Fuel oils having improved cold flow properties
    53.
    发明申请
    Fuel oils having improved cold flow properties 有权
    燃油具有改善的冷流特性

    公开(公告)号:US20040226216A1

    公开(公告)日:2004-11-18

    申请号:US10735490

    申请日:2003-12-12

    Applicant: Clariant GmbH

    Abstract: The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing a) bivalent structural units derived from ethylene of the formula 1 nullCH2nullCH2nullnullnull(1) b) from 5 to 12 mol % of bivalent structural units of the formula 2 1 where R1 is saturated, branched C5-C18-alkyl, and c) from 4 to 13 mol % of bivalent structural units of the formula 3 2 and the sum of the molar proportions of structural units of the formulae 2 and 3 being between 12 and 16 mol %, to the corresponding polymers, and also to their use for improving the cold flow behavior of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight.

    Abstract translation: 本发明涉及燃料油,其包含较大比例的硫含量至多为350ppm,芳烃含量至多为22重量%的中间馏分,以及乙烯和乙烯基酯的至少一种共聚物的较小比例, 所述共聚物含有a)衍生自式1 -CH 2 -CH 2 - (1)的乙烯的二价结构单元b)5至12mol%的式2的二价结构单元,其中R 1是饱和的,支化的C5- C18烷基,和c)4至13摩尔%的式3的二价结构单元和式2和3的结构单元的摩尔比例之和为12-16摩尔%的相应聚合物, 以及它们用于改善硫含量至多为350ppm且芳族化合物含量至多为22重量%的中间馏分的冷流行为的用途。

    Preparation of additive mixtures for mineral oils and mineral oil distillates
    54.
    发明申请
    Preparation of additive mixtures for mineral oils and mineral oil distillates 有权
    矿物油和矿物油馏分添加剂混合物的制备

    公开(公告)号:US20040065004A1

    公开(公告)日:2004-04-08

    申请号:US10676962

    申请日:2003-10-01

    Applicant: Clariant GmbH

    Abstract: The present invention provides a continuous process for preparing additive mixtures for mineral oils and mineral oil distillates, comprising A) a cold flow improver for middle distillates, and at least one further component selected from B) and C): B) a further cold flow improver, C) an organic solvent, which comprises mixing cold flow improver and optionally solvent by means of a static mixer, the temperature of the additive mixture at the outlet of the static mixer being from 0null C. to 100null C.

    Abstract translation: 本发明提供了用于制备用于矿物油和矿物油馏出物的添加剂混合物的连续方法,其包括A)用于中间馏分的冷流改进剂和至少一种选自B)和C)的另外的组分:B)另外的冷流 改进剂,C)有机溶剂,其包括通过静态混合器将冷流改进剂和任选溶剂混合,静态混合器出口处的添加剂混合物的温度为0℃至100℃

    Aviation fuels having improved freeze point
    55.
    发明授权
    Aviation fuels having improved freeze point 失效
    具有改善冻结点的航空燃料

    公开(公告)号:US06610110B1

    公开(公告)日:2003-08-26

    申请号:US09502131

    申请日:2000-02-11

    Applicant: John S. Manka

    Inventor: John S. Manka

    CPC classification number: C10L1/1973 C10L1/1691 C10L1/1981 C10L1/221

    Abstract: A novel aviation fuel characterized by having a low freeze point (typically no higher than −40° C.) comprising a mixture of an aviation fuel and a compound selected from at least one member of the group consisting of (1) the reaction product of an alkanol amine with a hydrocarbyl-substituted acylating agent wherein the hydrocarbyl group comprises a substantially linear alkyl or alkenyl group containing an average of about 8 to about 50 carbon atoms; or (2) the reaction product of (a) substantially linear hydrocarbyl-substituted phenol wherein the hydrocarbyl substituent contains an average of about 8 to about 40 carbon atoms with an aldehyde or a source thereof having between 1 to 10 carbon atoms; or (3) aromatic moieties containing from about 1 to 3 aromatic rings wherein the aromatic moieties contains up to three substituents hydrocarbyl substantially linear constituents having from about 1 to 50 carbon atoms and the aromatic moieties are coupled by alkylene groups having 1 to 100 carbon atoms; or (4) an ethylene vinyl acetate copolymer having a number average molecular weight of between about 2,500 to 10,000 with a mole percent ethylene to vinyl acetate ratio of between about 65:35 to 85:15.

    Abstract translation: 其特征在于具有低凝固点(通常不高于-40℃)的新型航空燃料,其包含航空燃料和选自以下的至少一种成员的化合物的混合物:(1) 链烷醇胺与烃基取代的酰化剂,其中烃基包含平均含约8至约50个碳原子的基本上直链的烷基或链烯基; 或(2)(a)基本上线性的烃基取代的苯酚的反应产物,其中烃基取代基含有约8至约40个碳原子的平均值,其中醛或其来源具有1至10个碳原子; 或(3)含有约1至3个芳族环的芳族部分,其中芳族部分含有至多3个取代基烃基基本上具有约1至50个碳原子的直链组分,芳族部分由具有1至100个碳原子的亚烷基 ; 或(4)数均分子量在约2,500至10,000之间的乙烯 - 乙酸乙烯酯共聚物,乙烯与乙酸乙烯酯的摩尔百分比为约65:35至85:15

    Condensates
    56.
    发明授权
    Condensates 失效
    冷凝水

    公开(公告)号:US06583093B2

    公开(公告)日:2003-06-24

    申请号:US10109848

    申请日:2002-04-01

    Abstract: A cyclic compound comprising m units of the formula Ia: and n units of the formula (Ib): joined together to form a ring, wherein Y and Y2 are divalent bridging groups which may be the same or different in each unit; R0 is H or (C1-C6) alkyl or is a metal or ammonium cation; R5 is H or (C1-C60) alkyl or OH group; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the provisos that i) at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3, and ii) in formula Ia at least one OH group is in the meta or para position to the COOR0 group and/or at least one R5 group is OH.

    Abstract translation: 包含m个单元的式Ia的环状化合物和式(Ib)的n个单元:连接在一起形成环,其中Y和Y 2是每个单元可以相同或不同的二价桥基; R 0是H 或(C1-C6)烷基或是金属或铵阳离子; R5是H或(C1-C60)烷基或OH基; j是1或2; R3是氢,烃基或杂取代烃基; R 1,R 2和R 4可以相同或不同,是羟基,氢,烃基或杂取代烃基,条件是:R1,R2,R4中的至少一个是羟基,m + n是4 在式Ia中,至少一个OH基位于COOR0基团的间位或对位,和/或至少一个R 5基团是OH。

    Fuel composition and blend
    57.
    发明授权
    Fuel composition and blend 失效
    燃料组成和混合

    公开(公告)号:US06270537B1

    公开(公告)日:2001-08-07

    申请号:US09567275

    申请日:2000-05-09

    Abstract: A jet fuel composition having reduced tendency to discoloration of high temperatures comprises a cyclic compound comprising m units of the formula 1a. and n units of the formula (Ib) joined together to form a ring, wherein Y is a divalent bridging group which may be the same or different in each unit; R0 is H or (C1-C6) alkyl; R5 is H or (C1-C60) alkyl; and j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; p1 each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the proviso that at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3 and preferably either R1 is hydroxyl and R2 and R4 are independently either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, or R2 and R4 are hydroxyl and R1 is either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl; and m+n is from 4 to 20, m is from 1 to 8 and n is at least 3.

    Abstract translation: 具有降低的高温变色趋势的喷气燃料组合物包括包含m个单元的式1a.和n个式(Ib)的单元连接在一起形成环的环状化合物,其中Y是二价桥连基团,其可以是 各单元相同或不同; R 0为H或(C 1 -C 6)烷基; R5是H或(C1-C60)烷基; 且j为1或2; R 3为氢,烃基或杂取代的烃基; p1,R 1,R 2和R 4各自可以相同或不同,为羟基,氢,烃基或杂取代的烃基,条件是R 1,R 2,R 4中的至少一个为羟基,m + n为 4至20,m为1-8且n为至少3,优选地R 1为羟基,R 2和R 4独立地为氢,烃基或杂取代烃基,或R 2和R 4为羟基,R 1为氢,烃基 或杂取代的烃基; m + n为4〜20,m为1〜8,n为3以上。

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