Abstract:
A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.
Abstract:
An apparatus and process for vaporizing and, optionally, igniting a liquid fuel, preferably, a distillate fuel. The apparatus includes the following components: a heat-conductive reticulated screen positioned within a chamber; a first inlet path into the chamber for delivering a liquid fuel onto the screen; a second inlet path into the chamber for contacting an oxidant with the screen and fuel; a means for heating the screen to a temperature sufficient to vaporize and, optionally, ignite the liquid fuel; and a recuperator in fluid communication with the chamber for transferring heat from the chamber to the second inlet path. The apparatus is suitably employed in compact and portable oxidation reactors, for example, in external combustion engines, catalytic partial oxidation reformers, and hybrid combustors operating in flame and/or catalytic modes.
Abstract:
A method and a system for the vaporization of a liquid fuel is provided and includes providing a supply of a liquid fuel and an oxidant, atomizing the liquid fuel and mixing it with the oxidant, vaporizing the fuel in thermal radiation, catalytically reacting the fuel oxidant mixture, and providing an ignition source for initiating the catalytic reaction. A hydrocarbon fuel can be mixed with oxygen, as a constituent of air, preferably forming a fuel rich fuel air mixture that passes through a catalytic reactor having an ultra-short channel length metal monolith substrate. The fuel air mixture is vaporized and partially oxidized.
Abstract:
The present invention provides a combustor for an aerospace gas turbine engine comprising two stages wherein each stage defines an inlet and an exit. The second stage inlet is in fluid communication with the first stage exit such that a first flowpath is defined and it passes substantially through the second stage. A plurality of flow channel tubes is positioned within the second stage and each flow channel tube passes sealingly through a header plate positioned upstream of the second stage inlet thereby defining a second flowpath that also passes substantially through the second stage. The first flowpath exit and the second flowpath exit are positioned adjacent and proximate to one another to provide for the generation of microflames or microflame jets exiting the second stage from between and around the flow channel tube exits. The first stage of the combustor provides a gasifier and a reformer. The present invention also may comprise an igniter for further combustion of the reacted products or an external heat source for start-up. The second stage also may comprise a microflame combustor.
Abstract:
The present invention provides a process and apparatus for the gasification of a liquid fuel and includes providing a supply of a liquid fuel, a supply of oxidant, and a supply of liquid water; atomizing the liquid fuel and mixing it with the oxidant and steam; catalytically reacting the fuel-oxidant-steam mixture in a catalyst bed; initiating the catalytic reaction with an ignition source; positioning a heat exchanger in proximity with the catalyst bed so as to convert the liquid water to steam; and feeding the steam into the catalytic reaction, thereby eliminating the need for a liquid fuel vaporizer. A preferred catalyst bed includes an ultra-short-channel-length metal substrate.
Abstract:
A method is provided for controlling the operating temperature of a catalytic reactor using a closed-loop system that provides for varying the reactor input and other operating parameters in order to maintain the operating temperature of the reactor at or near the initial setpoint temperature for operation of the reactor. In one example, maximum and minimum operating temperatures with a catalytic partial oxidation reactor are controlled, as well as maintaining control over the corresponding minimum required ratio of oxygen atoms to carbon atoms, such that the operating temperature within the reactor is maintained below the material limits but above threshold temperatures for coking.
Abstract:
The invention disclosed is a method for improving the selectivity of a desired chemical reaction over an undesired chemical reaction utilizing a reactor having at least one channel having a catalyst positioned thereon and a presenting a reactant flow stream at a known flow rate and inlet temperature over the catalyst at a velocity such that a boundary layer formed thereby relative to said catalytic surface defines a thickness that is sufficiently less than the thickness of a fully developed boundary layer over said catalytic surface whereby the desired chemical reaction occurs preferentially over the undesired chemical reaction.
Abstract:
The invention provides a method for transferring heat by conduction to the internal heat acceptor of an external combustion engine. Fuel and air are introduced and mixed to form an air/fuel mixture. The air/fuel mixture is directed into a catalytic reactor that is positioned substantially adjacent to the heater head. Heat is transferred via conduction from the catalytic reactor to the heater head and the catalytic reaction products are exhausted.
Abstract:
An apparatus and process for vaporizing and, optionally, igniting a liquid fuel, preferably, a distillate fuel. The apparatus includes the following components: a heat-conductive reticulated screen positioned within a chamber; a first inlet path into the chamber for delivering a liquid fuel onto the screen; a second inlet path into the chamber for contacting an oxidant with the screen and fuel; a means for heating the screen to a temperature sufficient to vaporize and, optionally, ignite the liquid fuel; and a recuperator in fluid communication with the chamber for transferring heat from the chamber to the second inlet path. The apparatus is suitably employed in compact and portable oxidation reactors, for example, in external combustion engines, catalytic partial oxidation reformers, and hybrid combustors operating in flame and/or catalytic modes.
Abstract:
A method is provided for controlling the operating temperature of a catalytic reactor using a closed-loop system that provides for varying the reactor input and other operating parameters in order to maintain the operating temperature of the reactor at or near the initial setpoint temperature for operation of the reactor. In one example, maximum and minimum operating temperatures with a catalytic partial oxidation reactor are controlled, as well as maintaining control over the corresponding minimum required ratio of oxygen atoms to carbon atoms, such that the operating temperature within the reactor is maintained below the material limits but above threshold temperatures for coking.