公开(公告)号：US6100431A

公开(公告)日：2000-08-08

申请号：US88778

申请日：1998-06-02

Applicant: Neil W. Boaz

Inventor： Neil W. Boaz

IPC: C07C45/27 ,  C07C45/32 ,  C07C201/12 ,  C07C205/06 ,  C07C205/11 ,  C07C205/37 ,  C07C205/45 ,  C07C319/14 ,  C07C323/22 ,  C07C319/00

CPC classification number: C07C201/12 ,  C07C201/14 ,  C07C319/14 ,  C07C45/27 ,  C07C45/32

Abstract: The preparation of aromatic ketones substituted with a thioether group at the ortho position is accomplished by the initial reaction of an aromatic nucleus substituted with a halide and an ortho nitro group with a nitroalkane in the presence of a hydroxide base. The resulting ortho-nitroalkyl nitroarene compound is converted to the corresponding ortho-nitroaryl ketone by an oxidative Nef reaction. The aromatic nitro group of the ortho-nitroaryl ketone is replaced with a thioether group by reaction with a thiolate anion, most preferably under phase-transfer conditions. Aromatic ketones may be used to prepare various pharmaceutical and herbicidal compounds.

公开(公告)号：US4788346A

公开(公告)日：1988-11-29

申请号：US54852

申请日：1987-05-27

Applicant: Michel Desbois

Inventor： Michel Desbois

IPC: B01J27/12 ,  C07B61/00 ,  C07C67/00 ,  C07C201/00 ,  C07C201/08 ,  C07C201/12 ,  C07C201/14 ,  C07C205/22 ,  C07C205/43 ,  C07F9/12 ,  C07C79/24 ,  C07C76/02

CPC classification number: C07C201/14

Abstract: A process for the preparation of para-nitrophenol by bringing a phenyl ester of an inorganic acid into contact with a nitrating agent in the presence of liquid hydrofluoric acid and a hydrolysis of the nitrated product obtained is carried out either simultaneously or in sequence with the nitration.

Abstract translation: 通过使无机酸的苯基酯在液体氢氟酸的存在下与硝化剂接触并且所得到的硝化产物的水解而制备对硝基苯酚的方法同时或按照硝化步骤进行 。

公开(公告)号：US4540818A

公开(公告)日：1985-09-10

申请号：US490730

申请日：1983-05-02

Applicant: Keizaburo Yamaguchi ,  Kenichi Sugimoto ,  Yoshimitsu Tanabe ,  Saburo Kawashima ,  Akihiro Yamaguchi

Inventor： Keizaburo Yamaguchi ,  Kenichi Sugimoto ,  Yoshimitsu Tanabe ,  Saburo Kawashima ,  Akihiro Yamaguchi

IPC: C07B61/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/70 ,  B01J25/02 ,  B01J27/00 ,  B01J27/02 ,  B01J27/08 ,  C07C20060101 ,  C07C67/00 ,  C07C201/00 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C07C87/50

CPC classification number: C07C201/14 ,  C07C221/00

Abstract: Preparation of 3,3'- or 3,4'-diaminodiphenylmethane by catalytically reducing and dechlorinating, in the presence of a reduction catalyst, a dinitrobenzophenone compound having the formula ##STR1## wherein X is chlorine and attached to a position 4 or 6 on the benzene ring, and Y is hydrogen or chlorine with the proviso that when Y is hydrogen, the nitro group is attached to a position 3' or 4', and when Y is chlorine, Y is attached to a position 4' and the nitro group is attached to a position 3'.

Abstract translation: 在还原催化剂存在下，通过催化还原和脱氯制备3,3'-或3,4'-二氨基二苯基甲烷，其具有下式的二硝基二苯甲酮化合物，其中X是氯并且连接到位置4或6上 苯环，Y为氢或氯，条件是当Y为氢时，硝基连接到3'或4'位置，当Y为氯时，Y连接到位置4'，硝基 组附加到位置3'。

公开(公告)号：US4524226A

公开(公告)日：1985-06-18

申请号：US563209

申请日：1983-12-19

Applicant: Shu-Chieh P. Wang ,  Martin B. Sherwin

Inventor： Shu-Chieh P. Wang ,  Martin B. Sherwin

IPC: C07C45/29 ,  C07C201/14 ,  C07C201/16 ,  C07C205/02 ,  C07C79/02

CPC classification number: C07C45/29 ,  C07C201/14 ,  C07C201/16

Abstract: A process for selectively forming nitro compounds by contacting, at elevated temperature and pressure and in a homogeneous gas phase, an aldehyde having from two to ten carbon atoms with nitrogen dioxide alone or in the presence of oxygen and/or water.

Abstract translation: 通过在升高的温度和压力下，均匀气相中将二至十个碳原子的二氧化碳与二氧化氮单独或在氧气和/或水的存在下接触来选择性地形成硝基化合物的方法。

公开(公告)号：US4079076A

公开(公告)日：1978-03-14

申请号：US667796

申请日：1976-03-17

Applicant: Pius Anton Wehrli

Inventor： Pius Anton Wehrli

IPC: C07C20060101 ,  C07C120/00

CPC classification number: C07C201/12 ,  C07C201/14 ,  C07C213/02 ,  C07C253/00 ,  C07C67/29 ,  C07C2101/14 ,  C07C2101/16

Abstract: A novel conjugated diene bisfunctionalization process wherein a nitro group and a hydroxyl group in the form of an ester are introduced into the conjugated diene molecule by treatment of conjugated dienes with nitric acid in the presence of an acid anhydride. The novel compounds produced by this process and transformation products thereof, are useful as bactericides and fungicides and valuable organic synthesis intermediates, A novel procedure for the production of nitriles and .gamma.-acetoxytiglic aldehyde is disclosed.

Abstract translation: 通过在酸酐的存在下用硝酸处理共轭二烯，将硝基和酯形式的羟基引入到共轭二烯分子中的新型共轭二烯双官能化方法。 通过该方法生产的新化合物及其转化产物可用作杀菌剂和杀真菌剂和有价值的有机合成中间体。公开了一种制备腈和γ-乙酰氧基乙醛的新方法。

公开(公告)号：US3816404A

公开(公告)日：1974-06-11

申请号：US20619771

申请日：1971-12-08

Applicant: TEXACO INC

Inventor： KABLAOUI M ,  LOVE R ,  DURANLEAU R

IPC: C07C205/51 ,  C07D201/02 ,  C07D201/10 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07C201/12 ,  C07C201/14 ,  C07D201/10 ,  Y02P20/582 ,  C07C205/45 ,  C07C205/51

Abstract: A METHOD FOR PREPARING CAPROLACTAM BY THE STEPS OF (1) NITRO-OXIDIZING CYCLOHEXENE TO 2-NITROCYCOLHEXANONE, (2) CLEAVING AND ESTERIFYING 2-NITROCYCLOHEXANONE WITH AN ALCOHOL TO FORM AN ALKYL 6-NITROHEXANOATE AND (3) CATALYTICALLY HYDROGENATING AND CYCLIZING THE NITROESTER TO CAPROLACTAM.

公开(公告)号：US3787492A

公开(公告)日：1974-01-22

申请号：US3787492D

申请日：1971-12-06

Applicant: STANDARD OIL CO

Inventor： LEE R

IPC: C07C205/08 ,  C07G99/00 ,  C07C127/12

CPC classification number: C10M1/08 ,  C07C201/14 ,  C07G17/00 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2217/046 ,  C10M2217/06 ,  C10N2270/02 ,  C07C205/08

Abstract: OIL-SOLUBLE PRODUCTS USEFUL AS LUBRICATING OIL ADDITIVE TO IMPART DETERGENCY AND DISPERSANT PROPERTIES THERETO ARE PREPARED BY THE CONDENSATION OF ALPHA-NITRO ALKYL CHLORIDES, HAVING AT LEAST 10 CARBON ATOMS IN THE ALKYL SUBSTITUENT, WITH POLYAMINO UREAS IN THE MOLAR RATIO OF FROM ABOUT 1.0:0.5 TO ABOUT 1.0:1.0, RESPECTIVELY.

公开(公告)号：US3706808A

公开(公告)日：1972-12-19

申请号：US3706808D

申请日：1971-10-18

Applicant: PURDUE RESEARCH FOUNDATION

Inventor： BACHMAN GUSTAVE BRYANT ,  EISENSTEIN STEPHEN E

IPC: C07C205/02 ,  C07C79/04 ,  C07C79/08

CPC classification number: C07C201/14 ,  C07C2601/14 ,  C07C205/02 ,  C07C205/05

Abstract: A process for the production of a nitroalkane or dinitroalkane by reacting an olefin or diolefin with nitric acid in the presence of a lower aliphatic monocarboxylic acid anhydride, thereby producing a nitro-ester or dinitro-ester, and reducing the nitro-ester or dinitro-ester with an alkali borohydride to produce the nitroalkane or dinitroalkane.

Abstract translation: 通过使烯烃或二烯烃与硝酸在低级脂族一元羧酸酐的存在下反应生产硝基烷烃或二硝基烷烃的方法，从而产生硝基酯或二硝基酯，还原硝基酯或二硝基 - 酯与碱性硼氢化物反应生成硝基烷烃或二硝基烷烃。

公开(公告)号：US3681444A

公开(公告)日：1972-08-01

申请号：US3681444D

申请日：1970-09-21

Applicant: DU PONT

Inventor： SULLIVAN ROBERT H

IPC: C07C205/57 ,  C07C79/46

CPC classification number: C07C201/08 ,  C07C201/14 ,  C07C205/57

Abstract: Preparation of p-nitrobenzoic and 4''-nitro-4-biphenylcarboxylic acids by contacting a p-sulfo benzoic acid or 4''-sulfo-4biphenylcarboxylic acid with at least one molar proportion of nitric acid as a 5-60 percent by weight aqueous solution in the liquid phase at 120* C.-300* C. to displace the sulfo group by a nitro group and by contacting a benzenesulfonic acid or a 4biphenyl sulfonic acid bearing an oxidizable alkyl group para to the sulfo group with aqueous nitric acid or a mixture of nitric acid and molecular oxygen containing gas at a temperature of 120*-300* C. in a single overall reaction.

Abstract translation: 通过使对磺基苯甲酸或4'-磺基-4-联苯基羧酸与至少一摩尔比例的硝酸接触，制备对硝基苯甲酸和4'-硝基-4-联苯基羧酸，为5-60重量％ 在120℃-300℃的液相中的水溶液中，通过硝基置换磺基，并且使具有磺基的可氧化烷基对基团的苯磺酸或4-联苯磺酸与水溶液 硝酸或硝酸和含分子氧气体的混合物在120℃-300℃的温度下在单一的总体反应中进行。

公开(公告)号：US3585218A

公开(公告)日：1971-06-15

申请号：US3585218D

申请日：1967-05-24

Applicant: MINNESOTA MINING & MFG

Inventor： BALBOTT RICHARD L

IPC: C07C205/08 ,  C07C409/04 ,  C07C409/20 ,  C07C409/22 ,  C07C409/38 ,  C07D211/92 ,  C07C27/00

CPC classification number: C07D211/92 ,  C07C201/14 ,  C07C407/00 ,  C07C407/003 ,  C07C409/04 ,  C07C409/22 ,  C07C409/38 ,  Y10S149/119 ,  C07C205/08 ,  C07C409/16

Abstract: FLUORINATIVE OXIDATIONS ARE EFFECTED USING ENERGIZED FLUOROXY COMPOUNDS SUCH AS (FO)2CF2. THE PRODUCTS INCLUDE SELECTIVELY FLUORINATED COMPOUNDS IN WHICH FLUORINE MAY REPLACE HYDROGEN ON CARBON OR NITROGEN. REDUCTION PRODUCTS OF THE OXIDANT MAY INCLUDE PEROXY GROUPS NOT INITIALLY PRESENT.