Abstract:
This invention provides processes for maintaining a desired particle size distribution in an oxygenate to olefin reaction system. In one embodiment, the invention comprises replacing lost catalyst fines with less active co-catalyst particles. By adding less active co-catalyst particles to the reaction system, desirable fluidization characteristics and hydrodynamics can be maintained without affecting the overall (or primary catalyst) performance and product selectivities. The invention is also directed to a population of catalyst particles having a desirable particle size distribution well-suited for realizing ideal fluidization and hydrodynamic characteristics.
Abstract:
This invention relates to a quenching device for temperature control in catalytic processes. More particularly, the quenching device includes gas and liquid spargers for interbed temperature control in an interbed mixing zone in a catalytic reactor. The quenching device includes a first injector for injecting a first quenching fluid into an outer mixing zone and a second injector for injecting a second quenching fluid into an inner mixing zone. The quenching fluids include both gaseous and liquid quenching fluids.
Abstract:
This invention is a method for reducing the total acid number of organic acid containing petroleum oil comprising forming a water-in-oil emulsion comprising an aqueous Group IIA metal hydroxide solution or slurry in a hydrocarbon oil, said water-in-oil emulsion having an aqueous droplet particle size diameter of from 1 to 25μ, adding the water-in-oil emulsion to the organic acid containing petroleum oil and permitting the mixture to stand for a time sufficient to permit the neutralization of the organic acids in the petroleum oil.
Abstract:
An improved de-entrainment device for use in distillation towers, especially vacuum distillation towers used for fractionating petroleum atmospheric resids comprises a baffle which is to be located in the portion of the tower below the feed zone and at the top of the flash zone. The baffle is in the form of an apertured plate above the stripping zone and in its preferred form comprises number of radial fins or blades, resembling a static fan with openings between the fins to permit vapors from the lower portions of the tower to pass upwards through the baffle with a minimal pressure drop. The fins of the baffle are preferably oriented at an angle between 30° and 60° away from the incoming feed so that the incoming feed stream skims over the top edges of the fins.
Abstract:
A gas-solids reaction system with termination devices to connect a riser with one or more separation devices. The termination devices have a radius of curvature that is at least 1.0 times as great as the diameter of the conduit forming the termination device. The termination devices can be openly or closely coupled to the separation devices.