公开(公告)号：US08575399B2

公开(公告)日：2013-11-05

申请号：US12957470

申请日：2010-12-01

Applicant: Wei-Bin Su ,  Hsun-Yi Huang ,  Jyh-Haur Hwang ,  Tzong-Bin Lin ,  Cheng-Tsung Hong ,  Hung-Chung Shen ,  Karl T. Chuang

Inventor： Wei-Bin Su ,  Hsun-Yi Huang ,  Jyh-Haur Hwang ,  Tzong-Bin Lin ,  Cheng-Tsung Hong ,  Hung-Chung Shen ,  Karl T. Chuang

IPC: C07C41/09 ,  B01J8/28 ,  C07C43/04

CPC classification number: C07C43/043 ,  B01D3/009 ,  B01J8/0453 ,  B01J8/28 ,  B01J27/053 ,  B01J27/12 ,  B01J29/40 ,  B01J29/7007 ,  B01J31/08 ,  B01J35/0006 ,  B01J2208/00265 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00539 ,  B01J2208/025 ,  B01J2219/00006 ,  C07C41/09 ,  Y02P20/127

Abstract: A dual-bed catalytic distillation tower has a catalytic column having an upper catalytic bed filled with low temperature dehydration catalysts and a lower catalytic bed filled with high temperature dehydration catalysts. When using the dual-bed catalytic distillation tower, the feed may be fed to the tower at the top of the upper catalytic bed, between the upper and lower catalytic beds, or at the bottom of the lower catalytic bed for dehydration to obtain DME. The dual-bed catalytic distillation tower has the advantage of flexible set up depending on various feeds, such as anhydrous or crude methanol and on different grades of DME to be obtained.

Abstract translation: 双床催化蒸馏塔具有催化塔，其具有填充有低温脱水催化剂的上催化床和装有高温脱水催化剂的下催化床。 当使用双床催化蒸馏塔时，进料可以在上催化床的顶部，上下催化床的顶部或下催化床的底部进料到塔中以进行脱水以获得DME。 双床催化蒸馏塔具有根据各种进料如无水或粗甲醇和不同等级的DME的灵活设置的优点。

公开(公告)号：US08558036B2

公开(公告)日：2013-10-15

申请号：US12946014

申请日：2010-11-15

Applicant: Wei Xu

Inventor： Wei Xu

IPC: C07C29/04

CPC classification number: B01J31/34 ,  B01J27/16 ,  B01J27/18 ,  B01J29/70 ,  B01J31/08 ,  C07C29/04 ,  C07C31/12 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  C10L1/1824

Abstract: Processes for producing mixed alcohols from mixed olefins and the catalyst systems for making such alcohols are provided. Additionally, processes for producing fuel compositions having mixed alcohols prepared from mixed olefins are also provided as embodiments of the present invention. The catalyst systems include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.

Abstract translation: 提供了从混合烯烃制备混合醇的方法和制备这些醇的催化剂体系。 此外，作为本发明的实施方案，也提供了由混合烯烃制备具有混合醇的燃料组合物的方法。 催化剂体系包括双相催化剂体系，其包括水溶性酸催化剂和固体酸催化剂。

公开(公告)号：US08440297B2

公开(公告)日：2013-05-14

申请号：US12623308

申请日：2009-11-20

Applicant: Leonardo C. Lopez ,  Scott T. Matteucci ,  Sarada P. Namhata

Inventor： Leonardo C. Lopez ,  Scott T. Matteucci ,  Sarada P. Namhata

IPC: D02G3/00 ,  B32B5/16 ,  B32B27/12

CPC classification number: B01J31/08 ,  Y10T428/23921 ,  Y10T428/25 ,  Y10T428/2913 ,  Y10T428/2915 ,  Y10T428/2927 ,  Y10T442/60 ,  Y10T442/674

Abstract: The instant invention generally provides polymer organoclay composite comprising a molecularly self-assembling material and an organoclay, and a process of making and an article comprising the polymer organoclay composite. The instant invention also generally provides a fiber comprising the polymer organoclay composite, and a process of fabricating and an article comprising the fiber.

Abstract translation: 本发明通常提供包含分子自组装材料和有机粘土的聚合物有机粘土复合材料，以及制备方法和包含聚合物有机粘土复合材料的制品。 本发明还通常提供了包含聚合物有机粘土复合材料的纤维，以及包含该纤维的制造方法和制品。

公开(公告)号：US20130079560A1

公开(公告)日：2013-03-28

申请号：US13684136

申请日：2012-11-21

Applicant: Jiangsu Sinorgchem Technology Co., Ltd.

Inventor： Xinmin CHEN ,  Jianliang Zhu

IPC: B01J31/26 ,  B01J31/06 ,  B01J31/00 ,  B01J31/02 ,  C07C209/38 ,  C07C209/26

CPC classification number: B01J31/26 ,  B01J23/04 ,  B01J31/00 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0271 ,  B01J31/06 ,  B01J31/08 ,  B01J37/0209 ,  C07C209/26 ,  C07C209/36 ,  C07C209/38 ,  C07C209/60 ,  C07C211/56 ,  C07C211/55

Abstract: A solid base catalyst having a carrier, an organic base, and an inorganic base. Both of the organic base and inorganic base are loaded on the carrier. The solid base catalyst is especially suitable for the synthesis of 4-Aminodiphenylamine (4-ADPA).

Abstract translation: 具有载体，有机碱和无机碱的固体碱催化剂。 有机碱和无机碱均载于载体上。 固体碱催化剂特别适用于4-氨基二苯胺（4-ADPA）的合成。

公开(公告)号：US20120091034A1

公开(公告)日：2012-04-19

申请号：US13262364

申请日：2010-03-24

Applicant: Aurelie Dandeu ,  Vincent Coupard

Inventor： Aurelie Dandeu ,  Vincent Coupard

IPC: C10G69/02

CPC classification number: C10G47/16 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/88 ,  B01J31/08 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J39/04 ,  C10G2/30 ,  C10G7/00 ,  C10G25/02 ,  C10G45/32 ,  C10G45/34 ,  C10G45/58 ,  C10G45/60 ,  C10G47/00 ,  C10G65/12 ,  C10G67/06 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/1025 ,  C10G2300/205 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

Abstract: The present invention describes a process for producing middle distillates from a C5+ liquid paraffinic fraction, termed a heavy fraction, with an initial boiling point in the range 15° C. to 40° C. produced by Fischer-Tropsch synthesis, comprising the following steps in succession: passing said C5+ liquid paraffinic fraction, termed a heavy fraction, over at least one ion exchange resin at a temperature in the range 80° C. to 150° C., at a total pressure in the range 0.7 to 2.5 MPa, at an hourly space velocity in the range 0.2 to 2.5 h−1; eliminating at least a portion of the water formed in step a); hydrogenating the unsaturated olefinic type compounds of at least a portion of the effluent derived from step b) in the presence of hydrogen and a hydrogenation catalyst; and hydroisomerization/hydrocracking of at least a portion of the hydrotreated effluent derived from step c) in the presence of hydrogen and a hydroisomerization/hydrocracking catalyst.

Abstract translation: 本发明描述了一种由C5 +液体石蜡馏分（称为重质馏分）生产中间馏分的方法，其初始沸点在费托合成产生的15℃至40℃的范围内，包括以下步骤 连续地将所述C5 +液体石蜡馏分称为重馏分，在至少一种离子交换树脂中，温度范围为80℃至150℃，总压力为0.7-2.5MPa， 时间范围为0.2至2.5 h-1; 消除在步骤a）中形成的至少一部分水; 在氢气和氢化催化剂存在下，将来自步骤b）的至少一部分流出物的不饱和烯烃型化合物氢化; 和在氢气和加氢异构化/加氢裂化催化剂存在下，来自步骤c）的至少一部分加氢处理的流出物的加氢异构化/加氢裂化。

公开(公告)号：US08133928B2

公开(公告)日：2012-03-13

申请号：US12129851

申请日：2008-05-30

Applicant: Ernst-Joachim Alps ,  Ulrich Blaschke ,  Christian Münnich ,  Stefan Westernacher

Inventor： Ernst-Joachim Alps ,  Ulrich Blaschke ,  Christian Münnich ,  Stefan Westernacher

IPC: B01J47/10 ,  B01J41/12

CPC classification number: B01J31/08

Abstract: A process for the storage or transportation of pretreated, conditioned ion exchangers as catalysts for chemical reactions is disclosed. The preconditioned ion-exchange resin is kept as preconditioned ion-exchange resin suspension in a storage or transporting container. The container with the preconditioned ion-exchange resin suspension is transported to either a storage site for storage or to a reactor for transfer of the resin to the reactor.

Abstract translation: 公开了一种用于储存或运输预处理的，调节离子交换剂作为化学反应催化剂的方法。 预处理的离子交换树脂作为预处理的离子交换树脂悬浮液保存在储存或运输容器中。 具有预处理的离子交换树脂悬浮液的容器被运输到用于储存的存储部位或用于将树脂转移到反应器的反应器。

公开(公告)号：US07754084B2

公开(公告)日：2010-07-13

申请号：US11899125

申请日：2007-09-04

Applicant: Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

Inventor： Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

IPC: C08J9/00

CPC classification number: B01J41/14 ,  B01J31/08 ,  C02F1/42 ,  C02F2001/422 ,  C02F2103/023

Abstract: The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak′, Ak″ are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2, where x is equal to 0 or 1, and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ⅓ PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.

Abstract translation: 本发明涉及基于至少一种芳族单体和至少一种具有通式（I）结构单元的交联剂的热稳定阴离子交换剂，其中Ak，Ak'，Ak“在每种情况下彼此独立地相同或相同 不同的是C 1 -C 18烷基，n是5和18之间的偶数，x + y = 2，其中x等于0或1，X是Cl，Br，OH，HCO 3，HSO 4，½（SO 4 ），½CO 3，NO 3，F，H 2 PO 4，½HPO 4，1 PO 4，结果这些阴离子交换剂优选为OH形式，耐受至少60℃，优选至少80℃的工作温度。 在相当长的时间内，其生产方法及其用途。

公开(公告)号：US20100119424A1

公开(公告)日：2010-05-13

申请号：US12451432

申请日：2008-05-14

Applicant: Fredrik Almqvist ,  Basudeb Basu

Inventor： Fredrik Almqvist ,  Basudeb Basu

IPC: B01J19/00 ,  B01J37/30

CPC classification number: C07C67/343 ,  B01J23/44 ,  B01J31/08 ,  B01J31/165 ,  B01J37/06 ,  B01J2231/4211 ,  B01J2231/4261 ,  B01J2531/824 ,  C07C1/321 ,  C07C17/263 ,  C07C37/18 ,  C07C41/30 ,  C07C2523/44 ,  C07C2531/08 ,  C07C2603/24 ,  C07D213/61 ,  C07D401/04 ,  C07D413/04 ,  C07D491/147 ,  C07C15/14 ,  C07C25/18 ,  C07C69/618 ,  C07C69/65 ,  C07C43/205 ,  C07C39/15

Abstract: The present invention relates to a method of producing a heterogeneous catalyst suitable for catalyzing Heck, Suzuki-Miyaura Sonogashira coupling and Buchwald-Hartwig reactions, comprising the steps of: a) providing a macroporous carrier, said macroporous carrier consisting of a core and a plurality of ion exchange groups covalently bonded to the surface of said core, where at least 90% of the ions bound to said carrier are formate ions; b) swelling said carrier in a polar solvent; c) providing a palladium (II) salt; d) suspending said carrier in an organic solvent thereby obtaining a suspension; e) adding said palladium salt to said suspension and allowing the resulting mixture to react at a temperature within the range of 0 70° C. until said carrier has turned black; f) washing said carrier in water; g) drying said carrier under vacuum.

Abstract translation: 本发明涉及适用于催化Heck，Suzuki-Miyaura Sonogashira偶联剂和Buchwald-Hartwig反应的多相催化剂的制备方法，包括以下步骤：a）提供大孔载体，所述大孔载体由核和多个 共价结合到所述芯的表面上的离子交换基团，其中与所述载体结合的至少90％的离子是甲酸根离子; b）在极性溶剂中溶胀载体; c）提供钯（II）盐; d）将所述载体悬浮在有机溶剂中，从而获得悬浮液; e）将所述钯盐加入到所述悬浮液中，并使所得混合物在0℃至70℃的温度下反应，直到所述载体变黑; f）在水中清洗载体; g）在真空下干燥所述载体。

公开(公告)号：US20090326300A1

公开(公告)日：2009-12-31

申请号：US12469821

申请日：2009-05-21

Applicant: Vincent COUPARD ,  Alexandra Chaumonnot

Inventor： Vincent COUPARD ,  Alexandra Chaumonnot

IPC: C07C1/20 ,  B01J31/02

CPC classification number: C07C1/20 ,  B01J29/0308 ,  B01J31/069 ,  B01J31/08 ,  B01J31/10 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/37 ,  C07C2521/08 ,  C07C2531/025 ,  C07C2531/04 ,  C07C11/10 ,  C07C11/02

Abstract: A process for cracking tert-alkyl ether(s) selected from among tert-amyl methyl ether (TAME) and ethyl tert-amyl ether (ETAE) for the production of tertiary olefins comprising bringing said tert-alkyl ether(s) into contact with at least one catalyst that is formed by at least one mesostructured hybrid organic-inorganic material that consists of at least two spherical elementary particles, whereby each of said spherical particles consists of a mesostructured matrix with a silicon oxide base to which are linked organic groups with acid terminal reactive functions, said groups representing less than 20 mol % of said matrix that is present in each of said spherical elementary particles, which have a maximum diameter of between 50 nm and 200 μm.

Abstract translation: 一种用于裂解选自叔戊基甲基醚（TAME）和乙基叔戊基醚（ETAE）的叔烷基醚的叔烷基醚用于生产叔烯烃的方法，包括使所述叔烷基醚与 至少一种催化剂，其由至少一种由至少两个球形基本颗粒组成的介孔结构化杂化有机 - 无机材料形成，其中每个所述球形颗粒由具有氧化硅基底的介孔结构基质组成，连接的有机基团与 酸末端反应性官能团，所述基团代表小于20摩尔％的所述基质，其存在于每个所述球形基本粒子中，其具有50nm至200μm的最大直径。

公开(公告)号：US20090169446A1

公开(公告)日：2009-07-02

申请号：US11980815

申请日：2007-10-31

Applicant: Steven C. Amendola ,  Michael Binder ,  Stefanie L. Sharp-Goldman ,  Michael T. Kelly ,  Phillip J. Petillo

Inventor： Steven C. Amendola ,  Michael Binder ,  Stefanie L. Sharp-Goldman ,  Michael T. Kelly ,  Phillip J. Petillo

IPC: B01J19/24

CPC classification number: C01B3/065 ,  B01J23/462 ,  B01J31/08 ,  B01J37/16 ,  B01J37/348 ,  Y02E60/362

Abstract: The present invention relates to a composition and method for storage and controlled release of hydrogen. In particular, the present invention relates to the use of borohydride based solutions as a hydrogen storage source and a catalyst system to release hydrogen therefrom.

Abstract translation: 本发明涉及氢的储存和控制释放的组合物和方法。 特别地，本发明涉及使用基于硼氢化物的溶液作为储氢源和从其中释放氢的催化剂体系。