REACTIVE MEMBRANE NETWORKS FOR CWA PROTECTION

    公开(公告)号:US20220062885A1

    公开(公告)日:2022-03-03

    申请号:US17009582

    申请日:2020-09-01

    Abstract: A membrane includes a first layer, and a second layer coupled to the first layer. The second layer includes a network of catalytic sites, each catalytic site having a catalytic center characterized by promoting a chemical reaction of a target material. A method of forming a chemically reactive membrane includes applying a first solution to a structure, the first solution includes a macrocyclic ligand having electron-donating ligands and a side functional group for crosslinking, crosslinking a plurality of the macrocyclic ligand to form a first network of crosslinked macrocyclic ligands, and applying a second solution to the structure, the second solution comprising a catalytic center. Each catalytic center complexes with the electron-donating ligands of each macrocyclic ligand to form catalytic sites in the first network of crosslinked macrocyclic ligands.

    Metal supported powder catalyst matrix and processes for multiphase chemical reactions

    公开(公告)号:US11224853B2

    公开(公告)日:2022-01-18

    申请号:US17043882

    申请日:2018-04-11

    Abstract: A catalytic membrane composite that includes porous supported catalyst particles durably enmeshed in a porous fibrillated polymer membrane is provided. The porous fibrillated polymer membrane may be manipulated to take the form of a tube, disc, or diced tape and used in multiphase reaction systems. The supported catalyst particles are composed of at least one finely divided metal catalyst dispersed on a porous support substrate. High catalytic activity is gained by the effective fine dispersion of the finely divided metal catalyst such that the metal catalyst covers the support substrate and/or is interspersed in the pores of the support substrate. In some embodiments, the catalytic membrane composite may be introduced to a stirred tank autoclave reactor system, a continuous flow reactor system, or a Parr Shaker reaction system and used to effect the catalytic reaction.

    Catalytic efficiency of flue gas filtration

    公开(公告)号:US11071947B2

    公开(公告)日:2021-07-27

    申请号:US17083077

    申请日:2020-10-28

    Abstract: Some embodiments of the present disclosure relate to a method of regenerating at least one filter medium comprising: providing at least one filter medium, wherein the at least one filter medium comprises: at least one catalyst material; and ammonium bisulfate (ABS) deposits, ammonium sulfate (AS) deposits, or any combination thereof; flowing a flue gas stream transverse to a cross-section of a filter medium, such that the flue gas stream passes through the cross section of the at least one filter medium, wherein the flue gas stream comprises: NOx compounds comprising: Nitric Oxide (NO), and Nitrogen Dioxide (NO2); and increasing an NOx removal efficiency of the at least one filter medium after removal of deposits.

    METHOD FOR PRODUCING TRANSITION ALUMINA CATALYST MONOLITHS

    公开(公告)号:US20210213423A1

    公开(公告)日:2021-07-15

    申请号:US15733841

    申请日:2019-05-28

    Applicant: BASF SE

    Abstract: A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising the following steps: a) Preparing a suspension paste in a liquid diluent of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and which suspension can furthermore comprise a binder material in a maximum amount of 20 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and/or a plasticizer and/or a dopant in a maximum amount of 10 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 μm, b) extruding the paste of step a) through one or more nozzles to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the porous catalyst monolith precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor of step c) at a temperature in the range of from 500 to 1000° C., to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface of the transition alumina precursor particles, the catalyst monolith precursor or transition alumina catalyst monolith. no further catalytically active metals, metal oxides or metal compounds are present in the suspension paste.

Patent Agency Ranking