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    High-performance overprint varnishes comprising composite SMA latices
    3.
    发明授权
    High-performance overprint varnishes comprising composite SMA latices 失效
    高性能套印清漆，包括复合SMA胶乳

    公开(公告)号：US5902846A

    公开(公告)日：1999-05-11

    申请号：US925275

    申请日：1997-09-08

    Applicant: Bruno Feret ,  Isabelle Betremieux

    Inventor： Bruno Feret ,  Isabelle Betremieux

    IPC: C08F257/02 ,  C08L35/06 ,  C09D151/00 ,  C09D191/06 ,  C08L91/06

    CPC classification number: C09D191/06 ,  C08F257/02 ,  C09D151/003 ,  C08L35/06

    Abstract: High-performance overprint varnishes, well-suited for the protective coating of a wide variety of substrates, e.g., papers, cardboards and packaging materials, include a composite latex and characteristically a polyethylene wax emulsion, the composite latex comprising the copolymerizate of at least one hydrophobic monomer within an aqueous solution of a styrene/maleic anhydride resin, the styrene/maleic anhydride resin having a molecular weight ranging from 500 to 5,000 and an acid number of at most 500, and the amount by weight of the styrene/maleic anhydride resin in the copolymerizate ranging from 5% to 50%.

    Abstract translation: 适用于各种基材例如纸，纸板和包装材料的保护涂层的高性能套印清漆包括复合胶乳和特征为聚乙烯蜡乳液，所述复合胶乳包含至少一种 苯乙烯/马来酸酐树脂的水溶液中的疏水性单体，苯乙烯/马来酸酐树脂的分子量范围为500〜5000，酸值为500以下，苯乙烯/马来酸酐树脂的重量 在共聚物中为5％至50％。

    Method for preparing saccharide monomers comprising at least one polymerizable carbonyl-oxyvinyl group
    6.
    发明授权
    Method for preparing saccharide monomers comprising at least one polymerizable carbonyl-oxyvinyl group 失效
    制备包含至少一个可聚合的羰基 - 氧基乙烯基的糖单体的方法

    公开(公告)号：US5543512A

    公开(公告)日：1996-08-06

    申请号：US378707

    申请日：1995-01-26

    Applicant: Julio Mentech ,  Isabelle Betremieux ,  Bruno Legger

    Inventor： Julio Mentech ,  Isabelle Betremieux ,  Bruno Legger

    IPC: C07H13/04 ,  C07H13/02 ,  C07H1/00

    CPC classification number: C07H13/04

    Abstract: The invention concerns a process for preparing saccharide monomers comprising at least one polymerizable acrylate or methacrylate group whereby the saccharide used in the process is selected from mono-, di- and tri-saccharides, in particular from non-reducing mono-, di- and tri-saccharides. The process comprises reacting the saccharide in an aqueous medium with an esterifying reagent containing the polymerizable acrylate or methacrylate group in the presence of a base while maintaining the pH of the reaction medium to a value within the range of 7 to 11 during the entire reaction time. The invention furthermore concerns saccharide monomers comprising at least one polymerizable acrylate or methacrylate group with a controlled degree of substitution.

    Abstract translation: 本发明涉及一种制备包含至少一种可聚合的丙烯酸酯或甲基丙烯酸酯基团的糖单体的方法，由此该方法中使用的糖选自单糖，二糖和三糖，特别是选自非还原性单，二和二糖 三糖。 该方法包括在碱的存在下，使水性介质中的糖与含有可聚合的丙烯酸酯或甲基丙烯酸酯基团的酯化试剂反应，同时在整个反应时间内将反应介质的pH保持在7至11的范围内 。 本发明还涉及包含至少一个具有受控取代度的可聚合丙烯酸酯或甲基丙烯酸酯基团的糖单体。

    AQUEOUS SELF-CROSSLINKABLE POLYMER DISPERSION MADE FROM HARD-CORE, SOFT-SHELL STRUCTURED POLYMER PARTICLES, AND COATING OR TREATMENT COMPOSITIONS
    7.
    发明申请
    AQUEOUS SELF-CROSSLINKABLE POLYMER DISPERSION MADE FROM HARD-CORE, SOFT-SHELL STRUCTURED POLYMER PARTICLES, AND COATING OR TREATMENT COMPOSITIONS 审中-公开
    来自硬核，软壳结构聚合物颗粒和涂层或处理组合物的水性自交联聚合物分散体

    公开(公告)号：US20120121903A1

    公开(公告)日：2012-05-17

    申请号：US13386452

    申请日：2010-07-15

    Applicant: Isabelle Betremieux ,  Alain Boone ,  Jean-Yves Loze

    Inventor： Isabelle Betremieux ,  Alain Boone ,  Jean-Yves Loze

    IPC: C09D133/12 ,  B32B5/00 ,  C09D11/10

    CPC classification number: C08F2/24 ,  C08F220/14 ,  C08F265/00 ,  C08F265/04 ,  C08F291/00 ,  C08L51/003 ,  C08L2666/02 ,  C09D133/14 ,  C09D151/003 ,  C09J151/003 ,  Y10T428/2933 ,  C08F220/06 ,  C08F2220/1825 ,  C08F222/1006

    Abstract: The present invention relates to an aqueous polymer dispersion, which includes hard/soft Shell structured particles, with the polymer phase of the core P1 having a glass transition temperature Tg1 from 60 to 120° C., the polymer phase of the shell P2 having a glass transition temperature Tg2 from −20 to 40° C., the minimum film-formation temperature MFFT being from 0 to 50° C., with the phase P1 representing from 1.5 to 60% by weight, with respect to the total weight of P1+P2, the phase P1 including at least one monomer M1 having at least two copolymerizable ethylenic unsaturations and at least one ethylenically unsaturated monomer M2 having at least one carboxylic acid and/or anhydride functional group, the phase P2 being from 40 to 85% by weight of the total weight of P1+P2 and with said phase P2 including: at least one monomer M3 selected from the monomers having, in addition to the polymerizable ethylenic unsaturation, at least one group selected from acetoacetoxy, diacetone, methylol or alkoxysilane. The invention also relates to protective and/or decorative coating compositions such as paints, varnishes, transparent coatings, inks or adhesives and fiber treatment compositions.”

    Abstract translation: 本发明涉及一种水性聚合物分散体，其包括硬/软壳结构的颗粒，芯P1的聚合物相的玻璃化转变温度Tg1为60-120℃，壳P2的聚合物相具有 玻璃化转变温度Tg2为-20〜40℃，最低成膜温度MFFT为0〜50℃，相P1相对于P1的总重量为1.5〜60重量％ + P2，相P1包含至少一种具有至少两个可共聚的烯属不饱和度的单体M1和至少一种具有至少一个羧酸和/或酸酐官能团的烯属不饱和单体M2，相P2为40-85％ P1 + P2的总重量和所述相P2的重量包括：至少一种单体M3，其选自除了可聚合的烯属不饱和键之外的至少一种选自乙酰乙酰氧基，双丙酮， 羟甲基或烷氧基硅烷。 本发明还涉及保护性和/或装饰性涂料组合物，例如油漆，清漆，透明涂料，油墨或粘合剂和纤维处理组合物。

    Finely particulate composite latices and use thereof in solvent-free paints
    9.
    发明授权
    Finely particulate composite latices and use thereof in solvent-free paints 失效
    细颗粒复合胶乳及其在无溶剂涂料中的应用

    公开(公告)号：US6054526A

    公开(公告)日：2000-04-25

    申请号：US63

    申请日：1998-01-20

    Applicant: Isabelle Betremieux ,  Bruno Feret ,  Christophe Verge

    Inventor： Isabelle Betremieux ,  Bruno Feret ,  Christophe Verge

    IPC: C08F2/16 ,  C08F2/22 ,  C08F257/02 ,  C08F291/00 ,  C09D151/00 ,  C09D151/06

    CPC classification number: C09D151/06 ,  C08F257/02 ,  C08F291/00 ,  C09D151/003

    Abstract: Composite latex whose average particle size is between 30 and 150 nm, as these particles result from polymerization of a mixture hydrophobic monomers composed of styrene and (meth)acrylic esters to produce an emulsion in an aqueous solution of a water-soluble or water-dispersible amphiphilic copolymer having a molecular weight of between 500 and 5,000 and whose acid number of less than 500, said latex being composed of a combination of hydrophobic and hydrophilic monomers incorporating carboxylic acid functions in the presence of a radical-producing initiator, wherein said aqueous water-soluble amphiphilic polymer is free of any other surfactant or protective colloid and wherein the mass percentage of amphiphilic copolymer in relation to the dry extract of the latex between 10 and 50%.

    Abstract translation: PCT No.PCT / FR96 / 01633 Sec。 371日期1998年1月20日 102（e）1998年1月20日PCT PCT 1996年10月18日PCT公布。 公开号WO97 / 15604 日期1997年5月1日平均粒径为30〜150nm的复合胶乳，由于这些颗粒是由苯乙烯和（甲基）丙烯酸酯组成的疏水性单体的混合物聚合而产生的水溶性水溶液中的乳液 或水分散性两亲共聚物，其分子量为500-5,000，酸值小于500，所述胶乳由在产生自由基的引发剂存在下引入羧酸官能团的疏水性和亲水性单体的组合构成， 其中所述水溶性水溶性两亲性聚合物不含任何其它表面活性剂或保护胶体，并且其中两亲共聚物相对于乳胶的干提取物的质量百分比为10至50％。

    Aqueous polymer dispersion for barrier coating
    10.
    发明授权
    Aqueous polymer dispersion for barrier coating 有权
    用于阻隔涂层的聚合物水分散体

    公开(公告)号：US07820754B2

    公开(公告)日：2010-10-26

    申请号：US11071979

    申请日：2005-03-04

    Applicant: Isabelle Betremieux ,  Baudouin Duque ,  Leo Saija

    Inventor： Isabelle Betremieux ,  Baudouin Duque ,  Leo Saija

    IPC: C08G63/91

    CPC classification number: C08F257/02 ,  C08F2/22 ,  C08F212/08 ,  C08F220/06 ,  C08F220/18 ,  C08F220/44 ,  C08F220/58 ,  C08F230/02 ,  C08G63/672 ,  C08K5/25 ,  C08L2201/50 ,  C09D143/02 ,  C08F2/26 ,  C08F2/24 ,  C08L25/14

    Abstract: The invention relates to an aqueous polymer dispersion which can be obtained from a mixture of monomers comprising, in parts by weight: a) 100 of at least one ethylenically unsaturated monomer not comprising an ionic group, b) 0.5 to 15 of at least one ethylenically unsaturated monomer carrying at least one carboxyl and/or carboxylic anhydride functional group, c) at least one ethylenically unsaturated monomer carrying at least one second functionality selected from: phosphate, phosphonate or phosphinate, in an amount such that the ratio c/(b+c) varies from 0.05 to 0.4, d) 0 to 2 of at least one ethylenically unsaturated monomer carrying at least one alkoxysilane functional group, e) 0 to 5 of at least one ethylenically unsaturated monomer additionally carrying at least one active carbonyl functional group or an other aldhehyde-reactive functional group, such as an ureido derivative, or morpholine, imidazoline, oxazolidine, aziridine, or an aldhehyde-reactive amine function, f) 0 to 10, preferably 2 to 8, of at least one ethylenically unsaturated monomer carrying at least one functional group selected from hydroxyl and primary or secondary amine. The invention also relates to a preparation process, to a coating composition comprising the said dispersion and to a method of use in coatings for metal or plastic substrates, in particular corrosion-inhibiting coatings for metal substrates.

    Abstract translation: 本发明涉及一种水性聚合物分散体，其可以由单体混合物获得，所述混合物包含以重量份计：a）100种至少一种不包含离子基团的烯属不饱和单体，b）至少一种烯键式 携带至少一个羧基和/或羧酸酐官能团的不饱和单体，c）至少一种携带至少一种选自磷酸酯，膦酸酯或次膦酸酯的第二官能团的烯属不饱和单体，其量使得c /（b + c）从0.05至0.4，d）0至2的至少一种带有至少一个烷氧基硅烷官能团的烯属不饱和单体，e）0至5个至少一种烯键式不饱和单体，其另外携带至少一个活性羰基官能团或 另一种醛脱水反应性官能团，例如脲基衍生物或吗啉，咪唑啉，恶唑烷，氮丙啶或醛交换反应性胺官能团，f）0至10 ，优选2至8个至少一种含有至少一个选自羟基和伯胺或仲胺的官能团的烯属不饱和单体。 本发明还涉及一种制备方法，包括所述分散体的涂料组合物和用于金属或塑料基材的涂料的方法，特别是用于金属基材的防腐涂料。

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