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51.
公开(公告)号:US20200208020A1
公开(公告)日:2020-07-02
申请号:US16643606
申请日:2018-09-14
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Eric G. Larson , Michael A. Kropp , Matthew J. Kryger , Shijing Cheng
Abstract: A thermally curable adhesive film, a tape, and a method of making the tape, wherein the film includes: a crosslinked (meth)acrylate matrix; and a thermally curable, one-part epoxy/thiol resin composition incorporated within the crosslinked (meth)acrylate matrix; wherein the thermally curable, one-part epoxy/thiol resin composition comprises: an epoxy resin component comprising an epoxy resin having at least two epoxide groups per molecule; a thiol component comprising a polythiol compound having at least two thiol groups; a nitrogen-containing catalyst for the epoxy resin; and an organic acid.
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52.
公开(公告)号:US20200207909A1
公开(公告)日:2020-07-02
申请号:US16632679
申请日:2018-08-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Joseph D. Rule , Zachary J. Thompson , Michael A. Kropp , Kolby L. White
IPC: C08G18/79 , C08G18/12 , C08G18/22 , C08G18/28 , C08G18/32 , C08G18/50 , C09J175/08 , C08G18/73 , C09J5/00
Abstract: The present disclosure provides a polymeric material including a reaction product of a polymerizable composition and having a solids content of 90% or greater. The polymerizable composition includes a uretdione-containing material including a reaction product of a diisocyanate reacted with itself, a first hydroxyl-containing compound having a single OH group, and a second hydroxyl-containing compound having more than one OH group. The first hydroxyl-containing compound is a primary alcohol or a secondary alcohol, plus the second hydroxyl-containing compound is a diol and the reaction product contains 0.2 to 0.5, inclusive, of diol equivalents relative to isocyanate equivalents. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:US20200105440A1
公开(公告)日:2020-04-02
申请号:US16621021
申请日:2018-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ankit Mahajan, Jr. , James Zhu , Saagar A. Shah , Mikhail L. Pekurovsky , Vivek Krishnan , Kevin T. Reddy , Christopher B. Walker, Jr. , Michael A. Kropp , Kara A. Meyers , Teresa M. Goeddel , Thomas J. Metzler , Jonathan W. Kemling , Roger W. Barton
IPC: H01B7/06 , H01B7/02 , H01B13/00 , H01B13/008
Abstract: A stretchable conductor includes a substrate with a first major surface and an elongate wire, wherein the substrate is an elastomeric material, the elongate wire is on the first major surface of the substrate, the wire includes a first end and a second end, and further includes at least one arcuate region between the first end and the second end. At least one portion of the arcuate region of the wire in the region has a first surface area portion embedded in the surface of the substrate and a second surface area portion unembedded on the substrate and exposed in an amount sufficient to render at least an area of the substrate in the region electrically conductive. The unembedded second surface portion of the arcuate region may lie above or below a plane of the substrate. Additionally, different methods of preparing said stretchable conductor are disclosed. Composite articles including said stretchable conductor in durable electrical contact with a conductive fabric are also disclosed.
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54.
公开(公告)号:US20200017677A1
公开(公告)日:2020-01-16
申请号:US16468062
申请日:2017-12-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ying Lin , Hassan Sahouani , Michael A. Kropp , Matthew J. Kryger , Luke E. Heinzen , Jonathan W. Kemling
Abstract: A catalyst-containing particle including a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for a thermoset polymeric system, and the acidic coating layer comprises a binder; and a method of making such particles. A curable, one-part epoxy/thiol resin composition that includes: an epoxy/thiol resin mixture including: an epoxy resin component that includes an epoxy resin having at least two epoxide groups per molecule; a thiol component that includes a polythiol compound having at least two primary thiol groups; and catalyst-containing particles dispersed in the epoxy/thiol resin mixture; wherein each particle includes a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for the epoxy resin; and a method of curing such curable composition.
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公开(公告)号:US10400072B2
公开(公告)日:2019-09-03
申请号:US16095184
申请日:2017-04-24
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ying Lin , Hassan Sahouani , Mary M. Caruso Dailey , Luke E. Heinzen , Michael A. Kropp , Patricia M. Savu , Jonathan W. Kemling , Wayne S. Mahoney
IPC: C08J3/24 , C08L33/16 , C08J3/12 , C08K9/10 , C08G59/40 , C09D133/16 , C08J9/36 , C08L33/10 , C08L63/00
Abstract: Composite particles are provided that can be used to cure epoxy resins. More particularly, the composite particles have a porous polymeric core particle, a curing agent and/or a curing catalyst for an epoxy resin positioned within the porous polymeric core particle, and a fluoropolymer-containing coating layer around the porous polymeric core particle. Additionally, curable compositions are provided that are mixtures containing an epoxy resin and the composite particles. The epoxy resin typically does not react until the curable composition is heated causing the release of the curing agent and/or curing catalyst from the composite particle. Further, cured compositions formed from the curable composition are provided.
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公开(公告)号:US20170291360A1
公开(公告)日:2017-10-12
申请号:US15635237
申请日:2017-06-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Carsten Franke , Joseph C. Dingeldein , Jay A. Esch , Robert L.W. Smithson , Jayshree Seth , Olester Benson, JR. , Karen J. Calverley , Alexander J. Huffman , Serkan Yurt , Setareh Niknezhad , Michael A. Kropp , John P. Baetzold
IPC: B29C67/00 , C09J9/00 , B33Y70/00 , B29C35/08 , B33Y80/00 , B33Y30/00 , B33Y50/02 , C09J5/00 , C09J4/00 , B33Y10/00
CPC classification number: C09J7/385 , B05D3/06 , B05D5/10 , B29C35/0805 , B29C64/112 , B29C2035/0827 , B29K2033/04 , B29K2105/0097 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B33Y80/00 , C08F2220/1875 , C09J4/00 , C09J5/00 , C09J7/20 , C09J9/00 , C09J11/04 , C09J133/00 , C09J2201/606 , C09J2205/31 , C09J2433/00 , C09J2467/005 , C08F220/18 , C08F2220/1858
Abstract: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate. Also, an adhesive article is provided, including a substrate having a major surface and an integral adhesive disposed on the major surface of the substrate. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
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57.
公开(公告)号:US20170253779A1
公开(公告)日:2017-09-07
申请号:US15448277
申请日:2017-03-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jay S. Schlechte , Peyton R. Nosbusch , George M. Stout , Michael A. Kropp
Abstract: A curable adhesive composition includes a curable epoxy resin, an amine curing agent, a toughening agent, and aluminum flakes. The aluminum flakes include a fatty acid milling aid on at least a portion of their surfaces. The aluminum flakes were heated after milling. An article includes an adhesive composition cured between at least two members. The cured adhesive composition includes the heat-treated aluminum flakes within a toughened epoxy resin cured with an amine curing agent. The method includes applying the curable adhesive composition of described above to a surface of at least one of two or more members, joining the members so that the curable adhesive composition is sandwiched between the two or more members, and curing the curable adhesive composition to form an adhesive bond between the two or more members.
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公开(公告)号:US09416299B2
公开(公告)日:2016-08-16
申请号:US14379322
申请日:2013-02-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael A. Kropp , Zachary J. Thompson
IPC: C08K3/34 , C09J4/00 , C08F287/00 , C09J153/00
CPC classification number: C09J4/00 , C08F287/00 , C09J153/00 , C08F220/18
Abstract: There is provided an adhesive composition comprising: a) at least one acrylic functional monomer; b) a first toughening agent; c) a second toughening agent; d) an adhesion promoter; and e) a high aspect ratio filler selected from at least one of a high aspect ratio fibrillated filler and a halloycite clay filler.
Abstract translation: 提供一种粘合剂组合物,其包含:a)至少一种丙烯酸官能单体; b)第一增韧剂; c)第二增韧剂; d)粘合促进剂; 和e)选自高纵横比原纤化填料和卤素矿粘土填料中的至少一种的高纵横比填料。
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公开(公告)号:US20150038630A1
公开(公告)日:2015-02-05
申请号:US14379322
申请日:2013-02-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael A. Kropp , Zachary J. Thompson
IPC: C09J4/00
CPC classification number: C09J4/00 , C08F287/00 , C09J153/00 , C08F220/18
Abstract: There is provided an adhesive composition comprising: a) at least one acrylic functional monomer; b) a first toughening agent; c) a second toughening agent; d) an adhesion promoter; and e) a high aspect ratio filler selected from at least one of a high aspect ratio fibrillated filler and a halloycite clay filler.
Abstract translation: 提供一种粘合剂组合物,其包含:a)至少一种丙烯酸官能单体; b)第一增韧剂; c)第二增韧剂; d)粘合促进剂; 和e)选自高纵横比原纤化填料和卤素矿粘土填料中的至少一种的高纵横比填料。
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公开(公告)号:US11897977B2
公开(公告)日:2024-02-13
申请号:US16965688
申请日:2019-01-16
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Zachary J. Thompson , Mary M. Caruso Dailey , Michael A. Kropp
IPC: C08F2/50 , C08F220/18 , C07D239/62 , C07D405/12
CPC classification number: C08F2/50 , C07D239/62 , C07D405/12 , C08F220/1802
Abstract: The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent derived from a barbiturate, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization.
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