Abstract:
A method of reacting an aromatic compound with an immiscible reacting agent involves the passage of the reactant along a flow path having a width of from 10 to 1000 &mgr;m in such a way that essentially laminar flow of the reactant takes place. Reaction takes place across the interface between the phases and without substantial mixing of the unreacted aromatic compound and the reacting agents. A preferred reaction is the nitration reaction which involves reaction of a first phase comprising an organic aromatic compound on a second phase comprising a nitrating agent to produce two new phases of different chemical composition to the starting phases. The aqueous and organic phases produced are ideally separated such that minimum contamination occurs. Other examples of this type of reaction include the sulphonation of an aromatic compound using sulphuric acid as the sulphonating agent. The aromatic compound is slowly consumed in the reaction yielding a single aqueous phase.
Abstract:
The turbine agitator assembly including a reservoir for liquid, a rotor mounted in the reservoir and with a plurality of radially extending blades, and sparger means for introducing a fluid into liquid in the reservoir. The fluid sparger means and the rotor are so constructed and arranged that, in use, the rotor blades (submerged in the liquid) and/or the liquid flow they generate disperse the sparged fluid. Each of the blades is hollow and has a discontinuous leading edge, only a single trailing edge along an acute angle, no external concave surface and an open radially outer end.
Abstract:
An electrode assembly for organic electrosynthesis (and a cell cascade comprising a plurality of such assemblies) for electrochemical reaction between a liquid first phase and a liquid (organic) second phase. The assembly comprises a non-permeable, electrically charged, rotated electrode, in use in contact with the first phase, to which the second phase is charged, and the reaction product of the two phases is removed from the electrode. Also, a process using the assembly or cascade.
Abstract:
A centrifugal absorption heat pump in which the heat released on condensation of the vapor of a first working fluid is used to generate a vapor from a solution of a second working fluid, and/or heat released on absorption of a third working fluid in an absorbent is used to evaporate a fourth working fluid.
Abstract:
A reactor including a rotatable disc (3) having a region (13) in an upper surface (5) thereof. Reactant (15) is supplied to the region (13) by way of a feed (4), the disc (3) is rotated at high speed, and the reactant (15) moves from the region (13) so as to form a film (17) on the surface (5). As the reactant (15) traverses the surface (5) of the disc (3), it undergoes chemical or physical processes before being thrown from the periphery of the disc (3) into collector means (7).
Abstract:
Steam-free non-catalytic cracking of hydrocarbons in reaction zomes each having surfaces heated externally and a heated surface to volume ratio above 3 cm-.sup.1, at a rate such that the flow through each reaction zone is essentially laminar.
Abstract:
An absorption-cycle heat pump comprises a rotary assembly including a vapor generator (GE,14), a condenser (CO,23), an absorber (AB,22), an evaporator (EV) and a solution heat exchanger (X,16). The vapor generator, the condenser and the absorber each include a wall (14, 23, 22 respectively) across which the volatile component (preferably water) and/or a liquid absorbent therefore are caused to flow under the action of the forces generated during rotation of the assembly. The evaporator comprises a plurality of finned heat exchange tubes 31 into which the volatile component is injected with a radially inwardly-directed component of motion, the tubes being of generally elliptical configuration disposed with their major axes extending generally radially. To maintain the evaporator heat exchange surfaces continuously wetted, excess volatile component is supplied such that a major part of the latter remains unvaporised after flow across the evaporator heat exchange surfaces and is collected in a reservoir (26), which also receives the condensate from the condenser, for re-injection into the evaporator tubes (31).
Abstract:
An electrode assembly for organic electrosynthesis (and a cell cascade comprising a plurality of such assemblies) for electrochemical reaction between a liquid first phase and a liquid (organic) second phase. The assembly comprises a non-permeable, electrically charged, rotated electrode, in use in contact with the first phase, to which the second phase is charged, and the reaction product of the two phases is removed from the electrode. Also, a process using the assembly or cascade.
Abstract:
Apparatus for effecting mass transfer between two fluid phases, at least the first of which is a liquid, which apparatus comprises an annular permeable element which is rotatable about its axis of symmetry, means to charge the first fluid to the permeable element, means to charge the second fluid to the permeable element, and means to discharge at least one of the fluids or a derivative thereof from the permeable element characterized in that the permeable element is formed by winding a tape under tension around the said axis and anchoring the tape to maintain it under tension.
Abstract:
A process for the conversion of a substantially fluid phase substrate by heterogeneous contact of the substrate or a fragment or derivative thereof with a substantially solid phase agent wherein the solid phase agent is comprised as a surface of a support element or part thereof and the support element is adapted to rotate around an axis such that the solid phase agent provides a rotating surface or part thereof and the substrate provides a film flowing substantially radially outward from the axis in dynamic contact with the agent.