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1.发明授权Epoxide photopolymerizable compositions containing cyclic amides as gelation inhibitor and methods of polymerizing 失效含环状酰胺作为凝胶抑制剂的环氧化物可光聚合组合物和聚合方法
公开(公告)号：US3951769A
公开(公告)日：1976-04-20
申请号：US447209
申请日：1974-03-01
Applicant: Sheldon Irwin Schlesinger
Inventor： Sheldon Irwin Schlesinger
IPC: C08F2/00 , C08F2/48 , C08G2/00 , C08G2/06 , C08G59/00 , C08G59/18 , C08G59/68 , C08G63/00 , C08G63/08 , C08G63/78 , C08G63/82 , C08G65/00 , C09D163/00 , G03F7/027 , B01J1/10 , G03C1/70
CPC classification number: G03F7/027 , C08G59/18 , Y10S528/935
Abstract: Polymerization of epoxides and mixtures of epoxides with lactones and vinyl compounds, polymerizable through the action of cationic catalysts, is controlled by providing, in association with a radiation-sensitive catalyst precursor, a gelation inhibitor in the form of a cyclic amide in which the amide nitrogen atom contains unsubstituted hydrogen.
Abstract translation: 环氧化物和环氧化物与内酯和乙烯基化合物的混合物的聚合可通过阳离子催化剂的作用聚合，通过与辐射敏感性催化剂前体相结合地提供环酰胺形式的凝胶抑制剂来控制，其中酰胺 氮原子含有未取代的氢。
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公开(公告)号：US4100321A
公开(公告)日：1978-07-11
申请号：US690307
申请日：1976-05-26
Applicant: Sheldon Irwin Schlesinger , Ronald J. Boszak
Inventor： Sheldon Irwin Schlesinger , Ronald J. Boszak
CPC classification number: G03F7/0217 , C08G59/686 , G03F7/28 , Y10S430/115 , Y10S430/12 , Y10T428/24835 , Y10T428/24901
Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, non-exposed area of the coating, resulting in a pigmented image.
Abstract translation: 丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物和衍生自可聚合混合物的缩水甘油基甲基丙烯酸酯加成的三元共聚物，其特性粘度在约0.09至0.28的范围内，环氧当量为至少约0.64 / 100g。 的聚合物，其与作为复合卤化物的辐射敏感性芳基重氮盐的催化剂混合，提供适用于干燥光聚合物阳性成像方法的组合物。 在此过程中，将室温下非粘性的聚合物与催化剂一起施加到基底上并暴露于例如通过透明或掩模的电磁辐射的能量源。 曝光后，涂层被加热到涂层的未曝光部分的软化点，并且向其施加粉末或调色剂，调色剂仅粘附到涂层的粘性未曝光区域，导致着色图像。
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公开(公告)号：US4054732A
公开(公告)日：1977-10-18
申请号：US690308
申请日：1976-05-26
Applicant: Sheldon Irwin Schlesinger , Ronald J. Boszak
Inventor： Sheldon Irwin Schlesinger , Ronald J. Boszak
IPC: C08G59/68 , G03F7/021 , G03F7/28 , C08F216/14 , C08F220/32
CPC classification number: G03F7/0217 , C08G59/686 , G03F7/28
Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, non-exposed area of the coating, resulting in a pigmented image.
Abstract translation: 丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物和衍生自可聚合混合物的缩水甘油基甲基丙烯酸酯加成的三元共聚物，其特性粘度在约0.09至0.28的范围内，环氧当量为至少约0.64 / 100g。 的聚合物，其与作为复合卤化物的辐射敏感性芳基重氮盐的催化剂混合，提供适用于干燥光聚合物阳性成像方法的组合物。 在此过程中，将室温下非粘性的聚合物与催化剂一起施加到基底上并暴露于例如通过透明或掩模的电磁辐射的能量源。 曝光后，涂层被加热到涂层的未曝光部分的软化点，并且向其施加粉末或调色剂，调色剂仅粘附到涂层的粘性未曝光区域，导致着色图像。
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Patent Agency Ranking
公开(公告)号：US4091194A
公开(公告)日：1978-05-23
申请号：US690309
申请日：1976-05-26
Applicant: Sheldon Irwin Schlesinger , Ronald J. Boszak
Inventor： Sheldon Irwin Schlesinger , Ronald J. Boszak
CPC classification number: G03F7/0217 , C08G59/686 , G03F7/28 , Y10S430/115 , Y10S430/12 , Y10T428/24835 , Y10T428/24901
Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, non-exposed area of the coating, resulting in a pigmented image.
Abstract translation: 丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物和衍生自可聚合混合物的缩水甘油基甲基丙烯酸酯加成的三元共聚物，其特性粘度在约0.09至0.28的范围内，环氧当量为至少约0.64 / 100g。 的聚合物，其与作为复合卤化物的辐射敏感性芳基重氮盐的催化剂混合，提供适用于干燥光聚合物阳性成像方法的组合物。 在此过程中，将室温下非粘性的聚合物与催化剂一起施加到基底上并暴露于例如通过透明或掩模的电磁辐射的能量源。 曝光后，涂层被加热到涂层的未曝光部分的软化点，并且向其施加粉末或调色剂，调色剂仅粘附到涂层的粘性未曝光区域，导致着色图像。
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5.发明授权
公开(公告)号：US3988159A
公开(公告)日：1976-10-26
申请号：US375348
申请日：1973-07-02
Applicant: Sheldon Irwin Schlesinger
Inventor： Sheldon Irwin Schlesinger
CPC classification number: G03C1/73
Abstract: The use of photosensitive nitrones in an imageformation system, if desired with auxiliary compounds for intensifying the photolytically formed image or for improving the fixing of the image, wherein the image is fixed by the use of heat.
Abstract translation: 在图像形成系统中使用光敏硝酸盐，如果需要，可以使用用于增强光解形成图像的辅助化合物或改善图像的定影，其中通过使用热固定图像。
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6.发明授权Photopolymerization of lactone-epoxide mixtures with aromatic diazonium salts as photocatalyst 失效内酯 - 环氧化物混合物与芳族重氮盐的光聚合作为光催化剂
公开(公告)号：US4080274A
公开(公告)日：1978-03-21
申请号：US585573
申请日：1975-06-10
Applicant: Sheldon Irwin Schlesinger
Inventor： Sheldon Irwin Schlesinger
CPC classification number: B01J19/12 , C08G59/688 , C08G65/2615
Abstract: Polymerization of polymerizable compositions comprising mixtures of lactones with monomeric or prepolymeric epoxides is effected by mixing such compositions with radiation-sensitive aromatic diazonium salts which decompose upon application of energy such as electromagnetic radiation to release Lewis Acid to initiate polymerization of said monomers.
Abstract translation: 包含内酯与单体或预聚环氧化物的混合物的可聚合组合物的聚合通过将这些组合物与辐射敏感的芳族重氮盐混合来实现，所述辐射敏感性芳族重氮盐在施加诸如电磁辐射的能量之间分解以释放路易斯酸以引发所述单体的聚合。
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7.发明授权Dry photopolymer imaging article having a diazonium salt and epoxide copolymer 失效具有重氮盐和环氧化物共聚物的干燥光聚合物成像制品
公开(公告)号：US4076536A
公开(公告)日：1978-02-28
申请号：US690310
申请日：1976-05-26
Applicant: Sheldon Irwin Schlesinger , Ronald J. Boszak
Inventor： Sheldon Irwin Schlesinger , Ronald J. Boszak
CPC classification number: G03F7/0217 , C08G59/686 , G03F7/28 , Y10S430/115 , Y10S430/12 , Y10T428/24835 , Y10T428/24901
Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, nonexposed area of the coating, resulting in a pigmented image.
Abstract translation: 丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物和衍生自可聚合混合物的缩水甘油基甲基丙烯酸酯加成的三元共聚物，其特性粘度在约0.09至0.28的范围内，环氧当量为至少约0.64 / 100g。 的聚合物，其与作为复合卤化物的辐射敏感性芳基重氮盐的催化剂混合，提供适用于干燥光聚合物阳性成像方法的组合物。 在此过程中，将室温下非粘性的聚合物与催化剂一起施加到基底上并暴露于例如通过透明或掩模的电磁辐射的能量源。 曝光后，涂层被加热到涂层的未曝光部分的软化点，并且将粉末或调色剂施加到其上，调色剂仅粘附在涂层的粘性，非曝光区域，导致着色图像。
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8.发明授权Dry positive photopolymer imaging process involving heating and application of toner 失效干正相光聚合物成像工艺涉及加热和应用调色剂
公开(公告)号：US3997344A
公开(公告)日：1976-12-14
申请号：US486169
申请日：1974-07-05
Applicant: Sheldon Irwin Schlesinger , Ronald J. Boszak
Inventor： Sheldon Irwin Schlesinger , Ronald J. Boszak
CPC classification number: G03F7/0217 , C08G59/686 , G03F7/28 , Y10S430/115 , Y10S430/12 , Y10T428/24835 , Y10T428/24901
Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, non-exposed area of the coating, resulting in a pigmented image.
Abstract translation: 丙烯酸缩水甘油酯和烯丙基缩水甘油醚的共聚物和衍生自可聚合混合物的缩水甘油基甲基丙烯酸酯加成的三元共聚物，其特性粘度在约0.09至0.28的范围内，环氧当量为至少约0.64 / 100g。 的聚合物，其与作为复合卤化物的辐射敏感性芳基重氮盐的催化剂混合，提供适用于干燥光聚合物阳性成像方法的组合物。 在此过程中，将室温下非粘性的聚合物与催化剂一起施加到基底上并暴露于例如通过透明或掩模的电磁辐射的能量源。 曝光后，涂层被加热到涂层的未曝光部分的软化点，并且向其施加粉末或调色剂，调色剂仅粘附到涂层的粘性未曝光区域，导致着色图像。
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