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Patent Agency Ranking
公开(公告)号：US12054677B2
公开(公告)日：2024-08-06
申请号：US17598551
申请日：2020-03-27
Applicant: BioBTX B.V.
Inventor： Niels Jan Schenk , André Heeres , Inouk Kruize-Muizebelt
Abstract: The present invention relates to a novel process for the preparation of low molecular weight aromatic compounds such as benzene, toluene, and xylenes (BTX) from plastics. Provided is a thermo-catalytic pyrolysis process for the preparation of aromatic compounds from a feed stream comprising plastic, comprising the steps of: a) subjecting a feed stream comprising a plastic to a pyrolysis treatment at a pyrolysis temperature in the range of 600-1000° C. to produce pyrolysis vapors; b) optionally cooling the pyrolysis vapors to a temperature that is below the pyrolysis temperature; e) contacting the vaporous phase with an aromatization catalyst at an aromatization temperature in the range of 450 700° C., which aromatization temperature is at least 50° C. lower than the pyrolysis temperature, in a catalytic conversion step to yield a conversion product comprising aromatic compounds; and d) optionally recovering the aromatic compounds from the conversion product.
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2.发明授权公开(公告)号：US11866650B2
公开(公告)日：2024-01-09
申请号：US16312433
申请日：2017-06-23
Applicant: BioBTX B.V.
Inventor： André Heeres , Niels Jan Schenk , Inouk Kruize-Muizebelt
CPC classification number: C10G1/02 , C10B57/06 , C10G1/002 , C10G1/086 , C10G45/50 , C10G2300/1011 , C10G2400/30
Abstract: A process for the preparation of aromatic compounds from a feed stream containing biomass or mixtures of biomass, the process comprising: a) subjecting a feed stream containing biomass or mixtures of biomass to a process to afford a conversion product comprising aromatic compounds; b) recovering the aromatic compounds from said conversion product; c) separating a higher molecular weight fraction comprising polyaromatic hydrocarbons (PAH) from a lower molecular weight fraction comprising benzene, toluene and xylene (BTX) by distillation; d) reducing at least part of said higher molecular weight fraction to obtain a reduced fraction comprising polycyclic aliphatics (PCA); and e) subjecting the higher molecular weight fraction obtained in step c), the reduced fraction obtained in step d), or a mixture thereof, to a process to obtain lower molecular weight aromatics (BTX).
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公开(公告)号：US20170247617A1
公开(公告)日：2017-08-31
申请号：US15513642
申请日：2014-09-25
Applicant: BioBTX B.V. , Rijksuniversiteit Groningen , KNN Advies B.V. , Syncom B.V.
Inventor： Niels Jan SCHENK , Arnold BIESBROEK , André HEERES , Hero Jan HEERES
CPC classification number: C10G1/086 , C10B53/02 , C10B57/06 , C10G1/002 , C10G1/10 , C10G3/42 , C10G3/49 , C10G29/16 , C10G35/04 , C10G35/065 , C10G35/095 , C10G35/12 , C10G35/14 , C10G2300/1003 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2400/30 , Y02E50/14 , Y02P20/145 , Y02P30/20
Abstract: Aromatic compounds are prepared from a feed stream comprising biomass or a mixture of biomass and synthetic polymer in a process, comprising: a) subjecting the feed stream to a pyrolysis treatment in the presence of a cracking catalyst to yield a vaporous fraction comprising hydrocarbons with olefinic unsaturation and oxygen containing organic compounds and coke-laden cracking catalyst; b) separating the vaporous fraction from the coke-laden cracking catalyst; c) contacting the vaporous fraction with a second, aromatization catalyst in a conversion treatment to yield a conversion product comprising aromatic compounds; and d) recovering aromatic compounds from the conversion product, wherein the cracking catalyst is a naturally occurring material, selected from the group consisting of inorganic salts, refractory oxides, minerals, industrial rock and mixtures thereof.
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公开(公告)号：US20220195310A1
公开(公告)日：2022-06-23
申请号：US17598551
申请日：2020-03-27
Applicant: BioBTX B.V.
Inventor： Niels Jan SCHENK , André HEERES , Inouk KRUIZE-MUIZEBELT
Abstract: The present invention relates to a novel process for the preparation of low molecular weight aromatic compounds such as benzene, toluene, and xylenes (BTX) from plastics. Provided is a thermo-catalytic pyrolysis process for the preparation of aromatic compounds from a feed stream comprising plastic, comprising the steps of: a) subjecting a feed stream comprising a plastic to a pyrolysis treatment at a pyrolysis temperature in the range of 600-1000° C. to produce pyrolysis vapors; b) optionally cooling the pyrolysis vapors to a temperature that is below the pyrolysis temperature; e) contacting the vaporous phase with an aromatization catalyst at an aromatization temperature in the range of 450 700° C., which aromatization temperature is at least 50° C. lower than the pyrolysis temperature, in a catalytic conversion step to yield a conversion product comprising aromatic compounds; and d) optionally recovering the aromatic compounds from the conversion product.
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5.发明申请公开(公告)号：US20200181498A1
公开(公告)日：2020-06-11
申请号：US16312433
申请日：2017-06-23
Applicant: BioBTX B.V.
Inventor： André HEERES , Niels Jan SCHENK , Inouk KRUIZE-MUIZEBELT
Abstract: A process for the preparation of aromatic compounds from a feed stream containing biomass or mixtures of biomass, the process comprising: a) subjecting a feed stream containing biomass or mixtures of biomass to a process to afford a conversion product comprising aromatic compounds; b) recovering the aromatic compounds from said conversion product; c) separating a higher molecular weight fraction comprising polyaromatic hydrocarbons (PAH) from a lower molecular weight fraction comprising benzene, toluene and xylene (BTX) by distillation; d) reducing at least part of said higher molecular weight fraction to obtain a reduced fraction comprising polycyclic aliphatics (PCA); and e) subjecting the higher molecular weight fraction obtained in step c), the reduced fraction obtained in step d), or a mixture thereof, to a process to obtain lower molecular weight aromatics (BTX).
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