公开(公告)号：US06890364B2

公开(公告)日：2005-05-10

申请号：US10322760

申请日：2002-12-19

Applicant: Bruno Delfort ,  Isabelle Durand ,  Anne Jaecker ,  Thierry Lacome ,  Xavier Montagne ,  Fabrice Paille

Inventor： Bruno Delfort ,  Isabelle Durand ,  Anne Jaecker ,  Thierry Lacome ,  Xavier Montagne ,  Fabrice Paille

IPC: C10L1/02 ,  C10L1/08 ,  C10L1/18 ,  C10L1/24 ,  C10L10/02

CPC classification number: C10L1/1855 ,  C10L1/026 ,  C10L10/02

Abstract: A diesel fuel compound has a major proportion of at least one diesel fuel and a minor proportion of at least one glycerol acetal corresponding to one of general formulas: in which: R1 and R2 each represent a hydrogen atom, a hydrocarbon radical with 1 to 20 carbon atoms, aliphatic, cycloaliphatic or aromatic, or an alkyl-ether chain, R1 and R2 being able together to form an oxygenated heterocyclic radical; R3 represents a hydrogen atom or a radical of general formula: where R4 is a radical defined as R1 or R2, except for the hydrogen atom, or a radical of general formula: where R1 and R2 are defined as above, the sum of the number of carbon atoms of R1, R2 and R3 in formulas (1) and (2) being at least 2 and it has no metal compounds of group IIA.

Abstract translation: 柴油燃料化合物具有主要比例的至少一种柴油燃料和少量至少一种对应于以下通式之一的甘油缩醛：其中：R 1和R 2各自表示氢原子，具有1至20个碳原子的烃基 碳原子，脂族，脂环族或芳族，或烷基 - 醚链，R1和R2能够一起形成含氧杂环基; R3表示氢原子或通式的基团：其中R4是除了氢原子以外定义为R1或R2的基团，或下列通式的基团：其中R1和R2如上所定义，数字之和 式（1）和（2）中R 1，R 2和R 3的碳原子数为2以上，并且不具有IIA族的金属化合物。

公开(公告)号：US20070283619A1

公开(公告)日：2007-12-13

申请号：US10590351

申请日：2005-01-27

Applicant: Gerard Hillion ,  Bruno Delfort ,  Isabelle Durand

Inventor： Gerard Hillion ,  Bruno Delfort ,  Isabelle Durand

IPC: C10L1/18

CPC classification number: C10L1/1855 ,  C07C67/03 ,  C10G2300/1011 ,  C10L1/026 ,  C10L1/1852 ,  C10L1/19 ,  C11C3/003 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/52

Abstract: A process for producing biofuels by transforming triglycerides into at least two families of biofuels, monoesters of fatty acids and soluble ethers and/or acetals of glycerol, comprises: at least one transesterification step in which said triglyceride is reacted by heterogeneous catalysis with at least one primary monoalcohol selected from methanol and ethanol to produce at least one methyl and/or ethyl ester of the fatty acids of the starting triglycerides and glycerol, said products being free of by-products; and an etherification step in which the glycerol is reacted with at least one olefinic hydrocarbon containing 4 to 12 carbon atoms; and/or an acetalization step in which the glycerol is reacted with at least one compound selected from aldehydes, ketones and acetals derived from aldehydes or ketones.

Abstract translation: 通过将甘油三酯转化为至少两个生物燃料，脂肪酸的单酯和甘油的可溶性醚和/或缩醛来生产生物燃料的方法包括：至少一个酯交换步骤，其中所述甘油三酯通过非均相催化与至少一种 选自甲醇和乙醇的一级一元醇，以产生起始甘油三酯和甘油的脂肪酸的至少一种甲基和/或乙酯，所述产物不含副产物; 和其中甘油与至少一种含有4至12个碳原子的烯烃反应的醚化步骤; 和/或缩醛化步骤，其中甘油与至少一种选自醛，酮和衍生自醛或酮的缩醛的化合物反应。

公开(公告)号：US06476081B1

公开(公告)日：2002-11-05

申请号：US09573559

申请日：2000-05-19

Applicant: Gérard Hillion ,  Isabelle Durand ,  Anne Sinquin ,  Marie Velly

Inventor： Gérard Hillion ,  Isabelle Durand ,  Anne Sinquin ,  Marie Velly

IPC: B01F1722

CPC classification number: B01F17/005 ,  Y10S516/915

Abstract: In order to manufacture a composition mainly containing compounds with ester and amide functions, in particular in the form of ester-amides, as well as compounds with amine functions, such as ester-amines, the salts of amines, monoglycerides and diglycerides, formed from monomeric, dimeric, trimeric and/or tetrameric fatty acids contained in a polymerized polyunsaturated oil, a process is implemented which comprises the following stages: a) use (or preparation) of a polymerized oil by polymerization of a polyunsaturated vegetable or animal oil; b) treatment of said polymerized oil by entrainment with water vapor; and c) reaction of the polymerized oil thus treated with an excess of at least one aminoalcohol, in the presence or not of a catalyst. This composition can be used as an emulsifying and dispersing surfactant, in particular as an additive for dispersing hydrates in oil effluents.

Abstract translation: 为了制备主要含有具有酯和酰胺官能团的化合物的组合物，特别是酯 - 酰胺形式的化合物，以及具有胺官能团的化合物，例如酯 - 胺，胺，单甘油酯和甘油二酯的盐，由 包含在聚合多不饱和油中的单体，二聚，三聚和/或四聚脂肪酸，实施包括以下步骤的方法：a）通过多不饱和植物油或动物油的聚合使用（或制备）聚合油; b ）通过夹带水蒸气处理所述聚合油; 在这种催化剂的存在或不存在下，这样处理的聚合油与过量的至少一种氨基醇的反应。该组合物可用作乳化和分散表面活性剂，特别是作为用于将水合物分散在油污水中的添加剂 。

公开(公告)号：US06221920B1

公开(公告)日：2001-04-24

申请号：US09160290

申请日：1998-09-25

Applicant: Gérard Hillion ,  Isabelle Durand ,  Robert Stern ,  Marie Velly

Inventor： Gérard Hillion ,  Isabelle Durand ,  Robert Stern ,  Marie Velly

IPC: B01F304

CPC classification number: C07C233/20 ,  B01F17/0042 ,  Y10S516/915

Abstract: The following are described herein: a composition that consists of a mixture that comprises at least amides, amines, ester-amides, ester-amines, amine salts and monoglycerides, that are all derived from monomeric, dimeric, trimeric and/or tetrameric fatty acids; a process for the production of said composition which comprises the transamidification reaction of a polyunsaturated vegetable oil that is polymerized thermally, with an excess of at least one amino alcohol, which may or may not be in the presence of a catalyst; and the uses of this composition particularly as an emulsifying agent that allow it, depending on the nature of the oil, to form an oil-in-water or water-in-oil emulsion, as a solid-dispersing agent, or as an agent for the stabilization of foams in a liquid or an emulsion.

Abstract translation: 本文描述了以下：由至少包含酰胺，胺，酯 - 酰胺，酯 - 胺，胺盐和单甘油酯的混合物组成的组合物，其全部衍生自单体，二聚，三聚和/或四聚脂肪酸 ; 一种用于生产所述组合物的方法，其包括热聚合的多不饱和植物油与过量的至少一种氨基醇的酰胺化反应，其可以或不在催化剂存在下; 以及该组合物的特别用作乳化剂的用途，根据油的性质，其可以形成水包油或油包水乳液，作为固体分散剂或作为试剂 用于稳定液体或乳液中的泡沫。

公开(公告)号：US08419810B2

公开(公告)日：2013-04-16

申请号：US10590351

申请日：2005-01-27

Applicant: Gerard Hillion ,  Bruno Delfort ,  Isabelle Durand

Inventor： Gerard Hillion ,  Bruno Delfort ,  Isabelle Durand

IPC: C10L1/19

CPC classification number: C10L1/1855 ,  C07C67/03 ,  C10G2300/1011 ,  C10L1/026 ,  C10L1/1852 ,  C10L1/19 ,  C11C3/003 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/52

Abstract: A process for producing biofuels by transforming triglycerides into at least two families of biofuels, monoesters of fatty acids and soluble ethers and/or acetals of glycerol, comprises: at least one transesterification step in which said triglyceride is reacted by heterogeneous catalysis with at least one primary monoalcohol selected from methanol and ethanol to produce at least one methyl and/or ethyl ester of the fatty acids of the starting triglycerides and glycerol, said products being free of by-products; and an etherification step in which the glycerol is reacted with at least one olefinic hydrocarbon containing 4 to 12 carbon atoms; and/or an acetalization step in which the glycerol is reacted with at least one compound selected from aldehydes, ketones and acetals derived from aldehydes or ketones.

Abstract translation: 通过将甘油三酯转化为至少两个生物燃料，脂肪酸的单酯和甘油的可溶性醚和/或缩醛来生产生物燃料的方法包括：至少一个酯交换步骤，其中所述甘油三酯通过非均相催化与至少一种 选自甲醇和乙醇的一级一元醇，以产生起始甘油三酯和甘油的脂肪酸的至少一种甲基和/或乙酯，所述产物不含副产物; 和其中甘油与至少一种含有4至12个碳原子的烯烃反应的醚化步骤; 和/或缩醛化步骤，其中甘油与至少一种选自醛，酮和衍生自醛或酮的缩醛的化合物反应。

公开(公告)号：US07097674B2

公开(公告)日：2006-08-29

申请号：US10322473

申请日：2002-12-19

Applicant: Bruno Delfort ,  Isabelle Durand ,  Anne Jaecker ,  Thierry Lacome ,  Xavier Montagne ,  Fabrice Paille

Inventor： Bruno Delfort ,  Isabelle Durand ,  Anne Jaecker ,  Thierry Lacome ,  Xavier Montagne ,  Fabrice Paille

IPC: C10L1/18 ,  C10L1/24

CPC classification number: C10L1/19 ,  C10L1/026 ,  C10L10/02

Abstract: A diese fuel composition containing a major proportion of at least one diesel fuel and a minor proportion of at least one glycerol acetal carbonate of the formulae: in which: R1 and R2 each represent a hydrogen atom, a hydrocarbon radical with 1 to 20 carbon atoms that is aliphatic, cycloaliphatic or aromatic, an alkyl-ether chain, whereby R1 and R2 together can form an oxygenated heterocyclic radical; R3 is a radical that is defined as R1 or R2, except for the hydrogen atom, or a radical of the formula: where R1 and R2 are defined as above.

Abstract translation: 含有主要比例的至少一种柴油燃料和少部分至少一种下式的甘油缩醛碳酸酯的一种柴油燃料组合物：其中：R 1和R 2各自表示氢原子，具有1至20个碳原子的烃基 即脂肪族，脂环族或芳族的烷基醚链，其中R1和R2一起可以形成含氧杂环基; R3是除了氢原子以外定义为R 1或R 2的基团，或下式的基团：其中R 1和R 2如上定义。

公开(公告)号：US06492430B1

公开(公告)日：2002-12-10

申请号：US09573558

申请日：2000-05-19

Applicant: Gérard Hillion ,  Isabelle Durand ,  Anne Sinquin ,  Marie Velly

Inventor： Gérard Hillion ,  Isabelle Durand ,  Anne Sinquin ,  Marie Velly

IPC: B01F304

CPC classification number: B01F17/005 ,  Y10S516/914 ,  Y10S516/915

Abstract: A process for preparing a composition comprising a mixture with ester and amine function in the form of ester-amines, amines, salts of amines, monoglycerides and diglycerides all derived from monomeric, dimeric, trimeric, and/or tetrameric fatty acids contained in polymerized polyunsaturated oil comprising: (a) polymerizing a polyunsaturated vegetable or animal oil to form a polymerized oil, (b) treating the polymerized oil with water vapor, and (c) reacting the polymerized oil with an excess of at least one compound containing at least one hydroxyl function and at least one tertiary amine function, optionally in the presence of a catalyst. Said methods further comprise adding the compositions to an oil effluent as dispersing agents for hydrates.

Abstract translation: 制备包含酯和胺的混合物的组合物的方法以酯 - 胺，胺，胺，单酸甘油酯和甘油二酸酯的形式起作用，其全部衍生自聚合多不饱和物中所含的单体，二聚，三聚和/或四聚脂肪酸 油包括：（a）聚合多不饱和植物油或动物油以形成聚合油，（b）用水蒸汽处理聚合的油，和（c）使聚合的油与过量的至少一种含至少一种 羟基官能团和至少一种叔胺官能团，任选地在催化剂存在下。 所述方法还包括将组合物加入油流出物中作为水合物的分散剂。