公开(公告)号：US3740387A

公开(公告)日：1973-06-19

申请号：US3740387D

申请日：1971-02-24

Applicant: STANDARD OIL CO

Inventor： LEE R ,  HARRIS S

IPC: C10L1/24 ,  C07C161/00

CPC classification number: C10L1/2493 ,  C10M1/08 ,  C10M2221/04

Abstract: OIL-SOLUBLE COMPOUNDS ARE PREPARED BY REACTING A NITRO-NITRITO ALKANE CONTAINING AT LEAST TEN CARBON ATOMS, AN ALKYLENE POLYAMINE, AND SULLFUR IN THE MOLAR RATIO OF FROM ABOUT 1,0:0.03:1.0 TO ABOUT 1,0:0.5:2.0, RESPECTIVELY, COMPOUNDS SO FORMED ARE USEFUL ANTI-RUST, ADDITIVES IN OLEAGINOUS COMPOSITIONS.

公开(公告)号：US3798270A

公开(公告)日：1974-03-19

申请号：US3798270D

申请日：1971-12-29

Applicant: STANDARD OIL CO

Inventor： LEE R ,  LOANE C

IPC: B03D1/01 ,  C10L1/22 ,  C10L1/228 ,  C07C119/00

CPC classification number: C10L1/2283 ,  B03D1/01 ,  B03D2203/02 ,  C10L1/22 ,  Y10S516/07

Abstract: REACTION OF AN ALPHA-NITRO ALKYL AMINE CONTAINING NITRO AND AMINO GROUPS ON ADJACENT CARBON ATOMS WITH AN ALIPHATIC PRIMARY AMINE OR AN ALIPHATIC POLYAMINE AND SULFUR DIOXIDE REDUCES THE NITRO GROUP AND FORMS THE CORRESPONDING ALIPHATIC ALPHA-IMINO AMINE CONTAINING IMINO AND AMINO GROUPS ON ADJACENT CARBON ATOMS. SUCH ALIPHATIC ALPHA-IMINO AINES ARE USEFUL PER SE AS ANTIOXIDANTS, SURFACTANTS, DETERGENTS, ANTI-RUST AGENTS, AND FLOTATION AGENTS IN AQUEOUS AND HYDROCARBON SYSTEMS, OR AS CHEMICAL INTERMEDIATES, FOR EXAMPLE FOR PREPARATION OF DYES.

公开(公告)号：US3772373A

公开(公告)日：1973-11-13

申请号：US3772373D

申请日：1969-10-30

Applicant: STANDARD OIL CO

Inventor： LEE R

IPC: C07C303/02 ,  C07C309/86 ,  C07C143/70

CPC classification number: C07C303/08 ,  C07C309/86

Abstract: ALKYLBENZENE SULFONYL CHLORIDE:

1-R,3-(CL-SO2-)BENZENE

WHEREIN R IS AN ALKYL GROUP, CAN BE PREPARED BY A CHLOROSULFONATION OF ALKYLBENZENE HYDROCARBONS WITHOUT FORMATION OF SULFURIC ACID AND WITHOUT CHLORINATION OF ALKYLBENZENE SULFONIC ACID. SAID METHOD IS CARRIED OUT BY REACTING ALKYLBENZENE WITH 1.0:1.0 MOLAR MIXTURE OF CHLOROSULFONIC ACID (CISO3H) AND SULFURYLCHLORIDE (SO2CL2).

公开(公告)号：US3787492A

公开(公告)日：1974-01-22

申请号：US3787492D

申请日：1971-12-06

Applicant: STANDARD OIL CO

Inventor： LEE R

IPC: C07C205/08 ,  C07G99/00 ,  C07C127/12

CPC classification number: C10M1/08 ,  C07C201/14 ,  C07G17/00 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2217/046 ,  C10M2217/06 ,  C10N2270/02 ,  C07C205/08

Abstract: OIL-SOLUBLE PRODUCTS USEFUL AS LUBRICATING OIL ADDITIVE TO IMPART DETERGENCY AND DISPERSANT PROPERTIES THERETO ARE PREPARED BY THE CONDENSATION OF ALPHA-NITRO ALKYL CHLORIDES, HAVING AT LEAST 10 CARBON ATOMS IN THE ALKYL SUBSTITUENT, WITH POLYAMINO UREAS IN THE MOLAR RATIO OF FROM ABOUT 1.0:0.5 TO ABOUT 1.0:1.0, RESPECTIVELY.

公开(公告)号：US3711408A

公开(公告)日：1973-01-16

申请号：US3711408D

申请日：1970-04-01

Applicant: STANDARD OIL CO

Inventor： KARLL R ,  LEE R

IPC: C10M169/00 ,  C10M1/36 ,  C10M1/38

CPC classification number: C10M1/08 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/02

Abstract: POLYMETHYLENE-CONTAINING SULFONAMIDES OF ALKYL SUBSTITUTED BENZENE SULFINIC ACIDS WHOSE ALKYL-SUBSTITUENT HAS A MOLECULAR WEIGHT IN THE RANGE OF 400 TO 2800 ARE OIL SOLUBLE, IMPART THERMALLY STABLE DISPERSANCY TO OIL SOLUTIONS OF THE SULFONAMIDES. THE SULFONAMIDES ARE PREFERABLY POLYMETHYLENE--CONTAINING DIPRIMARY AMINES SUCH AS POLYAZALKYLENE DIAMINE, POLYMETHYLENE DIAMENE, POLYETHYLENE IMINES OF 1000-40,000 MOLECULAR WEIGHT AND DI(AMINOPOLYMETHYLENE) PIPERAZINE. THE SULFONAMIDES ARE CONVENIENTLY PREPARED AS SOLUTES IN LIGHT MINERAL OIL (WHITE OIL TO SAE 10 TYPE HYDROCARBON OIL) BY REACTION OF SUITABLE ALKYLBENZENE SULFONIC ACID CHLORIDE AND THE POLYMETHYLENE-CONTAINING DIPRIMARY AMINE IN THE PRESENCE OF PYRIDINE AND C5-C8 ALKANE, REMOVING THE ALKENE AND PYRIDINE, TREATING THE RESIDUE WITH A LIGHT MINERAL OIL SUSPENSION OF CALCIUM HYDROXIDE AND FILTERING THE RESULTING MIXTURE.

公开(公告)号：US3726901A

公开(公告)日：1973-04-10

申请号：US3726901D

申请日：1969-08-08

Applicant: STANDARD OIL CO

Inventor： LEE R

IPC: C08F8/00 ,  C07C63/32

CPC classification number: C08F8/00 ,  C08F110/10

Abstract: OIL-SOLUBLE COMPOUNDS ARE PREPARED BY HEATING AT REFLUX TEMPERATURE A MIXTURE OF AN ALKANE NITRO-AMINE, CONTAINING AT LEAST ABOUT TEN CARBON ATOMS, AND AN ORGANIC POLYBASIC ALIPHATIC OR AROMATIC ACID, OR THE ANHYDRIDE THEREOF, COMPOUNDS SO FORMED ARE USEFUL ADDITIVES IN OLEAGINOUS COMPOSITIONS.

公开(公告)号：US3718663A

公开(公告)日：1973-02-27

申请号：US3718663D

申请日：1970-08-31

Applicant: STANDARD OIL CO

Inventor： LEE R ,  PIASEK E ,  KARLL R

IPC: C07C275/14 ,  C07F5/02 ,  C10M133/56 ,  C10M135/16 ,  C07D27/00

CPC classification number: C07C275/14 ,  C07F5/022 ,  C10M133/56 ,  C10M135/16 ,  C10M2215/04 ,  C10M2215/086 ,  C10M2215/10 ,  C10M2215/102 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/064 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03

Abstract: Complex substituted alkylene polyamines such as di(alkenylsuccinimide) of N1,N3 symmetrical bis(aminopolyazalkylene) ureas that react with boric acid in oil solution either with low boric acid utilization efficiency or react to form a hazy product whose haze cannot be removed by filtration are readily converted to the desired oil solution of boron and nitrogen containing products by first preparing an oil solution of super boron containing product of the complex substituted alkylene polyamine, combining the oil solution of super boron containing product with oil solution of the complex substituted alkylene polyamine and equilibrating the resulting mixture to a uniform boron to nitrogen content throughout.

Abstract translation: 复合取代的亚烷基多胺如N1，N3对称双（氨基多亚氮烷基）脲的二（烯基 - 琥珀酰亚胺）对称双（氨基多亚氮烷基）脲，其与硼酸在油溶液中反应，具有低硼酸利用效率或反应，形成其雾度不能通过 通过首先制备复合取代的亚烷基多胺的含超级含硼产物的油溶液，将含超硼含量产物的油溶液与络合物取代的亚烷基的油溶液结合，过滤容易地转化为所需的含硼和氮的产物油溶液 并将所得混合物平衡至一致的硼至氮含量。