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公开(公告)号：US07935757B2
公开(公告)日：2011-05-03
申请号：US12668233
申请日：2008-06-24
Applicant: Jurgen Scheerder , Emilio Martin , Gerardus Cornelis Overbeek
Inventor： Jurgen Scheerder , Emilio Martin , Gerardus Cornelis Overbeek
IPC: C08F2/28 , C08F220/34 , C08F220/10
CPC classification number: C08F2/28 , C08F220/14 , C08F220/18 , C08F220/34 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C09D4/00 , C09D151/003 , Y10T428/31935 , C08L2666/02
Abstract: A process is described for making an aqueous coating composition comprising a cationic vinyl oligomer comprising the following steps: I. preparation of a cationic vinyl oligomer by solution or bulk polymerization of components: i) 2 to 50 wt % of vinyl monomers bearing amine functional groups selected from the group consisting of non-ionic amine functional groups (a), permanent quaternary ammonium functional groups (b), neutralized amine functional groups (c) and mixtures thereof; and ii) 20 to 98 wt % of Ci to Ci8 alkyl (meth)acrylates; and II. dispersion of the cationic vinyl oligomer in an aqueous medium and neutralization of non-ionic amine functional groups.
Abstract translation: 描述了一种制备包含阳离子乙烯基低聚物的水性涂料组合物的方法，其包括以下步骤：I.通过组分的溶液或本体聚合制备阳离子乙烯基低聚物：i）2至50重量％的带有胺官能团的乙烯基单体 选自非离子胺官能团（a），永久性季铵官能团（b），中和胺官能团（c）及其混合物; 和ii）20至98重量％的C 1-8烷基（甲基）丙烯酸酯; 和II。 阳离子乙烯基低聚物在水性介质中的分散和非离子胺官能团的中和。
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公开(公告)号：US20060258801A1
公开(公告)日：2006-11-16
申请号：US10570163
申请日：2004-07-26
Applicant: Emilio Martin , Gerardus Overbeek , Marc Roelands , Rajasingham Satgurunathan
Inventor： Emilio Martin , Gerardus Overbeek , Marc Roelands , Rajasingham Satgurunathan
CPC classification number: C08G18/12 , C08G18/6692 , C09D175/04 , C08G18/3231 , C08L2666/20 , C08L2666/04
Abstract: An aqueous coating composition comprising: (i) (10) to (80) wt % of a polyurethane A which exhibits a minimum film forming temperature of ≦ambient temperature and which comprises a polyurethane obtained by the reaction of: (a) an isocyanate-terminated pre-polymer formed from components which comprise: (1) 10 to 30 wt % of a polyisocyanate; (2) 0.1 to 10 wt % of a polyol of weight average molecular weight less than 500, containing ionic or potentially ionic water-dispersing groups, and having two or more isocyanate-reactive groups; (3) 0 to 15 wt % of a polyol containing non-ionic water dispersing groups having two or more isocyanate-reactive groups; (4) 40 to 80 wt % of a polyol other than (2) or (3), having two or more isocyanate-reactive groups; where (1), (2), (3) and (4) add up to 100%; and (b) an active-hydrogen chain extending compound; and (ii) 20 to 90 wt % of a polymer dispersion B which exhibits a minimum film forming temperature of above ambient temperature; wherein (i) and (ii) add up to 100%. Processes for manufacture of said composition and methods of application to substrates are also described.
Abstract translation: 一种水性涂料组合物，其包含：（i）（10） - （80）wt％的聚氨酯A，其表现出最小成膜温度<=环境温度，并且其包含通过以下反应获得的聚氨酯：（a）异氰酸酯 由包含以下组分的组分形成的终止预聚物：（1）10至30重量％的多异氰酸酯; （2）0.1〜10重量％的重均分子量小于500的多元醇，其含有离子或潜在离子性水分散基团，并且具有两个或多个异氰酸酯反应性基团; （3）含有2个以上异氰酸酯反应性基团的非离子性水分散基团的多元醇0〜15重量％ （4）40〜80重量％的具有2个以上异氰酸酯反应性基团的（2）或（3）以外的多元醇; 其中（1），（2），（3）和（4）加起来为100％; 和（b）活性氢链增长化合物; 和（ii）20〜90重量％的表现出最高成膜温度高于环境温度的聚合物分散体B; 其中（i）和（ii）加起来为100％。 还描述了用于制造所述组合物的方法和施加于基材的方法。
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公开(公告)号：US20240124128A1
公开(公告)日：2024-04-18
申请号：US18555961
申请日：2022-04-18
Applicant: Emilio MARTIN ALEXANDRE
Inventor： Emilio MARTIN ALEXANDRE
Abstract: Consisting of a flap-type aerodynamic surface on the wing(s) (2) above the fuselage (1) of an aircraft with control surfaces (5) of the wing (2), the length of the device in the wing span direction being greater than or equal to the mid-chord of the flap, and comprising a thrust propeller engine (4), converting it into a propulsive flapper (3).
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公开(公告)号：US07223813B2
公开(公告)日：2007-05-29
申请号：US10380950
申请日：2001-10-11
Applicant: Alfred Jean Paul Buckmann , Emilio Martin , Gerardus Cornelis Overbeek , John Christopher Padget , Jurgen Scheerder , Tom Annable
Inventor： Alfred Jean Paul Buckmann , Emilio Martin , Gerardus Cornelis Overbeek , John Christopher Padget , Jurgen Scheerder , Tom Annable
CPC classification number: C09D201/00 , C09D133/062 , C08L2666/02
Abstract: An aqueous coating composition comprising a crosslinkable water-dispersible vinyl oligomer(s) wherein said composition when drying to form a coating has an open time of at least 20 minutes, a wet edge time of at least 10 minutes, a tack free time of ≦20 hours and an equilibrium viscosity of ≦5,000 Pa·s at any solids content when drying in the range of from 20 to 55 wt % using any shear rate in the range of from 9±0.5 to 90±5 s−1 and at 23±2° C.
Abstract translation: 一种包含可交联的水分散性乙烯基低聚物的水性涂料组合物，其中当干燥形成涂料时所述组合物的开放时间为至少20分钟，湿边缘时间为至少10分钟， = 20小时，当使用任何剪切速率在9±0.5至90±5s范围内干燥时，任何固体含量的平均粘度<= 5,000Pa·s。 -1和23±2℃
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公开(公告)号：US07094826B2
公开(公告)日：2006-08-22
申请号：US10381811
申请日：2001-10-11
Applicant: Emilio Martin , Gerardus Cornelis Overbeek , Pablo Steenwinkel , Ronald Tennebroek
Inventor： Emilio Martin , Gerardus Cornelis Overbeek , Pablo Steenwinkel , Ronald Tennebroek
IPC: C08J3/00 , C08K3/20 , C08L51/00 , C08L75/00 , C08G65/333
CPC classification number: C08G83/005 , C09D201/005
Abstract: An aqueous coating composition comprising a crosslinkable water-dispersible hyperbranched macromolecule(s) wherein the composition when drying has an open time of at least 20 minutes, a wet edge time of at least 10 minutes, a tack free time ≦15 hours, a dust free time ≦5 hours and an equilibrium viscosity of ≦5,000 Pa·s at any solids content when drying in the range of from 20 to 55% by weight using any shear rate in the range of from 9±0.5 to 90±5 s−1 and at 23±2° C.
Abstract translation: 一种水性涂料组合物，其包含可交联的水分散性超支化高分子，其中当干燥时的组合物的开放时间为至少20分钟，湿边缘时间为至少10分钟，无粘性时间<= 15小时， 无干燥时间<= 5小时，任何固体含量的平均粘度<= 5,000Pa·s，当干燥范围为20-55％（重量）时，任何剪切速率在9±0.5至90± 5秒-1和23±2℃
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Patent Agency Ranking
6.发明申请Aqueous coating composition comprising non-crosslinkable oligomer(s) and dispersed polymer(s) 有权包含不可交联的低聚物和分散的聚合物的水性涂料组合物，公开(公告)号：US20050182180A1
公开(公告)日：2005-08-18
申请号：US10509223
申请日：2003-03-21
Applicant: Emilio Martin , Jurgen Scheerder , Gerardus Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
Inventor： Emilio Martin , Jurgen Scheerder , Gerardus Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
IPC: C09D167/00 , C09D175/04 , C08K3/20
CPC classification number: C09D167/00 , C09D175/04 , C08L2666/04
Abstract: An aqueous coating composition comprising a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 min; a wet edge time of at least 10 min; a tack free time of ≦24 hrs and an equilibrium viscosity of 5,000 Pa·s.
Abstract translation: 一种包含不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少为10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。
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公开(公告)号：US20110027602A1
公开(公告)日：2011-02-03
申请号：US12668233
申请日：2008-06-24
Applicant: Jurgen Scheerder , Emilio Martin , Gerardus Cornelis Overbeek
Inventor： Jurgen Scheerder , Emilio Martin , Gerardus Cornelis Overbeek
CPC classification number: C08F2/28 , C08F220/14 , C08F220/18 , C08F220/34 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C09D4/00 , C09D151/003 , Y10T428/31935 , C08L2666/02
Abstract: A process is described for making an aqueous coating composition comprising a cationic vinyl oligomer comprising the following steps: I. preparation of a cationic vinyl oligomer by solution or bulk polymerisation of components: i) 2 to 50 wt % of vinyl monomers bearing amine functional groups selected from the group consisting of non-ionic amine functional groups (a), permanent quaternary ammonium functional groups (b), neutralised amine functional groups (c) and mixtures thereof; and ii) 20 to 98 wt % of Ci to Ci8 alkyl (meth)acrylates; and II. dispersion of the cationic vinyl oligomer in an aqueous medium and neutralisation of non-ionic amine functional groups.
Abstract translation: 描述了一种制备包含阳离子乙烯基低聚物的水性涂料组合物的方法，其包括以下步骤：I.通过组分的溶液或本体聚合制备阳离子乙烯基低聚物：i）2至50重量％的带有胺官能团的乙烯基单体 选自非离子胺官能团（a），永久性季铵官能团（b），中和胺官能团（c）及其混合物; 和ii）20至98重量％的C 1-8烷基（甲基）丙烯酸酯; 和II。 阳离子乙烯基低聚物在水性介质中的分散和非离子胺官能团的中和。
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公开(公告)号：US07022759B2
公开(公告)日：2006-04-04
申请号：US10380952
申请日：2001-10-11
Applicant: Emilio Martin , Gerardus Cornelis Overbeek , John Christopher Padget , Pablo Steenwinkel , Petrus Johannes Maria Van Oorschot , Ronald Tennebroek
Inventor： Emilio Martin , Gerardus Cornelis Overbeek , John Christopher Padget , Pablo Steenwinkel , Petrus Johannes Maria Van Oorschot , Ronald Tennebroek
IPC: C09D167/02 , C09D123/00 , C09D131/00 , C09D133/00
CPC classification number: C09D167/08 , C09D167/00
Abstract: An aqueous coating composition comprising a crosslinkable water-dispersible polyester oligomer wherein said composition when drying to form a coating has the following properties: an open time of at least 20 minutes, a wet edge time of at least 10 minutes, a thumb hard time of ≦48 hours and a tack-free time ≦20 hours and an equilibrium viscosity of ≦5000 Pa.s at any solids content when drying in the range of from 20 to 55 wt % using a shear rate in the range of from 9±0.5 to 90±5 s−1 and at 23±2° C.
Abstract translation: 一种包含可交联的水分散性聚酯低聚物的水性涂料组合物，其中所述组合物在干燥以形成涂层时具有以下性质：开放时间为至少20分钟，湿边缘时间为至少10分钟，拇指硬化时间为 <= 48小时，无粘性时间<= 20小时，当以20至55重量％的范围干燥时，任何固体含量的平均粘度<= 5000Pa.s，其剪切速率范围为 9±0.5至90±5秒-1和23±2℃
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公开(公告)号：US06362273B1
公开(公告)日：2002-03-26
申请号：US09509376
申请日：2000-03-27
Applicant: Emilio Martin , Gerardus Cornelis Overbeek , Yvonne Wilhelmina Smak
Inventor： Emilio Martin , Gerardus Cornelis Overbeek , Yvonne Wilhelmina Smak
IPC: C08J300
CPC classification number: C08G18/4854 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/3231
Abstract: Aqueous polymer dispersion containing a water-dispersed polyurethane polymer and a vinyl (preferably acrylic) polymer in a weight ratio of from 30/70 to 5/95, wherein said polyurethane polymer is the reaction product of: A) an isocyanate-terminated polyurethane prepolymer having an acid value of ≧44 mg KOH/g of prepolymer (solids) and formed from reactants comprising an organic polyisocyanate component and an organic poly(isocyanate-reactive) group) component in which the isocyanate-reactive groups are selected from —OH and optionally one or more of —NH2, —NH—, and —SH (usually a polyol), wherein i) at least 70 weight % of said polyisocyanate component is constituted by at least one aliphatic polyisocyanate, ii) said poly(isocyanate-reactive group) component includes at least one acid-bearing poly(isocyanate-reactive group) compound for providing anionic groups which provide or contribute to water-dispersibility, iii) the reactants are used in amounts corresponding to a ratio of isocyanate groups to isocyanate-reactive groups (usually hydroxyl) within the range of 1.4/1 to 2.9/1; and B) an active hydrogen chain-extending compound(s).
Abstract translation: 含有水分散聚氨酯聚合物和重量比为30/70至5/95的乙烯基（优选丙烯酸））聚合物的水性聚合物分散体，其中所述聚氨酯聚合物是以下物质的反应产物：A）异氰酸酯封端的聚氨酯预聚物 具有> = 44mg KOH / g预聚物（固体）并由包含有机多异氰酸酯组分和有机聚异氰酸酯反应性基团的反应物形成的酸值）组分，其中异氰酸酯反应性基团选自-OH 和任选的一个或多个-NH 2，-NH-和-SH（通常为多元醇），其中i）至少70重量％的所述多异氰酸酯组分由至少一种脂族多异氰酸酯构成，ii）所述聚（异氰酸酯反应性 基团）组分包括提供或有助于水分散性的阴离子基团的至少一种含酸聚（异氰酸酯反应性基团）化合物，iii）反应物以与异氰酸酯的比例相对应的量使用 e至异氰酸酯反应性基团（通常为羟基）在1.4 / 1至2.9 / 1的范围内; 和B）活性氢链延长化合物。
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公开(公告)号：US08334352B2
公开(公告)日：2012-12-18
申请号：US12678571
申请日：2008-09-19
Applicant: Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
Inventor： Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
CPC classification number: C08F290/06 , C07C229/12 , C08F222/1006 , C08F290/061 , C08F290/062 , C08F290/065 , C08F290/14 , C08F290/141 , C08F290/142 , C08F290/145 , C08G65/3322 , C08G65/33306 , C09D7/20
Abstract: The present invention relates to a method for preparing a branched non dendrimeric macromolecule, comprising: a) providing an addition product of an α,β-olefinically unsaturated compound and an amine comprising at least two hydroxyl groups; and b) esterifying at least part of the hydroxyl groups of the addition product with an olefinically unsaturated carboxylic acid, an olefinically unsaturated carboxylate anion or an olefinically unsaturated carboxylic acid anhydride. The invention further relates to macromolecules obtainable by a method of the invention.
Abstract translation: 本发明涉及一种制备支链非树枝状大分子的方法，其包括：a）提供α，β-烯属不饱和化合物和包含至少两个羟基的胺的加成产物; 和b）用烯属不饱和羧酸，烯属不饱和羧酸根阴离子或烯属不饱和羧酸酐酯化加成产物的至少部分羟基。 本发明还涉及通过本发明的方法获得的大分子。
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