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    High Recovery Drinking Water Process
    42.
    发明申请
    High Recovery Drinking Water Process 审中-公开
    高回收饮用水过程

    公开(公告)号：US20130043190A1

    公开(公告)日：2013-02-21

    申请号：US13588272

    申请日：2012-08-17

    Applicant: Riad A. Al-Samadi

    Inventor： Riad A. Al-Samadi

    IPC: C02F1/44

    CPC classification number: C02F1/42 ,  B01D61/025 ,  B01D61/027 ,  B01D61/04 ,  B01D65/08 ,  B01D2311/04 ,  B01D2311/08 ,  B01D2321/16 ,  B01J39/07 ,  B01J41/05 ,  B01J45/00 ,  B01J49/06 ,  B01J49/07 ,  C02F1/001 ,  C02F1/283 ,  C02F1/441 ,  C02F1/442 ,  C02F5/10 ,  C02F2001/422 ,  C02F2201/005 ,  C02F2301/046 ,  C02F2303/16 ,  C02F2303/185 ,  C02F2303/22 ,  B01D2311/2623 ,  B01D2311/2649 ,  B01D2311/12

    Abstract: Disclosed is a process that uses reverse osmosis (RO) or nanofiltration (NF) membranes and ion exchange (IX) water softening resins to maximize the production of drinking water, purified industrial service water or recycled purified municipal or industrial effluents. The membrane and ion exchange units are configured in a manner that enables operation of the system at high permeate recoveries in the range 90% to 99%, thus producing purified drinking water with a minimum volume of wastewater to drains and a very low membrane cleaning or membrane replacement frequency. The process mitigates membrane fouling and scale formation and minimizes the use of water treatment chemicals including acidic and alkali solutions and sodium chloride salt that is normally required to regenerate the IX resin.

    Abstract translation: 公开了一种使用反渗透（RO）或纳滤（NF）膜和离子交换（IX）水软化树脂来最大限度地生产饮用水，纯化的工业用水或再循环纯化的市政或工业废水的方法。 膜和离子交换单元被配置为使得系统在高渗透率下的操作能够在90％至99％的范围内回收，从而产生具有最小体积废水的净化饮用水和非常低的膜清洁或 膜更换频率。 该过程减轻了膜污染和结垢形成，并且最小化了通常需要再生IX树脂的水处理化学品（包括酸性和碱性溶液和氯化钠盐）的使用。

    Ion exchange resin and a process for the use thereof
    43.
    发明授权
    Ion exchange resin and a process for the use thereof 有权
    离子交换树脂及其使用方法

    公开(公告)号：US08349051B2

    公开(公告)日：2013-01-08

    申请号：US12442358

    申请日：2007-09-21

    Applicant: Nikolai Zontov

    Inventor： Nikolai Zontov

    IPC: C22B3/26 ,  C22B3/36

    CPC classification number: C22B3/42 ,  B01J39/20 ,  B01J41/14 ,  B01J45/00 ,  C08F20/44 ,  C08F22/30 ,  C22B23/043 ,  C22B23/0461 ,  Y02P10/234 ,  Y10T428/2982

    Abstract: A process for hydro-extracting non-ferrous metals from a slurry, pulp or solution, the process including a resin which is a copolymer of a polystyrene and a non-styrenic polymer, wherein the non-styrenic polymer includes the following subunit: Formula (I) wherein Rb is a divalent linking group, preferably alkylene, and most preferably (—CH2—CH2—; and Rd is NH, NR, O or absent. Preferably the resin has an acrylic backbone.

    Abstract translation: 一种从浆液，纸浆或溶液中提取有色金属的方法，该方法包括作为聚苯乙烯和非苯乙烯聚合物的共聚物的树脂，其中非苯乙烯类聚合物包括以下亚基：式（ I）其中R b是二价连接基团，优选亚烷基，最优选（-CH 2 -CH 2 - ;且R d是NH，NR，O或不存在）。优选地，树脂具有丙烯酸主链。

    Solution of metal-polymer chelate(s) and applications thereof
    44.
    发明授权
    Solution of metal-polymer chelate(s) and applications thereof 有权
    金属 - 聚合物螯合物的溶液及其应用

    公开(公告)号：US08193291B2

    公开(公告)日：2012-06-05

    申请号：US10590637

    申请日：2005-01-31

    Applicant: Caiteng Zhang

    Inventor： Caiteng Zhang

    IPC: C08F251/00 ,  C08G79/00 ,  C09K3/00

    CPC classification number: C08B37/003 ,  A23K20/163 ,  A23K20/20 ,  A61K8/60 ,  A61K8/73 ,  A61Q11/00 ,  B01D71/00 ,  B01D2251/90 ,  B01J20/24 ,  B01J20/262 ,  B01J20/265 ,  B01J45/00 ,  C05F11/00 ,  C07H3/00 ,  C07H5/06 ,  C07H23/00 ,  C08B1/00 ,  C08B15/00 ,  C08L1/02 ,  C08L5/08 ,  D06M15/03 ,  Y02E50/343 ,  Y02W30/47

    Abstract: In a solution of metal-polymer (chelate(s) and applications thereof, a metal-polymer chelate is prepared by mixing water and R—COOH soluble carbohydride molecules and/or hydroxyl or hydroxyl amino and/or carboxyl and/or carbohydrate polymers, metal salts and/or ammonia or amines. The solution of metal-polymer chelate(s) is used extensively in different technical areas including oxidation, condensation, degradation, oxidizing condensation, gas detection, artificial imitated chitosan solution, artificial imitated glucosamine, disinfectant, biochemical reaction for fermentation, biological protein and its metabolite purification, metal enzyme biocatalyst, dry activation of protein enzyme, bacteria preservation systems, oil product, plant, semiconductor, nano filtration, nano material production, nano inorganic matter, nano ceramic, nano plastic, nano textile, battery, liquid crystal, and biochip. These reactions give effects for chemical engineering, gas removal, and waste solvent treatment.

    Abstract translation: 在金属 - 聚合物（螯合物及其应用）的溶液中，通过混合水和R-COOH可溶性碳氢化合物分子和/或羟基或羟基氨基和/或羧基和/或碳水化合物聚合物来制备金属 - 聚合物螯合物， 金属盐和/或氨或胺，金属 - 聚合物螯合物溶液广泛应用于氧化，缩合，降解，氧化缩合，气体检测，人造仿制壳聚糖溶液，人造模拟葡萄糖胺，消毒剂， 生物化学反应发酵，生物蛋白及其代谢物纯化，金属酶生物催化剂，蛋白酶干活化，细菌保存系统，油品，植物，半导体，纳米过滤，纳米材料生产，纳米无机物，纳米陶瓷，纳米塑料， 纳米织物，电池，液晶和生物芯片，这些反应对化学工程，气体去除和废溶剂处理产生了影响 的。

    Method for generating metal chelating affinity ligands
    46.
    发明授权
    Method for generating metal chelating affinity ligands 有权
    产生金属螯合亲和配体的方法

    公开(公告)号：US07988858B2

    公开(公告)日：2011-08-02

    申请号：US12297231

    申请日：2007-05-23

    Applicant: Andreas Axen ,  Jean-Luc Maloisel ,  John Clachan ,  Helena Lindgren ,  Anne Catharina Bergh

    Inventor： Andreas Axen ,  Jean-Luc Maloisel ,  John Clachan ,  Helena Lindgren ,  Anne Catharina Bergh

    IPC: B01D15/08

    CPC classification number: C07C319/22 ,  B01D15/3828 ,  B01J20/286 ,  B01J20/289 ,  B01J20/3219 ,  B01J20/3251 ,  B01J20/3265 ,  B01J45/00 ,  C07B2200/11 ,  C07C319/06 ,  C07C319/12 ,  C07K1/22 ,  C07C323/25

    Abstract: The present invention relates to a method for generating at least one polydentate metal chelating affinity ligand, which method comprises the steps of (a) providing at least one scaffold defined by the general formula (I): H2N—(X1)n—S—S—(X2)m—CH2—NH2 wherein X1 and X2 irrespective of each other are carbon atoms or heteroatoms, and n and m irrespective of each other are integers of 1 to 5; (b) providing at least one polydentate metal chelating affinity ligand arm, optionally in a form wherein the metal chelating functionalities of at least one arm are protected, on each scaffold by derivatisation of the nucleophilic NH2 groups of the scaffold; (c) reducing the disulfide bond of the derivatised scaffold; and, if required (d) deprotecting the functionalities of the ligand arm(s) provided in step (b). In the most preferred embodiment, the reduction of the disulfide bond and the deprotection step is performed essentially simultaneously.

    Abstract translation: 本发明涉及产生至少一种多齿金属螯合亲和配体的方法，该方法包括以下步骤：（a）提供由通式（I）定义的至少一种支架：H2N-（X1）n-S- S-（X2）m-CH2-NH2，其中X1和X2彼此不同，是碳原子或杂原子，n和m彼此无关，为1〜5的整数; （b）通过支架的亲核NH 2基团的衍生化，提供至少一种多齿金属螯合亲和配体臂，任选地以至少一个臂的金属螯合官能团被保护的形式保护在每个支架上; （c）减少衍生化支架的二硫键; 如果需要（d）使步骤（b）中提供的配体臂的功能脱保护。 在最优选的实施方案中，二硫键的减少和脱保护步骤基本上同时进行。

    Polyazacrown-based materials for mercury capture and synthesis of those materials
    47.
    发明授权
    Polyazacrown-based materials for mercury capture and synthesis of those materials 有权
    用于汞捕获和合成这些材料的聚镓酸盐基材料

    公开(公告)号：US07968673B2

    公开(公告)日：2011-06-28

    申请号：US12070423

    申请日：2008-02-19

    Applicant: Mikhail Y. Redko ,  James E. Jackson ,  Volodymyr Tarabara ,  Julian Taurozzi

    Inventor： Mikhail Y. Redko ,  James E. Jackson ,  Volodymyr Tarabara ,  Julian Taurozzi

    IPC: C08G73/06

    CPC classification number: C02F1/285 ,  B01J20/26 ,  B01J20/262 ,  B01J20/265 ,  B01J45/00 ,  B32B3/26 ,  C02F2101/20 ,  C08G73/06 ,  Y10T428/249978

    Abstract: Polyazacrown polymers based on the azacrown monomer 1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane (“H6Aza222”) are disclosed. Azacrown monomer units are preferably linked with a suitable linking agent, and the resulting polymers are can absorb mercury from a water stream and form a stable complex therewith. Methods of making and using the polyazacrown polymers are also disclosed. The polymers have a high absorption capacity for and selectivity towards mercury, which properties are useful for the remediation of mercury-contaminated water. The polymers can be regenerated by the efficient removal of the absorbed mercury. Further, the absorbed mercury that is liberated from the polyazacrown polymers can be effectively concentrated and captured to prevent its re-release into the environment.

    Abstract translation: 公开了基于偶氮染料单体1,4,7,10,13,16,21,24-八氮杂二环[8.8.8]二十二烷（“H6Aza222”）的聚叠冠酰胺聚合物。 偶氮染料单体单元优选与合适的交联剂连接，所得聚合物可以从水流中吸收汞并与其形成稳定的络合物。 还公开了制备和使用聚氮杂高聚物的方法。 聚合物对汞的吸收能力和选择性都很高，这些性质对于汞污染水的修复是有用的。 可以通过有效去除吸收的汞来再生聚合物。 此外，可以有效地浓缩和捕获从聚氮杂高聚物中释放的吸收的汞，以防止其再次释放到环境中。

    PICOLYLAMINE RESINS
    48.
    发明申请
    PICOLYLAMINE RESINS 有权
    PICOLYLAMINE树脂

    公开(公告)号：US20110091365A1

    公开(公告)日：2011-04-21

    申请号：US12919846

    申请日：2009-02-27

    Applicant: Reinhold Klipper ,  Michael Schelhaas ,  Duilio Rossoni

    Inventor： Reinhold Klipper ,  Michael Schelhaas ,  Duilio Rossoni

    IPC: C08F212/08 ,  C01G13/00 ,  C01G49/00 ,  C01G3/00 ,  C01G9/00 ,  C01G21/00 ,  C01G11/00 ,  C01G45/00 ,  C01G56/00 ,  C01G31/00 ,  C01G55/00 ,  C01G51/00 ,  C01G53/00 ,  C01G5/00 ,  C01G7/00

    CPC classification number: C22B3/42 ,  B01J45/00 ,  C08F8/30 ,  C08F8/34 ,  C08F8/40 ,  C08F8/44 ,  C22B11/04 ,  C22B23/00 ,  Y02P10/234 ,  C08F212/08

    Abstract: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

    Abstract translation: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或（甲基）丙烯酸化合物并且在通式（I）的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 ）作为官能团，其中R 1是由吡啶基，甲基喹啉和甲基哌啶组成的组中的任意取代的基团，R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH（ NH 2）COOR 3或-CH 2 -S-CH 2 -CH（OH）-CH 2（OH）或其衍生物或-C≡S（NH 2），R 3是由H，Na和K组成的组中的基团，m是 1〜4的整数，n和p各自独立地为0.1〜1.9的数，n和p的和为2，M为聚合物基质，其制备方法及其制备方法 尤其用于湿法冶金和电镀。

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