公开(公告)号：US20120184758A1

公开(公告)日：2012-07-19

申请号：US13497429

申请日：2010-09-03

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C11C3/00

CPC classification number: C11C3/003 ,  C07C67/03 ,  Y02E50/13 ,  C07C69/52 ,  C07C69/24

Abstract: The invention relates to a continuous method for producing esters, in which at least one polyol ester of formula (I) (R1—COO)mR2 (I), where R1 represents hydrogen or an optionally substituted hydrocarbon group containing 1 to 50 carbon atoms, R2 represents an optionally substituted hydrocarbon group containing 2 to 10 carbon atoms, and m represents a number from 2 to 10 and is smaller than or equal to the number of carbon atoms in R2, is reacted with at least one monohydric alcohol of formula (II) R3—OH (II), where R3 represents an optionally substituted hydrocarbon group containing 1 to 30 C atoms, using microwave radiation in a reaction tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a single-mode microwave applicator, so as to obtain at least one ester of formula (III) R1—COO—R3 (III), where R1 and R3 have the meanings indicated above.

Abstract translation: 本发明涉及一种生产酯的连续方法，其中至少一种式（I）的多元醇酯（R1-COO）mR2（I），其中R1表示氢或含有1至50个碳原子的任选取代的烃基， R2表示任意取代的含有2〜10个碳原子的烃基，m表示2〜10的数，小于或等于R2中的碳原子数与式（II）的至少一种一元醇反应 ）R3-OH（II），其中R3表示含有1至30个C原子的任选取代的烃基，在反应管中使用微波辐射，其纵轴在单模的微波传播方向上延伸 微波施加器，以获得至少一种式（III）的酯R 1 -COO-R 3（III），其中R 1和R 3具有上述含义。

公开(公告)号：US20120095238A1

公开(公告)日：2012-04-19

申请号：US13378242

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C07C231/02 ,  C07D209/48 ,  C07D213/56

CPC classification number: C07C231/02 ,  B01J19/126 ,  C07D209/48 ,  C07D213/82 ,  C07C233/65 ,  C07C233/78

Abstract: The invention relates to a continuous method for producing amides of aromatic carboxylic acids by reacting at least one carbonic acid ester of formula (I) R3—OOOR4, wherein R3 represents an optionally substituted aromatic hydrocarbon group with 5 to 100 carbon atoms and R4 represents a hydrocarbon group with 1 to 30 carbon atoms, with at least one amine of formula (II) HNR1R2, wherein R1 and R2 independently represent hydrogen or a hydrocarbon group with 1 to 100 C atoms, in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form carboxamide.

Abstract translation: 本发明涉及通过使至少一种式（I）R 3 -OOOR 4的碳酸酯与其中R 3表示任选取代的芳族烃基与5至100个碳原子的碳酸酯反应制备芳族羧酸的酰胺的连续方法，R4代表 具有1至30个碳原子的烃基，与至少一种式（II）的胺HNR1R2，其中R1和R2独立地表示氢或具有1至100个C原子的烃基，反应管的纵轴延伸在 在微波照射下，微波微波施加器的微波的传播方向形成甲酰胺。

公开(公告)号：US20120095220A1

公开(公告)日：2012-04-19

申请号：US13378226

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: C07D295/13 ,  C07D241/20 ,  C07D213/75 ,  C07D239/42 ,  C07C231/02 ,  C07D277/46

CPC classification number: C07C231/02 ,  B01J19/126 ,  C07C233/03 ,  C07C233/05 ,  C07C233/09

Abstract: The invention relates to a continuous method for producing amides of aliphatic carboxylic acids by reacting at least one carbonic acid ester of formula (I) R3—COOR4 (I), wherein R3 represents hydrogen or an optionally substituted aliphatic hydrocarbon group with 1 to 100 carbon atoms and R4 represents a hydrocarbon group with 1 to 30 carbon atoms, or wherein R3 and R4 form an optionally substituted ring with 5, 6 or 7 ring members, with at least one amine of formula (II) HNR1R2 (II), wherein R1 and R2 independently represent hydrogen or a hydrocarbon group with 1 to 100 C atoms, in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form carboxamide.

Abstract translation: 本发明涉及通过使至少一种式（I）的R 3 -COOR 4（I）的碳酸酯（其中R 3表示氢或任选取代的脂族烃基）与1至100个碳反应制备脂族羧酸酰胺的连续方法 原子和R 4表示具有1至30个碳原子的烃基，或其中R 3和R 4与5,6或7个环成员形成任选取代的环，与至少一种式（II）的胺HNR 1 R 2（II），其中R 1 并且在微波照射下，反应管的纵轴在微波微波施加器的微波的传播方向上延伸，形成甲酰胺，R2独立地表示氢或具有1至100个C原子的烃基。

公开(公告)号：US20120090983A1

公开(公告)日：2012-04-19

申请号：US13378181

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: B01J19/12 ,  C07F9/02 ,  C07C309/01 ,  C07C209/68

CPC classification number: C07C231/02 ,  B01J19/126 ,  B01J2219/00033 ,  B01J2219/0888 ,  B01J2219/0892 ,  B01J2219/1227 ,  C07C303/22 ,  H05B6/701 ,  H05B6/806 ,  C07C233/47 ,  C07C233/54 ,  C07C309/14 ,  C07C309/15

Abstract: The invention relates to a continuous method for N-acylating amino group-carrying organic acids by reacting at least one carboxylic acid of formula (I) R1—COOH (I), wherein R1 represents hydrogen or an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, with at least one at least one amino group-carrying organic acid of formula (II) R2NH-A-X (II), wherein A represents an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, X represents an acid group or the metal salt thereof and R2 represents hydrogen, an optionally substituted hydrocarbon group with 1 to 50 C atoms or a group of the formula -A-X, wherein A and X independently are defined as above, in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form amide.

Abstract translation: 本发明涉及通过使至少一种式（I）R 1 -COOH（I）的羧酸（其中R 1表示氢或任选取代的烃基）与1至50个的羧酸反应来进行N-酰化含氨基的有机酸的连续方法 碳原子与至少一个至少一个带有氨基的式（II）的有机酸R2NH-AX（II）反应，其中A表示任选取代的具有1至50个碳原子的烃基，X表示酸基或 其金属盐和R 2表示氢，具有1至50个碳原子的任选取代的烃基或式-AX的基团，其中A和X独立地如上定义，在反应管中，其纵轴在 在微波照射下，单模微波加热器的微波的传播方向形成酰胺。

公开(公告)号：US20120088885A1

公开(公告)日：2012-04-12

申请号：US13378258

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: B01J19/00 ,  C08F255/10 ,  C07C1/20 ,  C07C231/02 ,  C11C3/04

CPC classification number: C07C1/321 ,  B01J19/126 ,  B01J2219/0871 ,  B01J2219/1227 ,  C07C67/08 ,  C07C231/02 ,  C07C2531/24 ,  C07D307/60 ,  H05B6/80 ,  H05B6/806 ,  C07C15/14 ,  C07C69/24 ,  C07C69/52 ,  C07C233/05 ,  C07C233/09 ,  C07C233/36

Abstract: The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.

Abstract translation: 本发明涉及连续进行化学反应的装置。 该装置包括微波发生器，容纳微波透明管的微波加热器和等温反应部分，该等温反应部分被布置为使得待反应的材料通过微波加热器被引导到微波透明管内部，该微波加热器用作加热 区域，并且通过从微波发生器发射到微波施加器中的微波将其加热至反应温度。 待加热和任选在压力下的材料一旦离开加热区，就从微波加热器转移到等温反应区，所述反应区设置在加热区的下游，并且一旦冷却 离开等温反应区。

公开(公告)号：US08101785B2

公开(公告)日：2012-01-24

申请号：US12444669

申请日：2007-10-05

Applicant: Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

Inventor： Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

IPC: C07C231/00 ,  B01J19/00

CPC classification number: C07C231/02 ,  C07C233/18

Abstract: The invention relates to a method for producing fatty acid alkanol amides by reacting at least one amine that contains at least one primary or secondary amino group and at least one hydroxyl group with at least one fatty acid to form an ammonium salt, said ammonium salt being subsequently converted into the alkanol amide by means of microwave radiation.

Abstract translation: 本发明涉及一种生产脂肪酸链烷醇酰胺的方法，该方法是使至少一种含有至少一个伯或仲氨基和至少一个羟基的胺与至少一种脂肪酸反应形成铵盐，所述铵盐为 随后通过微波辐射转化成链烷醇酰胺。

公开(公告)号：US20110092722A1

公开(公告)日：2011-04-21

申请号：US12935628

申请日：2009-03-18

Applicant: Matthias Krull ,  Roman Morschhaeuser ,  Michael Seebach ,  Ralf Bierbaum ,  Joerg Appel

Inventor： Matthias Krull ,  Roman Morschhaeuser ,  Michael Seebach ,  Ralf Bierbaum ,  Joerg Appel

IPC: C07C233/01

CPC classification number: C07C231/02 ,  C07C233/05 ,  C07C233/09 ,  C07C233/36

Abstract: The invention relates to a continuous method for producing fatty acid amides, according to which at least one fatty acid of formula (I), R3—COOH  (I) wherein R3 is an optionally substituted aliphatic hydrocarbon radical, is reacted with at least one amine of formula (II), HNR1R2  (II) wherein R1 and R2 are independently hydrogen or a hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is then reacted to form a fatty acid amide, under microwave irradiation in a reaction pipe, the longitudinal axis of the pipe being oriented in the direction of propagation of the microwaves of a monomode microwave applicator.

Abstract translation: 本发明涉及一种生产脂肪酸酰胺的连续方法，根据该方法，将至少一种式（I）的脂肪酸，其中R 3为任选取代的脂族烃基的R 3 -COOH（I）与至少一种胺 式（II）的HNR1R2（II），其中R1和R2独立地为氢或包含1至100个C原子的烃基，以形成铵盐，然后所述铵盐反应形成脂肪酸酰胺， 在反应管中的微波照射，管的纵向轴线沿着单模微波施加器的微波的传播方向取向。

公开(公告)号：US20100180492A1

公开(公告)日：2010-07-22

申请号：US12665005

申请日：2008-06-17

Applicant: Matthias Krull ,  Robert Janssen

Inventor： Matthias Krull ,  Robert Janssen

IPC: C10L10/14

CPC classification number: C10L1/146 ,  C10L1/1641 ,  C10L1/1966 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from comb polymers that carry alkyl side chains having on average a length of at least 18 C atoms per mole for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

Abstract translation: 本发明涉及至少一种作为石蜡结晶成核剂的油溶性化合物B）的用途，其选自带有烷基侧链的梳形聚合物，其平均具有至少18C原子/摩尔的长度 用于改善含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中与B）不同的矿物油C）的冷流改进剂的反应，该添加剂A）至少包含油溶性两亲化合物 一个与极性基团结合的烷基或烯基，所述烷基或链烯基具有10-500个C原子，极性基团具有2个或更多个氮原子。

公开(公告)号：US20100170146A1

公开(公告)日：2010-07-08

申请号：US12665010

申请日：2008-06-17

Applicant: Matthias Krull ,  Werner Reimann ,  Robert Janssen

Inventor： Matthias Krull ,  Werner Reimann ,  Robert Janssen

IPC: C10L10/18

CPC classification number: C10L1/143 ,  C10L1/1608 ,  C10L1/1641 ,  C10L1/1817 ,  C10L1/1981 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from substantially linear hydrocarbons with at least 22 C atoms, for improving the response of cold flow improvers for mineral oils C) in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.

Abstract translation: 本发明涉及至少一种用作石蜡结晶的成核剂的油溶性化合物B）的用途，其选自具有至少22个C原子的基本上直链的烃，以改善用于矿物质的冷流改进剂的响应 油C）在含有至少一种无灰，含氮洗涤剂添加剂A）的中间馏分中，其是包含与极性基团结合的至少一个烷基或烯基的油溶性两亲化合物，所述烷基或烯基具有10 至500个C原子和具有2个或更多个氮原子的极性基团。

公开(公告)号：US20080262252A1

公开(公告)日：2008-10-23

申请号：US11390884

申请日：2006-03-28

Applicant: Matthias Krull

Inventor： Matthias Krull

IPC: C11B5/00

CPC classification number: C10L10/08 ,  C10L1/143 ,  C10L1/1835 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C10M169/04 ,  C10M169/044 ,  C10M2205/022 ,  C10M2207/282 ,  C10M2209/101 ,  C10N2220/024 ,  C10N2220/026 ,  C10N2230/06 ,  C10N2230/10 ,  C10N2230/43

Abstract: The present invention provides oily liquids comprising A) at least one ester of fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, and a monohydric C1-C5-alcohol, at least 50% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by condensing (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone to a degree of condensation of between 2 and 50 alkylphenol units.

Abstract translation: 本发明提供油性液体，其包含A）至少一种碳链长度为8至30个碳原子的脂肪酸酯和一元醇C 1 -C 5 - 至少50％的至少含有至少一个双键的脂肪酸基团，和B）至少一种烷基酚醛树脂，其可通过将（i）至少一种具有至少一个C 6的烷基酚缩合 C 1 -C 24 - - 烷基或C 6 -C 24 - 链烯基，和（ii）至少一种醛或酮至 2-50个烷基酚单元的缩合度。