公开(公告)号：US20160272491A1

公开(公告)日：2016-09-22

申请号：US15036810

申请日：2014-11-14

Applicant: SHANGHAI HYDROGEN MOBILE REFRMER INSTRUMENT CO. LTD.

Inventor： HUA XIANG ,  DEFU XIANG ,  JINGJING SUN

IPC: C01B3/32 ,  C01B3/56 ,  B01J7/02

CPC classification number: C01B3/323 ,  B01J7/02 ,  B01J8/0403 ,  B01J19/242 ,  B01J19/243 ,  B01J2208/00141 ,  B01J2208/00415 ,  B01J2208/00716 ,  B01J2219/00083 ,  B01J2219/00135 ,  B01J2219/1944 ,  C01B3/505 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/1604 ,  Y02P20/128 ,  Y02P30/30

Abstract: Disclosed are a quick-start system for preparing hydrogen via aqueous methanol, and hydrogen preparation method. The system comprises a liquid storage container, a raw material feeding device, a quick-start device, a hydrogen preparation equipment and a membrane separation device; the quick-start device comprises a first start device and a second start device; the first start device comprises a first heating mechanism and a first gasification pipeline, the first gasification pipeline is wound around the first heating mechanism; one end of the first gasification pipeline is connected to the liquid storage container, and methanol is fed into the first gasification pipeline via the raw material feeding device, for the first heating mechanism to heat and gasify; the hydrogen preparation equipment comprises a reforming chamber; the second start device comprises a second gasification pipeline, a main body of the second gasification pipeline is disposed in the reforming chamber; the methanol output by the first gasification pipeline and/or the second gasification pipeline heats the second gasification pipeline while heating the reforming chamber, to gasify the methanol in the second gasification pipeline. The present invention can be quickly started, while having less energy consumption and good practicability.

Abstract translation: 公开了一种通过甲醇水溶液制备氢气的快速启动系统，以及氢气制备方法。 该系统包括液体储存容器，原料供给装置，快速启动装置，氢气制备装置和膜分离装置; 快速启动装置包括第一启动装置和第二启动装置; 第一启动装置包括第一加热机构和第一气化管道，第一气化管道围绕第一加热机构缠绕; 第一气化管道的一端与储液容器连接，经由原料供给装置将甲醇送入第一气化管路，第一加热机构进行加热气化; 氢气制备设备包括重整室; 第二启动装置包括第二气化管道，第二气化管道的主体设置在重整室中; 由第一气化管道和/或第二气化管道输出的甲醇在加热重整室的同时加热第二气化管道，使第二气化管道中的甲醇气化。 本发明可以快速启动，同时具有较少的能量消耗和良好的实用性。

公开(公告)号：US20160272489A1

公开(公告)日：2016-09-22

申请号：US15032606

申请日：2014-10-28

Applicant: TEMASEK POLYTECHNIC

Inventor： Lei Wang ,  Ming Han ,  Yunzhong Chen ,  Ee Ho Gareth Tang

IPC: C01B3/06 ,  B01J7/02 ,  H01M8/1018 ,  B01J23/42 ,  B01J31/06 ,  H01M8/065 ,  C01B3/00 ,  B01J21/18

CPC classification number: C01B3/065 ,  B01J7/02 ,  B01J21/18 ,  B01J23/42 ,  B01J31/06 ,  B01J2231/005 ,  B01J2531/005 ,  C01B3/0084 ,  H01M8/065 ,  H01M8/1018 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/324 ,  Y02E60/362

Abstract: The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibres and a binder, wherein the catalyst loaded fibres and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water.

Abstract translation: 本发明涉及固体燃料，系统和产生氢气的方法。 固体燃料包括硼氢化钠，负载催化剂的纤维和粘合剂，其中载有催化剂的纤维和粘合剂形成其中硼氢化钠被定位的支架结构。 该系统包括一个包含本发明的用于产生氢气的固体燃料的燃料盒，一个构造成容纳燃料盒的反应器，一个用于储存水的罐，一个用于将水从罐运送到燃料盒的泵和液体导管 容纳在反应器内以引起包含在燃料盒中的固体燃料的水解反应和用于调节水的流动的控制器。

公开(公告)号：US09346031B2

公开(公告)日：2016-05-24

申请号：US14382538

申请日：2012-03-20

Applicant: Moo Hwan Kim ,  Ho Seon Ahn ,  Gunyeop Park ,  Soojae Kim

Inventor： Moo Hwan Kim ,  Ho Seon Ahn ,  Gunyeop Park ,  Soojae Kim

IPC: B01J19/18 ,  B01J7/02 ,  C01D1/04 ,  B82Y40/00

CPC classification number: B01J19/18 ,  B01J7/02 ,  B01J2219/00051 ,  B82Y40/00 ,  B82Y99/00 ,  C01D1/04

Abstract: A sodium-nanoliquid reactivity experiment apparatus includes: a storage tank that stores liquid sodium; a mixing tank that is connected to the storage tank through a first transport line to receive supply of the liquid sodium and that injects nanoparticles to mix the nanoparticles with the liquid sodium; and a reactor that is connected to the mixing tank through a second transport line to receive supply of a sodium-nanoparticle mixture and that injects water to react the water with the sodium-nanoparticle mixture.

Abstract translation: 钠 - 纳米液体反应性实验装置包括：储存液体钠的储罐; 混合罐，其通过第一输送管线连接到储罐以接收液体钠的供应，并且注入纳米颗粒以将纳米颗粒与液体钠混合; 以及通过第二输送管线连接到混合罐以接收钠 - 纳米颗粒混合物的供应并且注入水以使水与钠 - 纳米颗粒混合物反应的反应器。

公开(公告)号：US20150368101A1

公开(公告)日：2015-12-24

申请号：US14745075

申请日：2015-06-19

Applicant: Cedar Ridge Research, LLC

Inventor： Larry W. Fullerton

IPC: C01B3/08 ,  B01J7/02 ,  F01B17/04 ,  H01L35/30

CPC classification number: C01B3/08 ,  B01J7/00 ,  B01J7/02 ,  B01J2219/00006 ,  C01B3/042 ,  C01B5/00 ,  C01B13/0207 ,  F01B17/04 ,  H01L35/30 ,  Y02E60/364 ,  Y02P20/129

Abstract: An aluminum-alkali hydroxide recyclable hydrogen generator is provided that enables generation of hydrogen for a consuming apparatus on demand. The hydrogen generator includes a source of aluminum, a source of a hydroxide, a source of water, and a reaction chamber, where the amount of at least one of the aluminum, sodium hydroxide, and water that is introduced into the reaction chamber is used to limit the chemical reaction to control the amount of hydrogen generated.

公开(公告)号：US09199843B2

公开(公告)日：2015-12-01

申请号：US13976862

申请日：2011-12-28

Applicant: Gilles Gonthier ,  Pierre Yvart ,  Christian Perut

Inventor： Gilles Gonthier ,  Pierre Yvart ,  Christian Perut

IPC: C01B3/08 ,  C01B3/06 ,  B01J7/02 ,  C01B3/10

CPC classification number: C01B3/06 ,  B01J7/02 ,  B01J2219/00182 ,  C01B3/065 ,  C01B3/10 ,  Y02E60/362

Abstract: The present invention relates to a process for the self-regulated production as a function of the demand, under submerged conditions, of a gas (G), said gas (G) being generated by a chemical reaction between a liquid (L) and a solid (S) (hydrogen generated by hydrolysis of a metal hydride, for example) and not being polluted between the generation thereof and the delivery thereof. The present invention also relates to a device suitable for the implementation of said process.

Abstract translation: 本发明涉及一种根据淹没条件下气体（G）的需求的自调节生产方法，所述气体（G）是由液体（L）和 固体（S）（例如通过金属氢化物的水解生成的氢），并且在其产生和其输送之间不被污染。 本发明还涉及一种适于实施所述方法的装置。

公开(公告)号：US09187325B2

公开(公告)日：2015-11-17

申请号：US13188202

申请日：2011-07-21

Applicant: Terry D. Turner ,  Bradley C. Benefiel ,  Dennis N. Bingham ,  Kerry M. Klinger ,  Bruce M. Wilding

Inventor： Terry D. Turner ,  Bradley C. Benefiel ,  Dennis N. Bingham ,  Kerry M. Klinger ,  Bruce M. Wilding

IPC: C01B3/34 ,  B01J10/00 ,  B01J19/24 ,  B01J7/02 ,  B01J4/00

CPC classification number: C01B3/348 ,  B01J4/001 ,  B01J7/02 ,  B01J10/002 ,  B01J10/005 ,  B01J19/246 ,  B01J2204/002 ,  B01J2219/00157 ,  B01J2219/00159 ,  B01J2219/0277 ,  C01B2203/0216

Abstract: Reactors for carrying out a chemical reaction, as well as related components, systems and methods are provided. In accordance with one embodiment, a reactor is provided that includes a furnace and a crucible positioned for heating by the furnace. The crucible may contain a molten salt bath. A downtube is disposed at least partially within the interior crucible along an axis. The downtube includes a conduit having a first end in communication with a carbon source and an outlet at a second end of the conduit for introducing the carbon material into the crucible. At least one opening is formed in the conduit between the first end and the second end to enable circulation of reaction components contained within the crucible through the conduit. An oxidizing material may be introduced through a bottom portion of the crucible in the form of gas bubbles to react with the other materials.

Abstract translation: 提供了进行化学反应的反应器，以及相关组件，系统和方法。 根据一个实施例，提供了一种反应器，其包括炉子和定位用于通过炉子加热的坩埚。 坩埚可以包含熔盐浴。 下管至少部分地沿轴线设置在内坩埚内。 下管包括导管，其具有与碳源连通的第一端和用于将碳材料引入坩埚的第二端处的出口。 在第一端和第二端之间的管道中形成至少一个开口，以使得包含在坩埚内的反应部件能够通过导管循环。 氧化材料可以以气泡的形式通过坩埚的底部引入，以与其它材料反应。

公开(公告)号：US09156687B2

公开(公告)日：2015-10-13

申请号：US13465863

申请日：2012-05-07

Applicant: Andrew P. Wallace ,  John M. Melack ,  Michael Lefenfeld

Inventor： Andrew P. Wallace ,  John M. Melack ,  Michael Lefenfeld

IPC: C01B3/06 ,  B01J19/00 ,  C01B3/50 ,  B01J7/02

CPC classification number: C01B3/06 ,  B01J7/02 ,  C01B3/065 ,  C01B3/501 ,  Y02E60/362

Abstract: A water reactive hydrogen generation system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is used in a fuel cell or other application. The water reactive hydrogen generation system includes a reactant fuel chamber, a reactor chamber (zone), a water solution inlet, a hydrogen output port, and a material delivery device. The material delivery device can include a drive screw and a sliding piston to move the fuel material into the reactor zone when a reaction is initiated. As the reaction takes place, the reaction waste product is removed from the reaction zone to allow additional reactant fuel materials and aqueous solutions to be introduced and to continue the hydrogen-generating reaction. A reaction waste product created is exchanged for additional reactant fuel material at determined intervals to allow the reaction to continue until the reactant fuel is exhausted.

Abstract translation: 水反应性氢生成系统包括将反应物燃料和水溶液组合以产生氢的装置和方法。 产生的氢气用于燃料电池或其他应用。 水反应性氢产生系统包括反应物燃料室，反应室（区），水溶液入口，氢输出口和物料输送装置。 当反应开始时，材料输送装置可以包括驱动螺杆和滑动活塞以将燃料材料移动到反应器区域中。 当反应发生时，将反应废物从反应区除去，以允许引入另外的反应物燃料材料和水溶液并继续发生氢反应。 将所产生的反应废物与确定的间隔交换用于附加的反应物燃料，以允许反应持续直至反应物燃料排出。

公开(公告)号：US08951312B2

公开(公告)日：2015-02-10

申请号：US13373258

申请日：2011-11-09

Applicant: Alvin Gabriel Stern

Inventor： Alvin Gabriel Stern

IPC: B01J7/00 ,  C01B3/02 ,  C01B3/08 ,  C25C1/02 ,  B01J7/02

CPC classification number: C25C1/02 ,  B01J7/02 ,  C01B3/08 ,  Y02E60/36 ,  Y02P10/212

Abstract: A compact, chemical-mechanical apparatus, having no electrical components, for storing and generating hydrogen safely, on-demand, at the time and point of use in small or large quantities using the environmentally clean chemical reaction between sodium metal and water to generate hydrogen (H2) gas and sodium hydroxide (NaOH) byproduct is presented, for powering electricity generating fuel cells for large scale commercial and private electric motor vehicle transport. The apparatus of the present invention supports hydrogen gas generation by the controlled addition of liquid water to solid sodium metal to produce hydrogen gas and sodium hydroxide using only mechanical components without electrical components that require external power and can generate sparks or short circuits, producing catastrophic failure in hydrogen systems. The sodium hydroxide can be reclaimed and recycled by electrolysis using hydroelectric power to recover the sodium metal for reuse in generating hydrogen, thereby forming a complete clean energy hydrogen power cycle.

Abstract translation: 一种紧凑的化学机械设备，没有电气部件，用于在使用时间和点使用时以安全，按需的方式储存和生成氢气，使用金属和水之间的环境清洁化学反应，以少量或大量的方式产生氢气 （H2）气和氢氧化钠（NaOH）副产物，用于为大规模商业和私人电动汽车运输的发电燃料电池供电。 本发明的装置通过将液态水控制加入到固体钠金属中来支持产生氢气，以仅使用机械部件来产生氢气和氢氧化钠，而不需要外部电力的电气部件并且可能产生火花或短路，从而产生灾难性故障 在氢气系统中。 可以通过使用水力发电的电解回收和再循环氢氧化钠，以回收钠金属，用于产生氢气再利用，从而形成完整的清洁能源氢能循环。

公开(公告)号：US08747766B2

公开(公告)日：2014-06-10

申请号：US12622546

申请日：2009-11-20

Applicant: Kenichi Noda

Inventor： Kenichi Noda

IPC: B01J35/02 ,  B01J8/02 ,  B01J19/00 ,  B01J7/02 ,  B01J33/00 ,  B01J20/28 ,  B01J35/00 ,  B01D50/00 ,  B01D53/34 ,  B01D53/22 ,  B01D59/12

CPC classification number: B01D71/022 ,  B01D53/228 ,  B01D69/02 ,  B01D2256/16 ,  B01D2323/08 ,  B01D2325/28 ,  B01J8/0257 ,  B01J19/2485 ,  B01J2208/00088 ,  B01J2219/00069 ,  C01B3/384 ,  C01B3/505 ,  C01B2203/0233 ,  C01B2203/04 ,  C01B2203/041 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/066 ,  C01B2203/0805 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1241 ,  C01B2203/1247 ,  C22C5/04 ,  Y02P20/52

Abstract: A hydrogen separation membrane comprising a palladium alloy that includes at least palladium, an added metal A, and an added metal B, the added metal A and the added metal B being two different metals other than palladium, each of the added metal A and the added metal B forming a complete solid solution with palladium, and the added metal A and the added metal B having a triple point in an equilibrium diagram and not forming an intermetallic compound. The hydrogen separation membrane exhibits excellent hydrogen permeability and durability.

Abstract translation: 一种氢分离膜，其包含至少包含钯，添加的金属A和添加的金属B的钯合金，添加的金属A和所添加的金属B是除钯之外的两种不同的金属，添加的金属A和 添加的金属B用钯形成完整的固溶体，并且添加的金属A和添加的金属B在平衡图中具有三重点而不形成金属间化合物。 氢分离膜表现出优异的透氢性和耐久性。

公开(公告)号：US20140154173A1

公开(公告)日：2014-06-05

申请号：US14235022

申请日：2012-07-24

Applicant: H2 CATALYST, LLC

Inventor： Douglas Howard Phillips

IPC: C01B3/08 ,  B01J7/02 ,  B01J19/08

CPC classification number: C01B3/08 ,  B01J7/02 ,  B01J19/087 ,  H01M8/065 ,  H01M8/0656 ,  Y02E60/36 ,  Y02E60/50

Abstract: Exemplary embodiments of methods and systems for hydrogen production using an electro-activated material are provided. In some exemplary embodiments, carbon can be electro-activated and used in a chemical reaction with water and a fuel, such as aluminum, to generate hydrogen, where the by-products are electro-activated carbon, and aluminum oxide or aluminum hydroxide. Controlling the temperature of the reaction, and the amounts of aluminum and electro-activated carbon can provide hydrogen on demand at a desired rate of hydrogen generation.

Abstract translation: 提供了使用电活化材料制氢的方法和系统的示例性实施例。 在一些示例性实施方案中，碳可以电活化并用于与水和诸如铝的燃料的化学反应以产生氢，其中副产物是电活性炭，以及氧化铝或氢氧化铝。 控制反应的温度，铝和电活性炭的量可以按需要的氢气产生速率提供氢气。