公开(公告)号：US20100063333A1

公开(公告)日：2010-03-11

申请号：US12520497

申请日：2007-12-20

Applicant: Andre Petitjean ,  Michel Strebelle ,  Andre Devos

Inventor： Andre Petitjean ,  Michel Strebelle ,  Andre Devos

IPC: C07C17/08 ,  B01J27/24 ,  B01J31/00 ,  B01J31/02

CPC classification number: B01J31/28 ,  B01J31/0231 ,  B01J31/0237 ,  B01J31/0271 ,  B01J31/24 ,  B01J31/30 ,  C07C1/26 ,  C07C17/10 ,  C07C2529/40 ,  C07C9/00 ,  C07C19/075

Abstract: Catalytic hydrochlorination system comprising at least one amine hydrochloride and at least one group VIII metal compound chosen from the group composed of mixtures of a platinum (IV) compound with tin (II) chloride, mixtures of a platinum (II) compound with triphenylphosphine oxide and mixtures of a palladium (II) compound with triphenylphosphine. This catalytic system is suitable for preparing vinyl chloride by reaction of acetylene with hydrogen chloride.

Abstract translation: 包含至少一种胺盐酸盐和至少一种VIII族金属化合物的催化氢氯化体系，其选自铂（IV）化合物与氯化锡（II）的混合物，铂（II）化合物与三苯基氧化膦的混合物和 钯（II）化合物与三苯基膦的混合物。 该催化体系适用于通过乙炔与氯化氢的反应来制备氯乙烯。

公开(公告)号：US20110077366A1

公开(公告)日：2011-03-31

申请号：US12995518

申请日：2009-05-29

Applicant: Andre Petitjean ,  Michel Lempereur ,  Dominique Balthasart ,  Michel Strebelle

Inventor： Andre Petitjean ,  Michel Lempereur ,  Dominique Balthasart ,  Michel Strebelle

IPC: C08F2/00 ,  C07C17/02

CPC classification number: C07C19/045 ,  C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  Y02P20/582 ,  C07C21/06

Abstract: Process for the manufacture of at least one ethylene derivative compound starting from a low value residual gas, preferably a refinery off-gas (ROG), according to which: a) the low value residual gas is subjected to a series of treatment steps in a low value residual gas recovery unit in order to remove the undesirable components present therein and to obtain a mixture of products containing ethylene and other constituents; b) the mixture of products is fractionated in one fractionation step into one fraction A containing almost all the ethylene, optionally into one individual fraction of ethane, and into one heavy fraction C; and c) the fraction A is conveyed to the manufacture of at least one ethylene derivative compound.

Abstract translation: 用于从低值残余气体，优选炼油厂废气（ROG）开始制造至少一种乙烯衍生物化合物的方法，其中：a）将低价值残余气体经受一系列处理步骤 低值残余气体回收装置，以除去其中存在的不期望的组分并获得含有乙烯和其它组分的产物的混合物; b）将产物的混合物在一个分馏步骤中分馏成含有几乎所有乙烯的一个馏分A，任选地分成一个单独的乙烷馏分，并分成一个重馏分C; 和c）将馏分A输送至制造至少一种乙烯衍生物化合物。

公开(公告)号：US20100331587A1

公开(公告)日：2010-12-30

申请号：US12919101

申请日：2009-02-20

Applicant: Andre Petitjean ,  Michel Lempereur ,  Dominique Balthasart ,  Michel Strebelle ,  Massimo Giansante

Inventor： Andre Petitjean ,  Michel Lempereur ,  Dominique Balthasart ,  Michel Strebelle ,  Massimo Giansante

IPC: C07C5/09

CPC classification number: C07C17/02 ,  C07C17/156 ,  C07C17/25 ,  C07C19/045 ,  Y02P20/582 ,  C07C21/06

Abstract: Process for the manufacture of at least one ethylene derivative compound starting from a low value residual gas, preferably a ROG, according to which:a) the low value residual gas is subjected to a series of treatment steps in a low value residual gas recovery unit in order to remove the undesirable components present therein and to obtain a mixture of products containing ethylene and other constituents;b) the said mixture of products is separated into a fraction enriched with compounds which are lighter than ethylene, containing part of the ethylene (fraction A), into a fraction enriched with ethylene (fraction B) and into a heavy fraction (fraction C);c) fraction A and fraction B are separately conveyed to the manufacture of at least one ethylene derivative compound.

Abstract translation: 用于从低值残留气体（优选ROG）开始制造至少一种乙烯衍生物的方法，其中：a）低值残留气体在低值残余气体回收单元中进行一系列处理步骤 以除去其中存在的不期望的组分并获得含有乙烯和其它组分的产物的混合物; b）将所述产物混合物分离成富含化合物的馏分，所述化合物比乙烯轻，含有部分乙烯（馏分A））成为富含乙烯（馏分B）的馏分和重馏分（馏分C） ; c）馏分A和馏分B分别输送至制造至少一种乙烯衍生物化合物。

公开(公告)号：US20070142682A1

公开(公告)日：2007-06-21

申请号：US10579094

申请日：2004-11-12

Applicant: Michel Strebelle ,  Andre Petitjean

Inventor： Michel Strebelle ,  Andre Petitjean

IPC: C07C19/00

CPC classification number: C07C17/156 ,  B01J21/04 ,  B01J21/063 ,  B01J23/72 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8926 ,  B01J27/122 ,  B01J27/138 ,  C07C17/152 ,  C07C17/154 ,  C07C45/33 ,  C07C19/045

Abstract: The invention provides a catalyst containing active elements including copper deposited on alumina containing at least 0.03 g of titanium, expressed in metal form, per kg of alumina and use thereof in gas hase reactions, such as the oxychlorination of ethylene to 1,2-dichloroethane. This catalyst is suitable for maintaining a constant oxygen content in the tail gases and hence in the recycled gases. The invention further pertains to the use of an alumina containing at least 0.03g titanium, expressed in metal form, per Kg of alumina, as catalyst support and as catalyst diluent. In an example a catalyst containing CuCl2, MgCl2, KCl and LiCl deposited on alumina containing 1.13 g of titanium, expressed in metal form, per Kg of alumina was used for the oxychlorination of ethylene to 1,2-dichloroethane in a fluidized bed reactor.

Abstract translation: 本发明提供一种含有活性元素的催化剂，其包含沉积在氧化铝上的含有至少0.03g钛（以金属形式表示）/ kg氧化铝的活性元素及其在气体反应中的用途，例如乙烯氧化成1,2-二氯乙烷 。 该催化剂适用于保持尾气中的氧含量恒定，因此适用于回收气体中。 本发明还涉及使用含有至少0.03g钛（以金属形式表示，每Kg氧化铝）作为催化剂载体和作为催化剂稀释剂的氧化铝。 在一个实例中，使用沉积在氧化铝上的含有CuCl 2，MgCl 2，KCl和LiCl的催化剂，该氧化铝含有1.13g以金属形式表示的钛/ Kg氧化铝，其用于 在流化床反应器中乙烯氧化成1,2-二氯乙烷。

公开(公告)号：US07612244B2

公开(公告)日：2009-11-03

申请号：US10579094

申请日：2004-11-12

Applicant: Michel Strebelle ,  Andre Petitjean

Inventor： Michel Strebelle ,  Andre Petitjean

IPC: C07C19/00 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC classification number: C07C17/156 ,  B01J21/04 ,  B01J21/063 ,  B01J23/72 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8926 ,  B01J27/122 ,  B01J27/138 ,  C07C17/152 ,  C07C17/154 ,  C07C45/33 ,  C07C19/045

Abstract: The invention provides a catalyst containing active elements including copper deposited on alumina containing at least 0.03 g of titanium, expressed in metal form, per kg of alumina and use thereof in gas hase reactions, such as the oxychlorination of ethylene to 1,2-dichloroethane. This catalyst is suitable for maintaining a constant oxygen content in the tail gases and hence in the recycled gases. The invention further pertains to the use of an alumina containing at least 0.03g titanium, expressed in metal form, per Kg of alumina, as catalyst support and as catalyst diluent. In an example a catalyst containing CuCl2, MgCl2, KCl and LiCl deposited on alumina containing 1.13 g of titanium, expressed in metal form, per Kg of alumina was used for the oxychlorination of ethylene to 1,2-dichloroethane in a fluidized bed reactor.

Abstract translation: 本发明提供一种含有活性元素的催化剂，其包含沉积在氧化铝上的含有至少0.03g钛（以金属形式表示）/ kg氧化铝的活性元素及其在气体反应中的用途，例如乙烯氧化成1,2-二氯乙烷 。 该催化剂适用于保持尾气中的氧含量恒定，因此适用于回收气体中。 本发明还涉及使用含有至少0.03g钛（以金属形式表示，每Kg氧化铝）作为催化剂载体和作为催化剂稀释剂的氧化铝。 在一个实例中，在流化床反应器中，使用沉积在氧化铝上的含有1.13g以金属形式表示的钛（以Kg为单位的氧化铝）的催化剂，用于将乙烯氧氯化成1,2-二氯乙烷。

公开(公告)号：US20080214879A1

公开(公告)日：2008-09-04

申请号：US11914048

申请日：2005-05-12

Applicant: Michel Strebelle ,  Andre Petitjean

Inventor： Michel Strebelle ,  Andre Petitjean

IPC: C07C17/152 ,  B01J23/72 ,  B01J21/04

CPC classification number: B01J23/72 ,  B01J23/78 ,  C07C17/156 ,  C07C19/045

Abstract: Oxychlorination catalyst containing at least copper as an active element deposited on a support characterized in that the support consists essentially of an alumina obtained by calcination of an alumina hydrate obtained as by-product of the ALFOL® linear primary alcohol process and use of such catalyst in an oxychlorination process of a hydrocarbon containing 1 to 4 carbon atoms.

Abstract translation: 至少含有铜作为沉积在载体上的活性元素的氧氯化催化剂，其特征在于载体主要由氧化铝组成，该氧化铝通过煅烧作为ALFOL线性伯醇方法的副产物获得的氧化铝水合物而获得， 催化剂在含有1至4个碳原子的烃的氧氯化过程中。