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    Process for the hydroformylation of an ethylenically unsaturated compound
    34.
    发明授权
    Process for the hydroformylation of an ethylenically unsaturated compound 失效
    烯键式不饱和化合物加氢甲酰化的方法

    公开(公告)号：US07414155B2

    公开(公告)日：2008-08-19

    申请号：US11759623

    申请日：2007-06-07

    Applicant: Eit Drent ,  Roelof Van Ginkel ,  Willem Wabe Jager

    Inventor： Eit Drent ,  Roelof Van Ginkel ,  Willem Wabe Jager

    IPC: C07F9/02 ,  C07F7/08

    CPC classification number: B01J31/2433 ,  B01J31/2476 ,  B01J31/248 ,  B01J31/28 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/824 ,  C07C45/50 ,  C07C67/347 ,  C07F9/65683 ,  C07C69/675 ,  C07C69/716 ,  C07C47/02

    Abstract: Process for the hydroformylation of an optionally substituted ethylenically unsaturated compound by reaction thereof with carbon monoxide and hydrogen in the presence of a specific catalyst system which includes a source of Group VIII metal cations; a diphosphine ligand having the general formula (I): X1—R—X2   (I) wherein X1 and X2 each independently represent an optionally substituted cyclic group with at least 5 ring atoms, of which one is a phosphorus atom, and R represents a bivalent optionally substituted bridging group which is connected to each phosphorus atom by a sp2 hybridized carbon atom; an acid having a pKa

    Abstract translation: 在包含第VIII族金属阳离子源的特定催化剂体系的存在下，通过与一氧化碳和氢气反应，任选取代的烯键式不饱和化合物的加氢甲酰化方法; 具有通式（I）的二膦配体：<？in-line-formula description =“In-line Formulas”end =“lead”？> X SUP>（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X 1和X 2各自独立地表示 任选取代的具有至少5个环原子的环状基团，其中一个是磷原子，R代表二价任选取代的桥连基团，其通过sp2-2杂交的碳原子连接到每个磷原子上 ; 具有pK 3的酸; 和卤素阴离子的来源。

    PROCESS FOR THE HYDROFORMYLATION OF AN ETHYLENICALLY UNSATURATED COMPOUND
    35.
    发明申请
    PROCESS FOR THE HYDROFORMYLATION OF AN ETHYLENICALLY UNSATURATED COMPOUND 失效
    乙烯化合物的水解方法

    公开(公告)号：US20070238892A1

    公开(公告)日：2007-10-11

    申请号：US11759623

    申请日：2007-06-07

    Applicant: Eit DRENT ,  Roelof VAN GINKEL ,  Willem JAGER

    Inventor： Eit DRENT ,  Roelof VAN GINKEL ,  Willem JAGER

    IPC: C07F9/28 ,  C07F15/00

    CPC classification number: B01J31/2433 ,  B01J31/2476 ,  B01J31/248 ,  B01J31/28 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/824 ,  C07C45/50 ,  C07C67/347 ,  C07F9/65683 ,  C07C69/675 ,  C07C69/716 ,  C07C47/02

    Abstract: Process for the hydroformylation of an optionally substituted ethylenically unsaturated compound by reaction thereof with carbon monoxide and hydrogen in the presence of a specific catalyst system. The specific catalyst system comprises: (a) a source of group VIII metal cations; (b) a diphosphine ligand having the general formula I X1—R—X2  (I) wherein X1 and X2 each independently represent an optionally substituted cyclic group with at least 5 ring atoms, of which one is a phosphorus atom, and R represents a bivalent optionally substituted bridging group, connected to each phosphorus atom by a sp2 hybridized carbon atom; (c) an acid having a pKa

    Abstract translation: 在特定催化剂体系存在下，通过与一氧化碳和氢气反应，任选取代的烯属不饱和化合物的加氢甲酰化方法。 具体的催化剂体系包括：（a）VIII族金属阳离子源; （b）具有通式I <β的二膦配体，其中-in-line-formula description =“In-line Formulas”end =“lead”→> X SUP>（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X 1和X 2各自独立地表示 任选取代的具有至少5个环原子的环状基团，其中一个是磷原子，R代表二价任意取代的桥连基团，通过sp2杂化的碳原子连接到每个磷原子上; （c）在18℃的水溶液中测得的pKa <3的酸或其衍生的盐; 和（d）卤化物阴离子源。 此外，还描述了在该方法中使用的一些具体的二齿二膦。

    Alkali-free demercaptanization catalyst for hydrocarbon compositions
    38.
    发明授权
    Alkali-free demercaptanization catalyst for hydrocarbon compositions 失效
    用于烃组合物的无碱非硫醇化催化剂

    公开(公告)号：US07087547B2

    公开(公告)日：2006-08-08

    申请号：US10451259

    申请日：2001-03-29

    Applicant: Alexei Konovalov ,  Vladimir Smirnov ,  Vladimir Konovalov ,  Irina Tarkhanova

    Inventor： Alexei Konovalov ,  Vladimir Smirnov ,  Vladimir Konovalov ,  Irina Tarkhanova

    IPC: B01J31/02 ,  B01J31/22 ,  C08F4/42

    CPC classification number: B01J27/122 ,  B01J23/70 ,  B01J31/0237 ,  B01J31/0247 ,  B01J31/0249 ,  B01J31/28 ,  C10G27/04 ,  C10G27/10

    Abstract: A catalyst for oxidative demercaptanization of hydrocarbon compositions, comprising 0.2–5% of an oxide selected from the group consisting of an oxide of a transition metal of group Ib, an oxide of a transition metal of group Vb, an oxide of a transition metal of group VIb, an oxide of a transition metal of group VIIb, a nickel oxide, a cobalt oxide, and a mixture of at least two of said oxides; 0.5–20% of a transition metal salt; 0.5–20% of a nitrogen-containing organic compound; and an inert component, the rest up to 100%; wherein, the above described catalyst is used for demercaptanization or sweetening of hydrocarbon compositions.

    Abstract translation: 一种用于烃组合物氧化脱硫化的催化剂，其包含0.2-5％的选自Ib族过渡金属的氧化物，Vb族过渡金属的氧化物，过渡金属的氧化物， VIb族，第VIIb族过渡金属的氧化物，氧化镍，氧化钴和至少两种所述氧化物的混合物; 0.5〜20％的过渡金属盐; 0.5-20％的含氮有机化合物; 和惰性组分，其余达100％; 其中，上述催化剂用于烃组合物的脱硫或脱硫。

    Catalytic method for the production of carbonyl compounds
    39.
    发明申请
    Catalytic method for the production of carbonyl compounds 有权
    用于生产羰基化合物的催化方法

    公开(公告)号：US20060135817A1

    公开(公告)日：2006-06-22

    申请号：US10534878

    申请日：2003-11-14

    Applicant: Franco Antognoli ,  Paul Rys

    Inventor： Franco Antognoli ,  Paul Rys

    IPC: C07C45/28

    CPC classification number: B01J31/0218 ,  B01J31/0215 ,  B01J31/28 ,  B01J2231/70 ,  C07C45/28

    Abstract: The invention relates to a catalytic method for the production of aliphatic and aromatic carbonyl compounds with at least one aldehyde or ketone function, whereby said compounds can also comprise at least one aldehyde and ketone function. A starting material comprising at least one aliphatic- and/or aromatic-bonded functional group of formula (I), where R1=H, alkyl or aryl, X=H, or a group which may be substituted by the sulphinyl group of a sulphoxide during the catalytic reaction, n=a whole number from 1 to 8, is oxidised in the presence of a sulphoxide and/or a sulphide and the presence of iron salts or redox pairs of iron/copper or silver/copper salts, by means of an oxidising agent with a redox potential of Eo>+2 V vs. NHE, whereby the sulphoxide or sulphide has a catalytic function. The method permits the production of carbonyl compounds, in particular, (poly)aldehydes and (poly)ketones with high selectivity, whereby the formation of alcohols and carboxylic acids, dimerisation products and other by-products is reduced to a minimum or essentially prevented. The final products obtained find application as important intermediates and final products.

    Abstract translation: 本发明涉及一种生产具有至少一种醛或酮官能团的脂族和芳族羰基化合物的催化方法，其中所述化合物还可以包含至少一种醛和酮官能团。 包含至少一种式（I）的脂族 - 和/或芳基键合官能团的起始材料，其中R 1 = H，烷基或芳基，X = H或可以是 在催化反应期间由亚砜的亚磺酰基取代，n = 1至8的整数，在亚砜和/或硫化物的存在下被氧化，并且铁/铜的铁盐或氧化还原对的存在或 银/铜盐，通过氧化还原电位与NHE的氧化还原电位相反，由此亚砜或硫化物具有催化功能。 该方法允许以高选择性生产羰基化合物，特别是（多）醛和（聚）酮，由此将醇和羧酸，二聚产物和其它副产物的形成降低到最小或基本上被预防。 获得的最终产品可用作重要的中间体和最终产品。

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