏分和中间馏分，初始沸点在15℃至40℃，终点在300℃至450℃范围内。 b）使中间馏分通过至少一种离子交换树脂; 从来自步骤b）的流出物中除去至少一部分水; 通过在保护床上通过，将称为蜡的所述重质馏分去污; 将纯化的中间体馏分和来自步骤d）的流出物重组，得到纯化的C5 +级分; f）氢化纯化的C5 +级分的不饱和化合物; g）来自步骤f）的流出物的加氢异构化/加氢裂化; h）将未反应的氢气和轻质气体分离并循环到加氢异构化/加氢裂化步骤; 并蒸馏来自步骤h）的流出物。

公开(公告)号：US08053609B2

公开(公告)日：2011-11-08

申请号：US11872318

申请日：2007-10-15

Applicant: William Crudge ,  Jaap Willem van Hal ,  Xiankuan Zhang

Inventor： William Crudge ,  Jaap Willem van Hal ,  Xiankuan Zhang

IPC: C07C27/00

CPC classification number: B01J31/08 ,  C07C29/106 ,  Y02P20/52 ,  C07C31/207 ,  C07C31/202 ,  C07C31/205

Abstract: A solid (i.e., heterogeneous) catalyst useful for preparing an alkylene glycol from the corresponding alkylene oxide as well as a process for the catalytic hydration of an alkylene oxide to an alkylene glycol utilizing such a catalyst are provided. The catalyst of the present invention is based on an ion exchange resin including polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene. The ion exchange resin further includes quaternary ammonium groups or quaternary phosphonium groups. The process includes reacting water and an alkylene oxide in at least one reactor under conditions to form an alkylene glycol, wherein the at least one reactor includes a catalyst based on an ion exchange resin that includes polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene.

Abstract translation: 提供了可用于从相应的烯化氧制备亚烷基二醇的固体（即非均相）催化剂，以及利用这种催化剂将烯化氧催化水合成亚烷基二醇的方法。 本发明的催化剂基于包含用约2-约10重量％的二乙烯基苯交联的聚苯乙烯的离子交换树脂。 离子交换树脂还包括季铵基或季鏻基。 该方法包括在至少一个反应器中在形成亚烷基二醇的条件下使水和烯化氧反应，其中至少一个反应器包括基于离子交换树脂的催化剂，所述催化剂包括以约2至约10重量％ wt。）％二乙烯基苯。

公开(公告)号：US20110236289A1

公开(公告)日：2011-09-29

申请号：US13132956

申请日：2009-12-22

Applicant: Shouji Iiyama ,  Tomohiro Yamamoto ,  Yukihiro Takata ,  Shinichiro Koyanagi ,  Kanji Sakata

Inventor： Shouji Iiyama ,  Tomohiro Yamamoto ,  Yukihiro Takata ,  Shinichiro Koyanagi ,  Kanji Sakata

IPC: C01B33/107 ,  B01J41/14

CPC classification number: C01B33/107 ,  B01J31/08 ,  C01B33/10773

Abstract: When a disproportionated chlorosilane is to be produced by causing a starting material chlorosilane liquid to flow through a catalyst-packed layer which is packed with a weakly basic anion exchange resin as a disproportionation reaction catalyst to carry out a disproportionation reaction, before the disproportionation reaction is carried out, the disproportionation reaction catalyst is brought into contact with a processing gas obtained by diluting a chlorosilane with an inert gas to prevent the deterioration of the disproportionation reaction catalyst at the start of the reaction so as to carry out the disproportionation of the chlorosilane efficiently.

Abstract translation: 当通过使原料氯硅烷液体流过填充有弱碱性阴离子交换树脂的催化剂填充层作为歧化反应催化剂进行歧化反应来制造歧化氯硅烷时，在歧化反应为 进行歧化反应催化剂与通过用惰性气体稀释氯硅烷获得的处理气体接触，以防止歧化反应催化剂在反应开始时的劣化，从而有效地进行氯硅烷的歧化 。

公开(公告)号：US20100324341A1

公开(公告)日：2010-12-23

申请号：US12875016

申请日：2010-09-02

Applicant: Takashi TERAJIMA ,  Toshihiro Takai ,  Kenji Fujiwara

Inventor： Takashi TERAJIMA ,  Toshihiro Takai ,  Kenji Fujiwara

IPC: C07C39/16

CPC classification number: B01J31/0239 ,  B01J31/0268 ,  B01J31/08 ,  B01J31/10 ,  B01J2231/342 ,  C07C37/20 ,  Y02P20/52 ,  C07C39/16

Abstract: The present invention provides an ion-exchange resin catalyst, as a catalyst for preparing bisphenol from phenol compounds and ketone, which has a higher selectivity to bisphenol and a longer life time, as compared to a conventional ion-exchange resin, and a method for preparing the same.The present invention also provides a method for preparing bisphenol comprising reacting phenol compounds with ketone, wherein the modified acidic ion-exchange resin in which at least one kind of cationic compound selected from the following (a), (b), (c) and (d) ionically binds to an acidic functional group, is used as a catalyst: (a) a quaternary phosphonium ion, (b) a quaternary ammonium ion, (c) a bis(phosphoranylidene) ammonium ion, and (d) an N-substituted nitrogen-containing aromatic cation.

Abstract translation: 本发明提供一种离子交换树脂催化剂，作为与常规离子交换树脂相比，具有较高的双酚选择性和较长使用寿命的酚类化合物和酮制备双酚的催化剂， 准备一样 本发明还提供一种制备双酚的方法，其包括使酚化合物与酮反应，其中所述改性酸性离子交换树脂其中至少一种选自以下（a），（b），（c）和 （d）与酸性官能团离子键合，用作催化剂：（a）季鏻离子，（b）季铵离子，（c）双（亚正膦基）铵离子，和（d）N 取代的含氮芳族阳离子。

公开(公告)号：US20100129591A1

公开(公告)日：2010-05-27

申请号：US12623308

申请日：2009-11-20

Applicant: Leonardo C. Lopez ,  Scott T. Matteucci ,  Sarada P. Namhata

Inventor： Leonardo C. Lopez ,  Scott T. Matteucci ,  Sarada P. Namhata

IPC: C08K5/541 ,  B32B27/00 ,  D03D27/00 ,  D04H13/00 ,  B01J32/00

CPC classification number: B01J31/08 ,  Y10T428/23921 ,  Y10T428/25 ,  Y10T428/2913 ,  Y10T428/2915 ,  Y10T428/2927 ,  Y10T442/60 ,  Y10T442/674

Abstract: The instant invention generally provides polymer organoclay composite comprising a molecularly self-assembling material and an organoclay, and a process of making and an article comprising the polymer organoclay composite. The instant invention also generally provides a fiber comprising the polymer organoclay composite, and a process of fabricating and an article comprising the fiber

Abstract translation: 本发明通常提供包含分子自组装材料和有机粘土的聚合物有机粘土复合材料，以及制备方法和包含聚合物有机粘土复合材料的制品。 本发明还通常提供了包含聚合物有机粘土复合材料的纤维，以及包含该纤维的制造方法和制品

公开(公告)号：US20090099393A1

公开(公告)日：2009-04-16

申请号：US11872318

申请日：2007-10-15

Applicant: William Crudge ,  Jaap Willem van Hal ,  Xiankuan Zhang

Inventor： William Crudge ,  Jaap Willem van Hal ,  Xiankuan Zhang

IPC: C07C29/10 ,  B01J31/06

CPC classification number: B01J31/08 ,  C07C29/106 ,  Y02P20/52 ,  C07C31/207 ,  C07C31/202 ,  C07C31/205

Abstract: A solid (i.e., heterogeneous) catalyst useful for preparing an alkylene glycol from the corresponding alkylene oxide as well as a process for the catalytic hydration of an alkylene oxide to an alkylene glycol utilizing such a catalyst are provided. The catalyst of the present invention is based on an ion exchange resin including polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene. The ion exchange resin further includes quaternary ammonium groups or quaternary phosphonium groups. The process includes reacting water and an alkylene oxide in at least one reactor under conditions to form an alkylene glycol, wherein the at least one reactor includes a catalyst based on an ion exchange resin that includes polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene.

Abstract translation: 提供了可用于从相应的烯化氧制备亚烷基二醇的固体（即非均相）催化剂，以及利用这种催化剂将烯化氧催化水合成亚烷基二醇的方法。 本发明的催化剂基于包含用约2-约10重量％的二乙烯基苯交联的聚苯乙烯的离子交换树脂。 离子交换树脂还包括季铵基或季鏻基。 该方法包括在至少一个反应器中在形成亚烷基二醇的条件下使水和烯化氧反应，其中至少一个反应器包括基于离子交换树脂的催化剂，所述催化剂包括以约2至约10重量％ wt。）％二乙烯基苯。

公开(公告)号：US07501531B2

公开(公告)日：2009-03-10

申请号：US11833129

申请日：2007-08-02

Applicant: Eugene Marie Godfried Andre Van Kruchten ,  Hendrik Stichter

Inventor： Eugene Marie Godfried Andre Van Kruchten ,  Hendrik Stichter

IPC: C07D317/36 ,  C07D317/38

CPC classification number: C07D317/36 ,  B01J31/08 ,  B01J31/26 ,  B01J2531/26 ,  C07D317/38

Abstract: A process for the preparation of an alkylene carbonate, said process comprising contacting the corresponding alkylene oxide with carbon dioxide in the presence of a metal salt immobilised on a solid support, wherein the metal salt comprises a cation of a metal selected from those in the third period and group 2, the fourth period and groups 2 and 4 to 12, the fifth period and groups 2, 4 to 7, 12 and 14, and the sixth period and groups 2 and 4 to 6 of the periodic table according to IUPAC nomenclature, and an anion selected from anions of inorganic acids and organic acids, and wherein the solid support contains a quaternary ammonium, a quaternary phosphonium, a quaternary arsenonium, a quaternary stibonium, or a ternary sulfonium cation.

Abstract translation: 一种制备碳酸亚烷基酯的方法，所述方法包括在固定在固体载体上的金属盐存在下使相应的烯化氧与二氧化碳接触，其中金属盐包含选自第三者中的金属的阳离子 期间和第2组，第4周期和第2组和第4至12组，第5周期和第2,4至7,12和14组以及周期表第6周期和第2组和第4至6组根据IUPAC术语 和选自阴离子的阴离子的无机酸和有机酸的阴离子，并且其中所述固体载体含有季铵，季鏻，季arsen，季锑或三元锍阳离子。

公开(公告)号：US20080087604A1

公开(公告)日：2008-04-17

申请号：US11899125

申请日：2007-09-04

Applicant: Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

Inventor： Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

IPC: C08J9/00 ,  B01D15/04

CPC classification number: B01J41/14 ,  B01J31/08 ,  C02F1/42 ,  C02F2001/422 ,  C02F2103/023

Abstract: The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak′, Ak″ are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2 and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ⅓ PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.

Abstract translation: 本发明涉及基于至少一种芳族单体和至少一种具有通式（I）的结构元件的交联剂的热稳定阴离子交换剂，其中Ak，Ak'，Ak“在每种情况下彼此独立地彼此独立地 或者不同的是C 1 -C 18 - 烷基，n是5至18之间的偶数，x + y = 2，X是Cl，Br，OH， HCO 3，HSO 4，½（SO 4 S），1/3 CO 3，NO 3， / SUB，F，H 2 PO 4，1/2 HPO 4，1/3 PO 4，和 结果是这些阴离子交换剂优选为OH形式，在相当长的时间内经受至少60℃，优选至少80℃的工作温度，其制备方法及其用途。

公开(公告)号：US20080041794A1

公开(公告)日：2008-02-21

申请号：US11893875

申请日：2007-08-16

Applicant: Vishal Shah

Inventor： Vishal Shah

IPC: C02F1/72

CPC classification number: C02F1/725 ,  B01J31/08 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  C02F1/42 ,  C02F1/722 ,  C02F2101/306 ,  C02F2101/308 ,  C02F2101/32 ,  C02F2101/327 ,  C02F2101/345 ,  C02F2101/363 ,  C02F2103/001 ,  C02F2103/007 ,  C02F2303/04 ,  C02F2305/023

Abstract: Methods of decontaminating water, catalysts therefor and methods of making catalysts for decontaminating water to neutralize contaminants including organic and non-organic contaminants, such as aromatic compounds and microorganisms, e.g. bacteria. A heterogeneous catalyst is formed by incubating a polymeric resin with a transition metal-salt solution, e.g. a CuSO4 solution. The contaminated water is treated by immersing the resulting heterogeneous catalyst in the contaminated water with hydrogen peroxide.

Abstract translation: 净化水的方法，其催化剂和制造用于净化水的催化剂的方法，以中和包括有机和非有机污染物在内的污染物，例如芳族化合物和微生物，例如芳族化合物和微生物。 菌。 通过将聚合物树脂与过渡金属盐溶液（例如， CuSO 4溶液。 污染的水通过将所得的非均相催化剂用过氧化氢浸入污染的水中来处理。

公开(公告)号：US20080026936A1

公开(公告)日：2008-01-31

申请号：US11747009

申请日：2007-05-10

Applicant: Sang-hyuk SUH ,  Chan-ho PAK ,  Hae-kyoung KIM

Inventor： Sang-hyuk SUH ,  Chan-ho PAK ,  Hae-kyoung KIM

IPC: B01J31/06

CPC classification number: H01M4/92 ,  B01J31/08 ,  B01J31/28 ,  B01J2231/42 ,  B01J2231/52 ,  B01J2231/70 ,  B82Y30/00 ,  H01M4/926

Abstract: The invention provides and a highly-dispersed supported catalyst that has a reduced average particle size of catalytic metal particles and is also supported by a porous support material. A method of preparing a supported catalyst that can reduce the average particle size of catalytic metal particles supported by a support material includes first mixing a charged support material with a solution containing a polymer electrolyte having a charge opposite to that of the support material to adsorb the polymer electrolyte on the support material. Next, the support material having the polymer electrolyte adsorbed thereon is mixed with a solution containing a catalytic metal precursor ion having a charge opposite to that of the polymer electrolyte to adsorb the catalytic metal precursor ion on the support material having the polymer electrolyte adsorbed on it. Finally, the catalytic metal precursor ion adsorbed on the support material having the polymer electrolyte adsorbed thereon is reduced to a catalytic metal in a reducing solution.

Abstract translation: 本发明提供了一种具有降低的催化金属颗粒的平均粒度的高度分散的负载型催化剂，并且还由多孔载体材料支撑。 制备能够降低由载体材料负载的催化金属颗粒的平均粒径的负载催化剂的方法包括首先将带电荷的载体材料与含有与载体材料相反的电荷的聚合物电解质的溶液混合以吸附 聚合物电解质在支撑材料上。 接着，将其上吸附有聚合物电解质的载体材料与含有与聚合物电解质相反的电荷的催化金属前体离子的溶液混合，以将催化金属前体离子吸附在吸附有聚合物电解质的载体材料上 。 最后，吸附在其上吸附有聚合物电解质的载体材料上的催化金属前体离子被还原为还原溶液中的催化金属。