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公开(公告)号：US11684903B2
公开(公告)日：2023-06-27
申请号：US16663333
申请日：2019-10-24
Applicant: Daniel Shafer
Inventor： Daniel Shafer
CPC classification number: B01J19/0093 , B01J16/005 , B01J37/0009 , B01J37/0215 , B01J37/0217 , B01J37/0225 , C01B3/38 , C10G3/42 , B01J2219/0099 , B01J2219/00795 , B01J2219/00822 , B01J2219/00833 , B01J2219/00835 , B01J2219/00855 , B01J2219/00882 , B01J2219/00891
Abstract: A catalytic microscale reactor with spiral reactor geometry may have a high surface area to volume ratio, high catalytic surface area, high heat transfer surface area, long residence time, and high single pass conversion. The catalytic surface may be treated with microsphere spacer particles which serve to maintain the space between them at an engineered distance without the need for precise manufacturing techniques. The design of the reactor may allow for a catalyst surface to be removed, uncoiled, refurbished, and recoiled in an automated continuous process. An automated continuous process may be suitable both for initially preparing a new catalytic surface as well as refurbishing a fouled catalytic surface and may reduce the time and cost to prepare a new surface.
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公开(公告)号：US09573109B2
公开(公告)日：2017-02-21
申请号：US14387930
申请日：2013-02-14
Applicant: UOP LLC
Inventor： David James Shecterle
CPC classification number: B01J16/005 , B01J21/04 , B01J23/42 , B01J37/24 , B01J2219/00006 , C10G45/60
Abstract: Embodiments of methods and apparatuses for isomerization of paraffins are provided. In one example, a method comprises the steps of separating an isomerization effluent into a product stream that comprises branched paraffins and a stabilizer overhead vapor stream that comprises HCl, H2, and C6-hydrocarbons. C6-hydrocarbons are removed from at least a portion of the stabilizer overhead vapor stream to form a HCl and H2-rich stream. An isomerization catalyst is activated using at least a portion of the HCl and H2-rich stream to form a chloride-promoted isomerization catalyst. A paraffin feed stream is contacted with the chloride-promoted isomerization catalyst in the presence of hydrogen for isomerization of the paraffins.
Abstract translation: 提供石蜡异构化方法和装置的实施方案。 在一个实例中，方法包括以下步骤：将异构化流出物分离成包含支链烷烃的产物流和包含HCl，H 2和C 6烃的稳定剂塔顶蒸气流。 从至少一部分稳定剂塔顶蒸气流中除去C6烃，以形成HCl和富H2流。 使用至少一部分HCl和富H 2流来活化异构化催化剂以形成氯化物促进的异构化催化剂。 在氢气存在下，将链烷烃进料流与氯化物促进的异构化催化剂接触以使石蜡异构化。
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63.发明授权Micro-channel water-gas shift reaction device having built-in flow-through-type metal catalyst 有权具有内置流通式金属催化剂的微通道水煤气变换反应装置公开(公告)号：US09180421B2
公开(公告)日：2015-11-10
申请号：US14237756
申请日：2012-08-08
Applicant: Kyung-Ran Hwang , Jong-Soo Park , Shin-Kun Ryi , Jin-Suk Lee , Chun-Boo Lee , Sung-Wook Lee
Inventor： Kyung-Ran Hwang , Jong-Soo Park , Shin-Kun Ryi , Jin-Suk Lee , Chun-Boo Lee , Sung-Wook Lee
CPC classification number: B01J16/005 , B01J19/0093 , B01J2219/00783 , B01J2219/00808 , B01J2219/00835 , B01J2219/00873 , C01B3/16 , C01B2203/0288 , C01B2203/04 , C01B2203/0405 , C01B2203/0475 , C01B2203/0485 , C01B2203/146 , C10J2300/093 , C10K1/004 , C10K1/005 , C10K3/04 , Y02P30/30
Abstract: The present invention relates to a micro-channel water-gas shift (WGS) reaction device for WGS for generating hydrogen and pre-combustion carbon capture and storage (CCS) from coal gasification, the device using a micro-channel heat exchanger and through-type metal catalyst capable of rapidly dissipating heat generated during single-stage WGS reaction of high concentration CO in a high temperature space.
Abstract translation: 本发明涉及一种用于从煤气化产生氢气和预燃碳捕获和储存（CCS）的WGS的微通道水煤气变换（WGS）反应装置，使用微通道热交换器和通孔的装置， 能够在高温空间中快速散发高浓度CO的单级WGS反应期间产生的热量的金属催化剂。
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公开(公告)号：US20150165408A1
公开(公告)日：2015-06-18
申请号：US14533835
申请日：2014-11-05
Inventor： Wlodzimierz W. Zmierczak , Jan D. Miller , Raj Rajamani , Steven Messiter , Nicholas B. Drinnan , Edward Choros
CPC classification number: B01J8/22 , B01J8/1836 , B01J15/005 , B01J16/005 , B01J19/243 , B01J19/2475 , B01J2208/00203 , B01J2208/00212 , B01J2208/00752 , B01J2208/00911 , B01J2208/00938 , B01J2219/00094 , C07C5/05 , C07C29/154 , C07C41/09 , C07C2523/44 , C07C2531/28 , C10G2/342 , C10G45/00 , C10G50/00 , C10G2300/4081 , C07C11/08 , C07C31/04 , C07C43/04
Abstract: A fluid-sparged helical channel reactor can include a constrained flow unit located within a reactor body. The unit has an inner wall and an outer wall which produces a helical constrained flow along a substantially enclosed helical flow path around an axial interior volume. At least part of the outer wall includes a sparging portion to allow fluid reactant to be sparged into the helical constrained flow. A liquid inlet fluidly connected to the reactor body and configured to allow addition of a liquid into the enclosed helical flow path. A sparging fluid inlet is fluidly connected to the reactor body which supplies a sparging fluid to the sparging portion of the constrained-flow unit. A liquid outlet fluidly is connected to the reactor body to allow removal of liquid from the constrained-flow unit. A gas outlet is fluidly associated with the enclosed helical flow path to allow removal of gases from the enclosed helical flow path.
Abstract translation: 流体喷射的螺旋通道反应器可以包括位于反应器主体内的约束流动单元。 该单元具有内壁和外壁，其沿着围绕轴向内部体积的基本上封闭的螺旋流动路径产生螺旋限制流。 外壁的至少一部分包括喷射部分，以允许流体反应物喷射到螺旋约束流中。 流体连接到反应器主体并被配置为允许将液体添加到封闭的螺旋流动路径中的液体入口。 喷射流体入口流体地连接到反应器主体，该反应器主体将喷射流体供应到约束流动单元的喷射部分。 液体出口流体地连接到反应器主体以允许从约束流动单元移除液体。 气体出口与封闭的螺旋流动路径流体相关，以允许从封闭的螺旋流动路径移除气体。
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公开(公告)号：US08980196B2
公开(公告)日：2015-03-17
申请号：US13256377
申请日：2010-03-15
Applicant: Wlodzimierz W. Zmierczak , Jan Dean Miller , Raj Rajamani , Steven Messiter , Nicholas Drinnan , Edward Choros
Inventor： Wlodzimierz W. Zmierczak , Jan Dean Miller , Raj Rajamani , Steven Messiter , Nicholas Drinnan , Edward Choros
IPC: B01J19/24 , B01J8/22 , B01J15/00 , B01J16/00 , C07C5/05 , C07C29/154 , C07C41/09 , C10G2/00 , C10G45/00 , C10G50/00
CPC classification number: B01J8/22 , B01J8/1836 , B01J15/005 , B01J16/005 , B01J19/243 , B01J19/2475 , B01J2208/00203 , B01J2208/00212 , B01J2208/00752 , B01J2208/00911 , B01J2208/00938 , B01J2219/00094 , C07C5/05 , C07C29/154 , C07C41/09 , C07C2523/44 , C07C2531/28 , C10G2/342 , C10G45/00 , C10G50/00 , C10G2300/4081 , C07C11/08 , C07C31/04 , C07C43/04
Abstract: A method of reacting compounds can include directing a liquid into a helical constrained flow (37) having an inner circumferential flow surface and an outer circumferential flow surface. The helical constrained flow (37) can be formed around an axial interior volume (38). At least a portion of the helical constrained flow can be exposed to a sparging portion (35) to allow a fluid to be sparged into the liquid along the helical constrained flow (37). The fluid reactant can be sparged through the helical constrained flow so as to form a fluid product.
Abstract translation: 使化合物反应的方法可以包括将液体引导到具有内周流动表面和外周流动表面的螺旋约束流（37）中。 螺旋限制流（37）可围绕轴向内部容积（38）形成。 螺旋限制流的至少一部分可以暴露于鼓泡部分（35），以允许流体沿着螺旋约束流（37）喷射到液体中。 流体反应物可以通过螺旋约束流喷射，以便形成流体产物。
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Patent Agency Ranking
公开(公告)号：US08829136B2
公开(公告)日：2014-09-09
申请号：US12946895
申请日：2010-11-16
Applicant: David M. Glaser , Roderick Coffey , John G. Woods, III , Anthony F. Jacobine
Inventor： David M. Glaser , Roderick Coffey , John G. Woods, III , Anthony F. Jacobine
IPC: C08F20/10 , B01J19/18 , C08F2/00 , B01J14/00 , C08F293/00 , B01J16/00 , B01J19/00 , C08F220/18
CPC classification number: C08F220/18 , B01J14/005 , B01J16/005 , B01J19/0066 , B01J19/1881 , B01J2219/00063 , B01J2219/00069 , B01J2219/00094 , B01J2219/00162 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B01J2219/00238 , C08F2/00 , C08F293/005 , C08F2438/01
Abstract: A method of conducting controlled radical polymerization, including: (a) providing a mixture of at least one monomer; at least one monomer solvent; at least one compound metal coordinating capable; and at least one initiator; (b) directing the mixture at a rate over a solid catalyst surface contained in an external chamber to the vessel, the catalyst including a metal or metal compound capable of at least two oxidation states; (c) monitoring the reaction vessel temperature; (d) adjusting the flow rate when the temperature is outside a selected temperature range; and (e) allowing the polymerization to proceed to desired conversion level.
Abstract translation: 一种进行受控自由基聚合的方法，包括：（a）提供至少一种单体的混合物; 至少一种单体溶剂; 至少一种配位的复合金属; 和至少一个引发剂; （b）以混合物的速率将包含在外部室中的固体催化剂表面的速率引导至容器，所述催化剂包括能够具有至少两种氧化态的金属或金属化合物; （c）监测反应容器的温度; （d）当温度在选定的温度范围之外时调节流量; 和（e）允许聚合进行到所需的转化水平。
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67.发明申请MICRO-CHANNEL WATER-GAS SHIFT REACTION DEVICE HAVING BUILT-IN FLOW-THROUGH-TYPE METAL CATALYST 有权具有内置流量型金属催化剂的微通道水 - 气移动反应装置公开(公告)号：US20140178259A1
公开(公告)日：2014-06-26
申请号：US14237756
申请日：2012-08-08
Applicant: Kyung-Ran Hwang , Jong-Soo Park , Shin-Kun Ryi , Jin-Suk Lee , Chun-Boo Lee , Sung-Wook Lee
Inventor： Kyung-Ran Hwang , Jong-Soo Park , Shin-Kun Ryi , Jin-Suk Lee , Chun-Boo Lee , Sung-Wook Lee
IPC: B01J16/00
CPC classification number: B01J16/005 , B01J19/0093 , B01J2219/00783 , B01J2219/00808 , B01J2219/00835 , B01J2219/00873 , C01B3/16 , C01B2203/0288 , C01B2203/04 , C01B2203/0405 , C01B2203/0475 , C01B2203/0485 , C01B2203/146 , C10J2300/093 , C10K1/004 , C10K1/005 , C10K3/04 , Y02P30/30
Abstract: The present invention relates to a micro-channel water-gas shift (WGS) reaction device for WGS for generating hydrogen and pre-combustion carbon capture and storage (CCS) from coal gasification, the device using a micro-channel heat exchanger and through-type metal catalyst capable of rapidly dissipating heat generated during single-stage WGS reaction of high concentration CO in a high temperature space.
Abstract translation: 本发明涉及一种用于从煤气化产生氢气和预燃碳捕获和储存（CCS）的WGS的微通道水煤气变换（WGS）反应装置，使用微通道热交换器和通孔的装置， 能够在高温空间中快速耗散高浓度CO的单级WGS反应期间产生的热量的金属催化剂。
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公开(公告)号：US20140044613A1
公开(公告)日：2014-02-13
申请号：US14059911
申请日：2013-10-22
Applicant: PRECISION COMBUSTION, INC.
Inventor： William C. Pfefferle , Shahrokh Etemad
IPC: B01J16/00
CPC classification number: B01J16/005 , B01J12/007 , B01J19/2475 , C07C2/58 , C07C2529/068
Abstract: A novel catalytic reactor is provided for controlling the contact of a limiting reactant with a catalyst surface. A first flow vessel defines an interior surface and an exterior surface, and the interior surface has a catalyst deposited on at least a portion thereof. A second flow vessel is positioned within the first flow vessel and the second flow vessel defines a porous surface designed to deliver a fluid uniformly to at least a portion of the interior surface of the first flow vessel.
Abstract translation: 提供了一种新颖的催化反应器来控制极限反应物与催化剂表面的接触。 第一流动容器限定内表面和外表面，并且内表面具有沉积在其至少一部分上的催化剂。 第二流动容器位于第一流动容器内，并且第二流动容器限定多孔表面，该多孔表面被设计成将流体均匀地输送到第一流动容器的内表面的至少一部分。
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公开(公告)号：US20130296603A1
公开(公告)日：2013-11-07
申请号：US13886464
申请日：2013-05-03
Inventor： Kuo-Wei HUANG , Zhiping LAI
IPC: B01J16/00
CPC classification number: B01J16/005 , B01J8/009 , B01J8/0257 , B01J15/005 , B01J19/2475 , B01J23/462 , B01J31/189 , B01J2219/00135 , B01J2231/49 , B01J2531/0244 , B01J2531/821 , C07C67/00 , C07C67/40 , C07C69/14
Abstract: Dehydrogenative coupling can be achieved in nearly quantitative conversions and yields using a membrane reactor.
Abstract translation: 脱氢偶联可以在几乎定量的转化和使用膜反应器的产率下实现。
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70.发明申请公开(公告)号：US20120189875A1
公开(公告)日：2012-07-26
申请号：US13437771
申请日：2012-04-02
Applicant: HALBERT FISCHEL , SHELDON L. EPSTEIN
Inventor： HALBERT FISCHEL , SHELDON L. EPSTEIN
CPC classification number: B01J10/007 , B01F7/008 , B01J12/007 , B01J14/005 , B01J15/005 , B01J16/005 , B01J19/1806 , B01J19/1893 , B01J2219/00083 , B01J2219/00135 , C01B3/065 , C01B3/40 , C01B2203/0233 , C01B2203/0261 , C01B2203/0277 , C01B2203/0283 , C01B2203/066 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , H01M2/38 , H01M4/90 , H01M4/92 , H01M8/004 , H01M8/188 , H01M8/2445 , H01M8/2459 , H01M10/345 , Y02E60/362 , Y02E60/528
Abstract: Galvanic electrochemical cells (100, 300, 700, 900) for converting chemical energy into electrical energy, such as batteries, flow cells and fuel cells with a cylindrical rotating filter (120X, 326, 726, 910) having ion-porous (120P, 326P, 726P, 910P) and ion-non-porous filter (120N, 326N, 726N, 910N) for use with both thixotropic and non-conducting electrolytes that generates fluid flows in electrolytes between static cylindrical current collector segments (106, 304X, 306X, 710X, 902X; 108, 314X, 316X, 712X, 906) and the filter (120, 326, 726, 910) are disclosed that generate electric currents varying in amplitude that can be converted into alternating current electricity.
Abstract translation: 用于将化学能转换为电能的电化学电池（100,300,700,900），所述电化学电池具有带有离子多孔的圆柱形旋转过滤器（120X，326,726,910），例如电池，流动池和燃料电池， 326P，726P，910P）和离子 - 无孔过滤器（120N，326N，726N，910N），用于触发和非导电电解质，其在静态圆柱形集电器段（106,304X，306X）之间产生电解液中的流体流 ，710X，902X; 108,314X，316X，712X，906）和滤波器（120,326,726,910），其产生可被转换成交流电的幅度变化的电流。
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