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    Method of coating a catalyst to a support for use in acrolein oxidation
    21.
    发明授权
    Method of coating a catalyst to a support for use in acrolein oxidation 有权
    将催化剂涂布到用于丙烯醛氧化的载体上的方法

    公开(公告)号：US06632772B2

    公开(公告)日：2003-10-14

    申请号：US09746773

    申请日：2000-12-22

    Applicant: Won-Ho Lee ,  Kyung-Hwa Kang ,  Dong-Hyun Ko ,  Young-Chang Byun

    Inventor： Won-Ho Lee ,  Kyung-Hwa Kang ,  Dong-Hyun Ko ,  Young-Chang Byun

    IPC: B01J2108

    CPC classification number: B01J23/8885 ,  B01J37/0036 ,  B01J37/0232

    Abstract: A method of coating a catalyst to a support for use in acrolein oxidation reaction. Metallic salt components of the catalyst including molybdate, vanadate and tungstate are dissolved in a liquid to form a suspension of particles of the catalyst. The precipitation of the catalyst particles is controlled by homogenizing the catalyst particles suspended in the liquid. The phase separation between the catalyst particles and the liquid can be substantially slowed down by the homogenization. Then the catalyst is coated on an inert support by applying the suspension of the catalyst particles to the support. In the suspension, the total weight of water is about 0.8 to about 5 times of the total weight of the metallic salts in the catalyst. This method of preparing suspension minimizes the amount of the liquid required to dissolve the metallic salts, which reduces the amount of time and energy to be used in evaporating the liquid from the suspension. Additionally, in obtaining catalyst from the suspension prepared by this method, it is possible to avoid the deterioration of the catalytic performance since less heat is required to evaporate the water.

    Abstract translation: 将催化剂涂布在用于丙烯醛氧化反应的载体上的方法。 包括钼酸盐，钒酸盐和钨酸盐在内的催化剂的金属盐组分溶解在液体中以形成催化剂颗粒的悬浮液。 通过使悬浮在液体中的催化剂颗粒均质化来控制催化剂颗粒的沉淀。 催化剂颗粒和液体之间的相分离可以通过均化显着减慢。 然后通过将催化剂颗粒的悬浮液施加到载体上将催化剂涂覆在惰性载体上。 在悬浮液中，水的总重量为催化剂中金属盐总重量的约0.8至约5倍。 这种制备悬浮液的方法使溶解金属盐所需的液体量最小化，这减少了用于从悬浮液蒸发液体的时间和能量的量。 另外，在通过该方法制备的悬浮液中获得催化剂时，可以避免催化性能的劣化，因为需要较少的热来蒸发水。

    Process for the production of an oxidation catalyst on-line
    22.
    发明授权
    Process for the production of an oxidation catalyst on-line 失效
    在线生产氧化催化剂的方法

    公开(公告)号：US06365543B1

    公开(公告)日：2002-04-02

    申请号：US09388218

    申请日：1999-09-01

    Applicant: Lanny D. Schmidt ,  Ashish Bodke

    Inventor： Lanny D. Schmidt ,  Ashish Bodke

    IPC: B01J2300

    CPC classification number: C10G11/02 ,  B01J23/40 ,  B01J23/42 ,  B01J35/06 ,  B01J37/0201 ,  B01J37/0232 ,  C07C5/48 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/48 ,  C07C2527/224 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/02

    Abstract: A process and catalyst for the partial oxidation of paraffinic hydrocarbons, such as ethane, propane, naphtha, and natural gas condensates, to olefins, such as ethylene and propylene. The process involves contacting a paraffinic hydrocarbon with oxygen in the presence of a catalyst under autothermal process conditions. The catalyst comprises a Group 8B metal and, optionally, a promoter metal, such as tin or copper, supported on a fiber monolith support, preferably a ceramic fiber mat monolith. In another aspect, the invention is a process of oxidizing a paraffinic hydrocarbon to an olefin under autothermal conditions in the presence of a catalyst comprising a Group 8B metal and, optionally, a promoter metal, the metals being loaded onto the front face of a monolith support. An on-line method of synthesizing and regenerating catalysts for autothermal oxidation processes is also disclosed.

    Abstract translation: 用于将链烷烃（例如乙烷，丙烷，石脑油和天然气）部分氧化的方法和催化剂冷凝成烯烃，例如乙烯和丙烯。 该方法包括在自热过程条件下在催化剂存在下使链烷烃与氧接触。 该催化剂包含8B族金属和任选的负载在纤维整料载体上，优选陶瓷纤维垫料整料的助催化剂金属，例如锡或铜。 在另一方面，本发明是在含有第8B族金属和任选的助催化剂金属的催化剂存在下，在自热条件下将链烷烃烃氧化成烯烃的方法，将金属加载到整料的正面上 支持。 还公开了用于自热氧化方法的催化剂的合成和再生的在线方法。

    Photooxidation catalyst and manufacturing method therefor
    24.
    发明申请
    Photooxidation catalyst and manufacturing method therefor 失效
    光氧化催化剂及其制备方法

    公开(公告)号：US20020002112A1

    公开(公告)日：2002-01-03

    申请号：US09886836

    申请日：2001-06-21

    Inventor： Keiichi Muramatsu

    IPC: B01J023/00

    CPC classification number: B01J37/0244 ,  B01J21/063 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0228 ,  B01J37/0232

    Abstract: This invention relates to a photocatalyst and a manufacturing method therefore, in which the adhesion to a support is increased and a baking step is simplified. The photocatalyst comprises the support and a metallic oxide layer provided on the support by applying and baking a colloidal solution including at least a metallic oxide precursor on the support, wherein the metallic oxide layer includes a high density metallic oxide layer of a less porous structure and a low density metallic oxide layer of a more porous structure.

    Abstract translation: 本发明涉及一种光催化剂及其制造方法，其中对载体的粘附性增加并且烘烤步骤简化。 所述光催化剂包括载体和金属氧化物层，所述金属氧化物层通过在载体上施加和烘烤至少包含金属氧化物前体的胶体溶液而形成，其中所述金属氧化物层包括具有较小孔结构的高密度金属氧化物层， 更多孔结构的低密度金属氧化物层。

    Catalyst and process for preparing and using same
    26.
    发明授权
    Catalyst and process for preparing and using same 失效
    催化剂及其制备和使用方法

    公开(公告)号：US6117813A

    公开(公告)日：2000-09-12

    申请号：US874635

    申请日：1997-06-13

    Applicant: John R. McCauley ,  J. Gary McDaniel

    Inventor： John R. McCauley ,  J. Gary McDaniel

    IPC: B01D53/86 ,  B01J23/63 ,  B01J23/78 ,  B01J23/83 ,  B01J37/02 ,  B01J23/02 ,  B01J23/10 ,  B01J23/76

    CPC classification number: B01D53/864 ,  B01J23/63 ,  B01J23/78 ,  B01J23/83 ,  B01J37/0232

    Abstract: The invention is a catalyst composition and process for making and using the catalyst composition. The catalyst composition promotes the combustion of carbon monoxide to carbon dioxide. The catalyst composition includes an effective concentration of Group VIII transition metal oxide, an effective concentration of Group IIIB transition metal oxide, an effective concentration of Group IIA alkaline earth metal oxide, and, desirably, microspheroidal alumina. The preferred Group VIII transition metal oxide is cobalt oxide. The preferred Group IIIB transition metal oxide is lanthanum oxide. The preferred Group IIA alkaline earth metal is strontium oxide. The process is for producing a combustion promotor catalyst of carbon monoxide to carbon dioxide. The carrier for the catalyst is effective in FCC units when used on a support which is other than a mullite-containing support.

    Abstract translation: 本发明是催化剂组合物和制备和使用催化剂组合物的方法。 催化剂组合物促进一氧化碳向二氧化碳的燃烧。 催化剂组合物包括有效浓度的第Ⅷ族过渡金属氧化物，IIIB族过渡金属氧化物的有效浓度，IIA族碱土金属氧化物的有效浓度，以及理想的微球氧化铝。 优选的VIII族过渡金属氧化物是氧化钴。 优选的IIIB族过渡金属氧化物是氧化镧。 优选的IIA族碱土金属是氧化锶。 该方法用于生产一氧化碳至二氧化碳的燃烧促进剂催化剂。 当用于不同于含莫来石的载体的载体上时，用于催化剂的载体在FCC装置中是有效的。

    Method for producing coating powders catalysts and drier water-borne coatings by spraying compositions with compressed fluids
    27.
    发明授权
    Method for producing coating powders catalysts and drier water-borne coatings by spraying compositions with compressed fluids 失效
    通过用压缩流体喷涂组合物来生产涂层粉末催化剂和干燥剂水性涂料的方法

    公开(公告)号：US5716558A

    公开(公告)日：1998-02-10

    申请号：US338900

    申请日：1994-11-14

    Applicant: Kenneth Andrew Nielsen ,  John Nicholas Argyropoulos ,  Burkhard Eric Wagner

    Inventor： Kenneth Andrew Nielsen ,  John Nicholas Argyropoulos ,  Burkhard Eric Wagner

    IPC: B01D1/18 ,  B01J37/02 ,  B05D1/02 ,  C08J3/12 ,  C09D5/02 ,  B29B9/10

    CPC classification number: B05D1/025 ,  B01D1/18 ,  B01J37/0232 ,  C08J3/122 ,  C09D5/021 ,  B05D2401/90

    Abstract: This invention relates to methods for spraying liquid compositions containing volatile solvent by using compressed fluids, such as carbon dioxide or ethane, to form solid particulates, coating powders, and catalyst materials, which can be produced with narrow particle size distributions and can be sprayed at higher solids levels, in ambient air or with heated air applied to just the spray instead of a spray chamber. Novel catalyst supports can be produced having a beneficial morphology such as for olefin catalysis. Drier water-borne coatings can be applied to substrates by using compressed fluids to spray water-borne coating compositions having conventional water levels, thereby reducing runs and sags and shortening dry times.

    Abstract translation: 本发明涉及通过使用压缩流体如二氧化碳或乙烷喷射含有挥发性溶剂的液体组合物以形成固体颗粒，涂料粉末和催化剂材料的方法，其可以以窄的粒度分布产生并且可以在 更高的固体含量，在环境空气中或加热的空气仅施加喷雾而不是喷雾室。 可以生产具有有利形态的新型催化剂载体，例如用于烯烃催化。 干燥剂水性涂料可以通过使用压缩流体喷涂具有常规水含量的水性涂料组合物施加到基材上，从而减少流动和下垂并缩短干燥时间。

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