Free radical post-crosslinked adsorbent and method of preparation
    31.
    发明授权
    Free radical post-crosslinked adsorbent and method of preparation 有权
    自由基后交联吸附剂及其制备方法

    公开(公告)号:US08076384B2

    公开(公告)日:2011-12-13

    申请号:US12456019

    申请日:2009-06-10

    Abstract: A post-crosslinked adsorbent comprises: monomer units of (a) at least 55 wt % at least one polyvinylaromatic monomer and (b) up to 45 wt % at least one monovinylaromatic monomer; and 0.5-2.5 mmol/g pendent vinyl groups; wherein the dry adsorbent has BET specific surface area in the range of about 650-1000 m2/g, BET average pore diameter 7.2-10 nm, BET porosity 1.29-2.45 mL/g, BJH adsorption micropore volume was less than 20% of total BJH adsorption pore volume, and HK micropore volume was less than 21% of total BJH adsorption pore volume. The invention is also directed to a preparation method for the polymeric adsorbent.

    Abstract translation: 后交联吸附剂包括:(a)至少55重量%的至少一种聚乙烯基芳族单体和(b)至多45重量%的至少一种单乙烯基芳族单体的单体单元; 和0.5-2.5mmol / g悬挂的乙烯基; 其中所述干吸附剂的BET比表面积为约650-1000m2 / g,BET平均孔径为7.2-10nm,BET孔隙率为1.29-2.45mL / g,BJH吸附微孔体积小于总吸附量的20% BJH吸附孔体积和HK微孔体积小于总BJH吸附孔体积的21%。 本发明还涉及聚合物吸附剂的制备方法。

    Process for producing porous polyimide resin and porous polymide resin
    34.
    发明申请
    Process for producing porous polyimide resin and porous polymide resin 有权
    多孔聚酰亚胺树脂和多孔聚酰胺树脂的制造方法

    公开(公告)号:US20040101626A1

    公开(公告)日:2004-05-27

    申请号:US10380178

    申请日:2003-03-13

    Abstract: A method of producing porous polyimide resin that enables pores to be formed in a precursor of polyimide resin, with its form of microphase-separated structure wherein a dispersive compound is dispersed in the precursor of polyimide resin being kept unchanged, so as to provide significantly reduced dielectric constant and also provide improvement in mechanical strength and heat resistance, and the porous polyimide resin produced in the same producing method. A coating comprising porous polyimide resin is formed by applying resin solution comprising a precursor of polyimide resin and a dispersive compound and then drying a solvent, to form a coating in which the dispersive compound is dispersed in the precursor of polyimide resin; extracting the dispersive compound from the coating for removal to make the precursor of the polyimide resin porous; and imidizing the coating after preheated in a temperature range of 190-250null C.

    Abstract translation: 在聚酰亚胺树脂的前体中形成多孔聚酰亚胺树脂的方法,其形成微相分离结构,其中分散化合物分散在聚酰亚胺树脂的前体中保持不变,从而显着降低 介电常数并且还提供机械强度和耐热性的改善,以及以相同的制造方法制造的多孔聚酰亚胺树脂。 包含多孔聚酰亚胺树脂的涂层是通过涂布包括聚酰亚胺树脂前体和分散化合物的树脂溶液形成的,然后干燥溶剂,形成其中分散化合物分散在聚酰亚胺树脂的前体中的涂层; 从涂层中提取分散化合物以除去以使聚酰亚胺树脂的前体多孔; 并在190-250℃的温度范围内预热后对涂层进行酰亚胺化

    Nanoporous polymer films for extreme low and interlayer dielectrics
    35.
    发明授权
    Nanoporous polymer films for extreme low and interlayer dielectrics 失效
    用于极低和层间电介质的纳米多孔聚合物膜

    公开(公告)号:US06187248B1

    公开(公告)日:2001-02-13

    申请号:US09196452

    申请日:1998-11-19

    Abstract: A process for producing a nanoporous polymer film of no greater than 10 micron thickness having low dielectric constant value, including the steps of: (a) providing a polymer in a solution with at least two solvents for the polymer in which a lowest boiling solvent and a highest boiling solvent have a difference in their respective boiling points of approximately 50° C. or greater; (b) forming a film of the polymer in solution with at least the two solvents on a substrate; (c) removing a predominant amount of the lowest boiling solvent; (d) contacting the film with a fluid which is a non-solvent for the polymer, but which is miscible with the at least two solvents to induce phase inversion in the film; (e) forming an average pore size in the film in the range of less than 30 nanometers. The present invention is also nanoporous films made by the above process.

    Abstract translation: 一种用于制备具有低介电常数值的不大于10微米厚度的纳米多孔聚合物膜的方法,包括以下步骤:(a)在聚合物中提供聚合物至少两种溶剂,其中最低沸点溶剂和 最高沸点溶剂的沸点相差约为50℃以上; (b)在基材上用至少两种溶剂在溶液中形成聚合物膜; (c)除去主要量的最低沸点溶剂; (d)使膜与用于聚合物的非溶剂的流体接触,但与至少两种溶剂可混溶以在膜中诱导相转化; (e)在小于30纳米的范围内形成膜中的平均孔径。本发明还是通过上述方法制备的纳米多孔膜。

    Video attachment to a microscope
    37.
    发明授权
    Video attachment to a microscope 失效
    视频附件到显微镜

    公开(公告)号:US5568188A

    公开(公告)日:1996-10-22

    申请号:US336869

    申请日:1994-11-09

    CPC classification number: A61B3/132 A61B3/135 G02B21/362 C08J2201/0502

    Abstract: The video attachment is an apparatus to be mounted laterally on a microscope and which is independent of the optic of the microscope. The apparatus comprises an imaging lens system and a video camera. The light beam path in the apparatus is deflected in such a manner that the video camera does not impede the use of the microscope. The video attachment is preferably used with a microscope of a slit lamp for the diagnosis of the eye.

    Abstract translation: 视频附件是横向安装在显微镜上并且与显微镜的光学元件无关的装置。 该装置包括成像透镜系统和摄像机。 装置中的光束路径被偏转,使得摄像机不会妨碍显微镜的使用。 视频附件优选与用于诊断眼睛的裂隙灯的显微镜一起使用。

    Microporous isocyanate-based polymer compositions and method of
preparation
    38.
    发明授权
    Microporous isocyanate-based polymer compositions and method of preparation 失效
    微孔异氰酸酯基聚合物组合物及其制备方法

    公开(公告)号:US5478867A

    公开(公告)日:1995-12-26

    申请号:US268059

    申请日:1994-06-29

    Applicant: Ricky L. Tabor

    Inventor: Ricky L. Tabor

    Abstract: A novel microporous isocyanate-based xerogel composition is disclosed. The composition can be prepared by a method comprising (1) (1) admixing (a) a polyisocyanate component, (b) a substantially unreactive solvent, and, optionally, (c) a polymerization catalyst, water, an active-hydrogen compound or a mixture thereof, provided that (c) is included wherein (b) does not also function to catalyze polymerization; under reaction conditions sufficient to form a gel; and (2) removing the solvent under non-supercritical conditions sufficient to form a microporous xerogel composition. The compositions can be readily evacuated for use in thermal insulative applications such as vacuum panels, for uses such as appliance insulation, which show superior K-factor values when compared with, for example, conventional rigid polyurethane open-cell foams as used in similar applications.

    Abstract translation: 公开了一种新型的微孔异氰酸酯基干凝胶组合物。 组合物可以通过以下方法制备:(1)(1)混合(a)多异氰酸酯组分,(b)基本上不反应的溶剂,和任选地(c)聚合催化剂,水,活性氢化合物或 其包含(c)的混合物,其中(b)也不起催化聚合的作用; 在足以形成凝胶的反应条件下; 和(2)在足以形成微孔干凝胶组合物的非超临界条件下除去溶剂。 组合物可以容易地排出用于热绝缘应用,例如真空面板,用于诸如器具绝缘的用途,当与类似应用中使用的常规刚性聚氨酯开孔泡沫相比时,其显示出优异的K因子值 。

    Process for the production of microporous polybenzimidazole articles
    39.
    发明授权
    Process for the production of microporous polybenzimidazole articles 失效
    生产微孔聚苯并咪唑制品的方法

    公开(公告)号:US4828699A

    公开(公告)日:1989-05-09

    申请号:US87548

    申请日:1987-08-20

    Inventor: John W. Soehngen

    Abstract: Disclosed herein are microporous polybenzimidazole articles prepared by the addition of a leachable additive to a polybenzimidazole polymer solution or dope and the subsequent leaching of the additive from the polybenzimidazole article. The microporous polybenzimidazole article may be formed into filaments or films. The micropores of the microporous polybenzimidazole article may be filled with an absorbent resin which will act to absorb chemicals or other harmful products. The microporous polybenzimidazole article with absorbent material may be formed into clothing which is highly resistant to both chemicals and heat.

    Abstract translation: 本文公开了通过向聚苯并咪唑聚合物溶液或涂料中加入可浸出添加剂并随后从聚苯并咪唑制品中浸出添加剂而制备的微孔聚苯并咪唑制品。 微孔聚苯并咪唑制品可以形成长丝或薄膜。 微孔聚苯并咪唑制品的微孔可以填充吸收树脂,其吸收化学物质或其它有害物质。 具有吸收材料的微孔聚苯并咪唑制品可以形成为对化学品和热均具有高度抗性的衣服。

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