Low-temperature fabrication of glass optical components
    24.
    发明授权
    Low-temperature fabrication of glass optical components 有权
    玻璃光学元件的低温制造

    公开(公告)号:US07143609B2

    公开(公告)日:2006-12-05

    申请号:US10283402

    申请日:2002-10-29

    Abstract: A method is provided for molding from glass certain complex optical components, such as lenses, microlens, arrays of microlenses, and gratings or surface-relief diffusers having fine or hyperfine microstructures suitable for optical or electro-optical applications. Thereby, mold masters or patterns, which define the profile of the optical components, made on metal alloys, particularly titanium or nickel alloys, or refractory compositions, with or without a non-reactive coating are used. Given that molding optical components from oxide glasses has numerous drawbacks, it has been discovered in accordance with the invention that non-oxide glasses substantially eliminates these drawbacks. The non-oxide glasses, such as chalcogenide, chalcohalide, and halide glasses, may be used in the mold either in bulk, planar, or power forms. In the mold, the glass is heated to about 10–110° C., preferably about 50° C., above its transition temperature (Tg), at which temperature the glass has a viscosity that permits it to flow and conform exactly to the pattern of the mold.

    Abstract translation: 提供了一种用于从玻璃模制某些复合光学部件的方法,诸如透镜,微透镜,微透镜阵列,以及具有适合于光学或电光学应用的精细或超细微结构的光栅或表面浮雕扩散器。 因此,使用限定在具有或不具有非反应性涂层的金属合金,特别是钛或镍合金或耐火材料组合物上制成的光学部件的轮廓的模具主体或图案。 鉴于来自氧化物玻璃的成型光学部件具有许多缺点,根据本发明已经发现,非氧化物玻璃基本上消除了这些缺点。 非氧化物玻璃,例如硫族化物,卤化铝和卤化物玻璃可以以体积,平面或电力形式用于模具中。 在模具中,将玻璃加热至约10-110℃,优选约50℃,高于其转变温度(Tg),在该温度下,玻璃具有允许其流动并准确地符合 模具图案。

    Gallium lanthanum sulfide glasses and optical waveguides and devices using such glasses
    26.
    发明申请
    Gallium lanthanum sulfide glasses and optical waveguides and devices using such glasses 有权
    镓镧硫化物玻璃和使用这种玻璃的光波导和器件

    公开(公告)号:US20030118315A1

    公开(公告)日:2003-06-26

    申请号:US10210074

    申请日:2002-08-02

    Abstract: A new and improved hybrid of Ga:La:S (GLS) glass is provided, namely a glass comprising gallium sulfide, lanthanum oxide, and at least 2 mol % lanthanum fluoride. The Ga:La:S:O:F (GLSOF) glass retains the important properties of the Ga:La:S system, while introducing improved thermal stability and spectroscopic properties. In addition, GLSOF glasses are non-toxic. The glass formation region for GLSOF has been carefully evaluated with compositional variations. It has been identified that an area of glass formation as indicated by circles, is a new and previously undiscovered glass formation region.

    Abstract translation: 提供了一种新的改进的Ga:La:S(GLS)玻璃的混合物,即包含硫化镓,氧化镧和至少2mol%氟化镧的玻璃。 Ga:La:S:O:F(GLSOF)玻璃保留了Ga:La:S系统的重要性质,同时引入了改进的热稳定性和光谱性质。 另外,GLSOF眼镜是无毒的。 GLSOF的玻璃形成区域已经通过组成变化进行了仔细的评估。 已经确定,由圆形表示的玻璃形成区域是新的和先前未发现的玻璃形成区域。

    Process for removing hydrogen and carbon impurities from glasses by
adding a tellurium halide
    27.
    发明授权
    Process for removing hydrogen and carbon impurities from glasses by adding a tellurium halide 失效
    通过加入卤化碲从玻璃中除去氢和碳杂质的方法

    公开(公告)号:US5779757A

    公开(公告)日:1998-07-14

    申请号:US670910

    申请日:1996-06-26

    Abstract: Hydrogen and/or carbon impurities are removed from chalcogenide or chalcoide glasses by the addition of a halide, such as TeCl.sub.4, to the batch composition. During melting of the batch composition, the metal halide reacts with the hydrogen and/or carbon impurities to form a hydrogen halide and/or carbon tetrahalide gas and a metal which becomes incorporated into the chalcogen-based glass. Useful halides include halides of sulfur, selenium, tellurium, polonium, or halides of a metal (such as aluminum, magnesium, zirconium, or a mixture thereof) that forms a stable oxide. Mixed metal halides may also be used. The glass melt is then distilled, outgassed, homogenized, fined, and annealed. An apparatus specially designed for making a fiber preform by the above process is also described. An annealed preform made by this method may be drawn into a low-loss fiber in the 2 .mu.m to 12 .mu.m range.

    Abstract translation: 氢和/或碳杂质通过向批料组合物中加入卤化物如TeCl 4从硫族化物或卤代卤素玻璃中除去。 在批量组合物熔化期间,金属卤化物与氢和/或碳杂质反应形成卤化氢和/或四卤化碳气体,以及掺入硫属元素玻璃中的金属。 有用的卤化物包括形成稳定氧化物的金属(例如铝,镁,锆或其混合物)的硫,硒,碲,onium或卤化物的卤化物。 也可以使用混合金属卤化物。 然后将玻璃熔体蒸馏,除气,均化,精制和退火。 还描述了通过上述方法专门设计用于制造纤维预制件的装置。 通过该方法制备的退火预制件可以被拉制成2μm至12μm范围内的低损耗纤维。

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