公开(公告)号：US4082633A

公开(公告)日：1978-04-04

申请号：US639977

申请日：1975-12-11

Applicant: Jozef Willem Eerkens

Inventor： Jozef Willem Eerkens

IPC: B01D59/34 ,  B01J19/12 ,  G02B27/00 ,  H01S3/08 ,  B01J1/10 ,  B01K1/00

CPC classification number: B01J19/121 ,  B01D59/34 ,  H01S3/08009

Abstract: An isotope separation arrangement for separating a preselected isotope from a mixture of chemically identical but isotopically different molecules by either photon-induced pure rovibrational or vibronic selective excitation of the molecules containing the atoms of the isotope to be separated from a lower to a higher energy state, and a chemical reaction of the higher energy state molecules with a chemically reactive agent to form a chemical compound containing primarily the atoms of isotope to be separated in a physicochemical state different from the physicochemical state of the mixture of chemically identical but isotopically different molecules. The chemical compound containing the atoms of the isotope to be separated may be subsequently processed to obtain the isotope.

公开(公告)号：US4080274A

公开(公告)日：1978-03-21

申请号：US585573

申请日：1975-06-10

Applicant: Sheldon Irwin Schlesinger

Inventor： Sheldon Irwin Schlesinger

IPC: B01J19/12 ,  C08F2/50 ,  C08G59/68 ,  C08G65/26 ,  B01J1/10 ,  G03C1/54 ,  G03C1/70

CPC classification number: B01J19/12 ,  C08G59/688 ,  C08G65/2615

Abstract: Polymerization of polymerizable compositions comprising mixtures of lactones with monomeric or prepolymeric epoxides is effected by mixing such compositions with radiation-sensitive aromatic diazonium salts which decompose upon application of energy such as electromagnetic radiation to release Lewis Acid to initiate polymerization of said monomers.

Abstract translation: 包含内酯与单体或预聚环氧化物的混合物的可聚合组合物的聚合通过将这些组合物与辐射敏感的芳族重氮盐混合来实现，所述辐射敏感性芳族重氮盐在施加诸如电磁辐射的能量之间分解以释放路易斯酸以引发所述单体的聚合。

公开(公告)号：US4075073A

公开(公告)日：1978-02-21

申请号：US771858

申请日：1977-02-23

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: C07C409/16 ,  B01J1/10

CPC classification number: C07C409/16 ,  C07C407/00 ,  C07C407/003

Abstract: A method for synthesizing bis(perfluoro-t-butyl) peroxide through the photolysis of perfluoro-t-butyl hypofluorite in the presence of tetrafluorohydrazine.

Abstract translation: 在四氟肼存在下，通过全氟叔丁基次氟化物的光解，合成双（全氟叔丁基）过氧化物的方法。

公开(公告)号：US4064025A

公开(公告)日：1977-12-20

申请号：US744475

申请日：1976-11-24

Applicant: Hao-Lin Chen

Inventor： Hao-Lin Chen

IPC: B01D59/34 ,  B01J19/12 ,  B01J1/10

CPC classification number: B01D59/34 ,  B01J19/122

Abstract: Separation of isotopes, particularly of carbon or nitrogen, is achieved by the selective photodissociation of an azo compound or a diazoalkane, particularly azomethane or diazomethane.

Abstract translation: 通过偶氮化合物或重氮烷烃，特别是氮甲烷或重氮甲烷的选择性光解来实现同位素特别是碳或氮的分离。

公开(公告)号：US4056455A

公开(公告)日：1977-11-01

申请号：US701819

申请日：1976-07-01

Applicant: Rudolf Lademann ,  Franz Landauer ,  Heinrich Lenzmann ,  Klaus Schmiedel ,  Wolfram Schwiersch

Inventor： Rudolf Lademann ,  Franz Landauer ,  Heinrich Lenzmann ,  Klaus Schmiedel ,  Wolfram Schwiersch

IPC: B01J19/12 ,  C07C17/00 ,  C07C17/14 ,  C07C22/04 ,  C07C22/06 ,  C07C25/02 ,  C07C67/00 ,  B01J1/10

CPC classification number: C07C17/14

Abstract: Continuous preparation of mono- or di-(trichloromethyl)-benzenes or of mono- or di-(trichloromethyl)-benzenes substituted in the benzene ring by halogen atoms from the corresponding mono- or dimethylbenzenes and chlorine in several steps with radiation by means of rays of high energy, is effected by reacting mono- or dimethylbenzene with chlorine in 4 to 14 steps, at a temperature in the range of from 20.degree. to 130.degree. C, whereby chlorine is introduced into the second step and the following steps, the resulting waste gas is introduced into step 1 and chlorine contained in the waste gas is reacted in reactor 1 with fresh mono- and dimethylbenzene. A preferred embodiment for carrying out the process is reaction in a reactor arrangement in cascade form, wherein the number of steps corresponds to the number of reactors and wherein as reactors circulation reactors are used.

公开(公告)号：US4053380A

公开(公告)日：1977-10-11

申请号：US676517

申请日：1976-04-13

Applicant: Yoshiji Fujita ,  Yoshiaki Omura ,  Fumio Mori ,  Kazuo Itoi ,  Takashi Nishida ,  Yoshin Tamai ,  Sukeji Aihara ,  Takeo Hosogai ,  Fumio Wada

Inventor： Yoshiji Fujita ,  Yoshiaki Omura ,  Fumio Mori ,  Kazuo Itoi ,  Takashi Nishida ,  Yoshin Tamai ,  Sukeji Aihara ,  Takeo Hosogai ,  Fumio Wada

IPC: C07C17/00 ,  C07C17/10 ,  C07C17/25 ,  C07C17/278 ,  C07C17/35 ,  C07C17/358 ,  C07C17/361 ,  C07C21/02 ,  C07C21/04 ,  C07C29/62 ,  C07C31/36 ,  C07C43/12 ,  C07C43/174 ,  B01J1/10

CPC classification number: C07C17/25 ,  C07C17/00 ,  C07C17/10 ,  C07C17/278 ,  C07C17/35 ,  C07C17/358 ,  C07C17/361 ,  C07C17/363 ,  C07C21/02 ,  C07C21/04 ,  C07C29/62 ,  C07C31/36 ,  C07C43/12 ,  C07C43/174

Abstract: 1,1,1-Trihalogeno-4-methyl pentenes and 1,1-dihalogeno-4-methyl-1,3-pentadienes are produced. These compounds are of value as intermediates for the production of pyrethrin analogs which are of use as insecticides or agricultural chemicals.

公开(公告)号：US4039411A

公开(公告)日：1977-08-02

申请号：US591706

申请日：1975-06-30

Applicant: Jaime A. Woodroffe ,  James C. Keck

Inventor： Jaime A. Woodroffe ,  James C. Keck

IPC: B01D59/34 ,  B01D59/50 ,  G02B27/00 ,  B01J1/10 ,  B01K1/00

CPC classification number: B01D59/50 ,  Y10S62/914 ,  Y10S62/919

Abstract: A system for isotope separation or enrichment wherein molecules of a selected isotope type in a flow of molecules of plural isotope types are vibrationally excited and collided with a background gas to provide enhanced diffusivity for the molecules of the selected isotope type permitting their separate collection. The system typically is for the enrichment of uranium using a uranium hexafluoride gas in combination with a noble gas such as argon. The uranium hexafluoride molecules having a specific isotope of uranium are vibrationally excited by laser radiation. The vibrational energy is converted to a translation energy upon collision with a particle of the background gas and the added translation energy enhances the diffusivity of the selected hexafluoride molecules facilitating its condensation on collection surfaces provided for that purpose. This process is periodically interrupted and the cryogenic flow halted to permit evaporation of the collected molecules to provide a distinct, enriched flow.

Abstract translation: 用于同位素分离或富集的系统，其中多个同位素类型的分子流中的选择的同位素类型的分子被振动激发并与背景气体碰撞，以提供允许其分离收集的所选同位素类型的分子的增强的扩散性。 该系统通常是使用六氟化铀气体与惰性气体如氩气组合来富集铀。 具有特定铀同位素的六氟化铀分子被激光辐射振动激发。 当与背景气体的颗粒碰撞时，振动能量被转化为平移能量，并且所添加的平移能量增强了所选择的六氟化物分子的扩散性，从而促使其在为此目的提供的收集表面上冷凝。 周期性地中断该过程，并且停止低温流以允许收集的分子蒸发以提供不同的富集流。

公开(公告)号：US4035270A

公开(公告)日：1977-07-12

申请号：US570877

申请日：1975-04-23

Applicant: Richard K. Lyon ,  Andrew Kaldor

Inventor： Richard K. Lyon ,  Andrew Kaldor

IPC: B01D59/34 ,  G02B27/00 ,  B01J1/10

CPC classification number: B01D59/34

Abstract: The instant invention relates to a process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in said material. More particularly, the invention relates to a method for the isotopically selective excitation of gas phase UF.sub.6 by infrared photon absorption followed by selective reaction of said excited UF.sub.6 with atomic chlorine, bromine, or iodine to form a product which may be separated by means known in the art.

Abstract translation: 本发明涉及将材料分离成两个或更多个部分的方法，其中每个部分中给定元素的同位素的丰度与所述材料中相同材料的同位素的丰度不同。 更具体地说，本发明涉及一种用于通过红外光子吸收然后被所述激发的UF6与原子氯，溴或碘的选择性反应同时选择性激发气相UF6的方法，以形成可通过已知的方法分离的产物 艺术。

公开(公告)号：US4032477A

公开(公告)日：1977-06-28

申请号：US668291

申请日：1976-03-18

Applicant: Michael Gratzel

Inventor： Michael Gratzel

IPC: B01J19/12 ,  C01B3/04 ,  C09K3/00 ,  B01J1/10

CPC classification number: B01J19/122 ,  C01B3/042 ,  Y02E60/364

Abstract: An enhanced electron yield is obtained during irradiation of a sensibilizer with light in the presence of water when a hydrophobic organic material is present as a separate phase having an electron repelling surface in contact with the water and containing the sensibilizer.

公开(公告)号：US4029559A

公开(公告)日：1977-06-14

申请号：US697000

申请日：1976-06-17

Applicant: John B. Marling

Inventor： John B. Marling

IPC: B01D59/34 ,  B01J19/12 ,  C01B4/00 ,  B01J1/10

CPC classification number: B01J19/121 ,  B01D59/34 ,  C01B4/00

Abstract: Enrichment of carbon, hydrogen and/or oxygen isotopes by means of isotopically selective photo-predissociation of formaldehyde is achieved by irradiation with a fixed frequency ion laser, specifically, a neon, cadmium, or xenon ion laser.

Abstract translation: 通过使用固定频率离子激光器，特别是氖，镉或氙离子激光器照射来实现通过甲醛的同位素选择性光预解离来富集碳，氢和/或氧同位素。