Electrolyser for production of catholyte

    公开(公告)号:US20230015817A1

    公开(公告)日:2023-01-19

    申请号:US17851730

    申请日:2022-06-28

    Abstract: Electrolyzer for catholyte production comprises an inner hollow cylindrical anode, an outer cylindrical cathode, and a diaphragm interposed between them. The length of the working part of the anode is at most 2 to 6 times the outer diameter of the anode. The inner hollow anode is made of one or two sections, the sections being connected to each other by a flow dielectric cylindrical sleeve having a diameter not larger than the outer diameter of the anode. The inner hollow anode has openings for introduction of water into inner cavity of the anode and openings for discharge of water at opposite ends of diameters of the anode lid. The electrolyzer for catholyte production operates in a horizontal position because outlet openings of the anode lid are located at the ends of the diameter of the anode lid, close to the outlet openings of the electrolyzer lid facing vertically upwards.

    Method and electrolyser for disinfectant production
    2.
    发明授权
    Method and electrolyser for disinfectant production 有权
    消毒剂生产方法和电解槽

    公开(公告)号:US08568574B2

    公开(公告)日:2013-10-29

    申请号:US13008742

    申请日:2011-01-18

    Abstract: A method for obtaining a disinfectant from an aqueous solution of sodium chloride by using a diaphragm electrolyser is disclosed. The method comprise channeling a fresh water flow inside a tubular cathode, separating 0.4-0.8% of the quantity of the fresh water flow and channeling the separated fresh water flow into the cathode chamber. Next, 16-20% of sodium chloride at the concentration of 0.02-1.2% is channeled to the anode chamber after a sodium chloride mixer. Fresh water flow is channeled from inside the cathode to a branch of an anode chamber in a cover-mixer of an electrolyser. The flow, originating from the cathode chamber, is discharged for utilization, wherein an anolyte flow from the anode chamber is channeled to the branch of the anode chamber. The concentration of active chlorine in the anolyte is reduced by employing a water supply to a predetermined level required of a disinfectant and the disinfectant with a pH level of 5.5-7.5 is discharged from the electrolyser. Hydrogen is channeled to an exhaust outlet from the cathode chamber. An electrolyser for use with the method is also disclosed.

    Abstract translation: 公开了一种通过使用隔膜电解槽从氯化钠水溶液中获得消毒剂的方法。 该方法包括在管状阴极内引导淡水流,分离出新鲜水流量的0.4-0.8%并将分离的淡水流引导到阴极室中。 接下来,在氯化钠混合器之后将浓度为0.02-1.2%的氯化钠16-20%引入阳极室。 在电解槽的覆盖混合器中,淡水流从阴极内部引导至阳极室的分支。 来自阴极室的流动被排出以利用,其中来自阳极室的阳极电解液流向阳极室的分支。 通过使用向消毒剂所需的预定水平的水供应,降低阳极电解液中活性氯的浓度,并且从电解槽排出pH为5.5-7.5的消毒剂。 氢气被引导到阴极室的排气出口。 还公开了一种用于该方法的电解器。

    METHOD AND ELECTROLYSER FOR DISINFECTANT PRODUCTION
    3.
    发明申请
    METHOD AND ELECTROLYSER FOR DISINFECTANT PRODUCTION 有权
    消毒剂生产方法和电解质

    公开(公告)号:US20120061254A1

    公开(公告)日:2012-03-15

    申请号:US13008742

    申请日:2011-01-18

    Abstract: A method for obtaining a disinfectant from an aqueous solution of sodium chloride by using a diaphragm electrolyser is disclosed. The method comprise channeling a fresh water flow inside a tubular cathode, separating 0.4-0.8% of the quantity of the fresh water flow and channeling the separated fresh water flow into the cathode chamber. Next, 16-20% of sodium chloride at the concentration of 0.02-1.2% is channeled to the anode chamber after a sodium chloride mixer. Fresh water flow is channeled from inside the cathode to a branch of an anode chamber in a cover-mixer of an electrolyser. The flow, originating from the cathode chamber, is discharged for utilization, wherein an anolyte flow from the anode chamber is channeled to the branch of the anode chamber. The concentration of active chlorine in the anolyte is reduced by employing a water supply to a predetermined level required of a disinfectant and the disinfectant with a pH level of 5.5-7.5 is discharged from the electrolyser. Hydrogen is channeled to an exhaust outlet from the cathode chamber. An electrolyser for use with the method is also disclosed.

    Abstract translation: 公开了一种通过使用隔膜电解槽从氯化钠水溶液中获得消毒剂的方法。 该方法包括在管状阴极内引导淡水流,分离出新鲜水流量的0.4-0.8%并将分离的淡水流引导到阴极室中。 接下来,在氯化钠混合器之后将浓度为0.02-1.2%的氯化钠16-20%引入阳极室。 在电解槽的覆盖混合器中,淡水流从阴极内部引导至阳极室的分支。 来自阴极室的流动被排出以利用,其中来自阳极室的阳极电解液流向阳极室的分支。 通过使用向消毒剂所需的预定水平的水供应,降低阳极电解液中活性氯的浓度,并且从电解槽排出pH为5.5-7.5的消毒剂。 氢气被引导到阴极室的排气出口。 还公开了一种用于该方法的电解器。

    TWO-CHAMBER COAXIAL ELECTROLYSER DEVICE
    4.
    发明申请
    TWO-CHAMBER COAXIAL ELECTROLYSER DEVICE 有权
    双室同轴电动装置

    公开(公告)号:US20080264781A1

    公开(公告)日:2008-10-30

    申请号:US12111733

    申请日:2008-04-29

    Abstract: The disclosure relates to an electrochemical treatment of liquids and production of gases. Increased operating efficiency of an electrochemical device is achieved through the combination of measures: (1) sealing of the device on an element-by-element basis; (2) transfer of the liquid and gaseous phase interface into a passive extension of an anode chamber; (3) utilization of a tubular cathode as an inner wall and a cylindrical anode with an external coating as an outer wall; (4) positioning of channels and determining their dimensions so as to maintain helicity of electrolyte movement combined with the increase of the production output; (5) positioning and design of terminals, which provide for the reduction of their heating; and (6) ability of the device to operate under the conditions, when its longitudinal axis deviates from the vertical line by an angle of γ≦85° and under pumping conditions.

    Abstract translation: 本公开涉及液体的电化学处理和气体的产生。 电化学装置的提高的操作效率通过以下措施来实现:(1)基于元件密封装置; (2)将液相和气相界面转移到阳极室的被动延伸部分; (3)使用管状阴极作为内壁和具有外部涂层作为外壁的圆柱形阳极; (4)定位通道并确定其尺寸,以保持电解液运动的螺旋性,加上生产量的增加; (5)端子的定位和设计,可减少其加热; 和(6)当其纵向轴线偏离垂直线一个伽马<85°的角度并且在泵送条件下时,该装置在这种条件下操作的能力。

    Method and electrolyser for disinfectant production
    6.
    发明授权
    Method and electrolyser for disinfectant production 有权
    消毒剂生产方法和电解槽

    公开(公告)号:US09340883B2

    公开(公告)日:2016-05-17

    申请号:US14036987

    申请日:2013-09-25

    Abstract: Exemplary electrolytic methods are disclosed relating to preparation of useful products, e.g., disinfectants, from aqueous solutions of electrolytes. Disinfectant production with a capacity of a single electrolyzer may amount to 1200 liters per hour and up to 600 grams of active chlorine per hour by utilizing 3-7 gram sodium chloride (NaCl) for the production of 1 gram of active chlorine on the basis of a reliable and safe hydraulic structure. A fresh water supply may initially be directed into an internal tubular cathode chamber for cathode cooling purposes, before the participation in final disinfectant production process. A coolable cathode may increase the hold-up time of the electrolyte in the electrode chamber without application of circulation circuits, improving significantly the efficiency of sodium chloride utilization. The simplicity of the method makes it possible to increase both the productivity of a single electrolyzer and the efficiency of the process.

    Abstract translation: 公开了关于从电解质的水溶液制备有用产物,例如消毒剂的示例性电解方法。 具有单个电解槽容量的消毒剂生产量可以达到每小时1200升,每小时最多600克活性氯,通过使用3-7克氯化钠(NaCl)生产1克活性氯,基于 可靠安全的液压结构。 在参与最终消毒剂生产过程之前,最初可以将淡水供应引入用于阴极冷却目的的内部管状阴极室。 可冷却的阴极可以增加电极室中电解质的滞留时间,而不需要循环回路,从而显着提高氯化钠的利用效率。 该方法的简单性使得可以提高单个电解器的生产率和工艺的效率。

    METHOD AND ELECTROLYSER FOR DISINFECTANT PRODUCTION
    7.
    发明申请
    METHOD AND ELECTROLYSER FOR DISINFECTANT PRODUCTION 审中-公开
    消毒剂生产方法和电解质

    公开(公告)号:US20140021061A1

    公开(公告)日:2014-01-23

    申请号:US14036987

    申请日:2013-09-25

    Abstract: The present invention relates to the chemical engineering for getting useful products from aqueous solution of electrolytes with various concentration by electrolytic method and it can be used for the production of disinfectants widely utilized in medicine, biology, and ecology.This invention solves a task of disinfectant production with the capacity of a single electrolyser amounting to 1200 litres per hour and up to 600 grams of active chlorine per hour by utilizing 3-7 gram sodium chloride (NaCl) for the production of 1 gram of active chlorine on the basis of a reliable and safe hydraulic structure. The main condition for the effective solving of the task is the initial directing of fresh water supply into the internal tubular cathode chamber for the cathode cooling purposes, before the participation in final disinfectant production process. A coolable cathode enables to increase the hold-up time of the electrolyte in the electrode chamber without application of circulation circuits improving significantly the efficiency of sodium chloride utilization. The simplicity of the method makes it possible to increase both the productivity of a single electrolyser and the efficiency of the process.

    Abstract translation: 本发明涉及通过电解方法从各种浓度的电解质水溶液中获得有用产品的化学工程,并且可用于生产广泛应用于医药,生物和生态学的消毒剂。 本发明通过使用3-7克氯化钠(NaCl)生产1克活性物质,解决了每小时1200升和每小时600克活性氯的单个电解槽的能力的消毒剂生产任务。 基于可靠和安全的液压结构的氯。 有效解决任务的主要条件是在参与最终消毒剂生产过程之前,首先将淡水供应引导到阴极冷却目的的内部管状阴极室中。 可冷却的阴极能够增加电极室中的电解质的滞留时间,而不需要循环回路显着提高氯化钠的利用效率。 该方法的简单性使得可以提高单个电解槽的生产率和工艺的效率。

    Cylindrical membranous electrolytic cell and assembled anode and diaphragm
    8.
    发明授权
    Cylindrical membranous electrolytic cell and assembled anode and diaphragm 有权
    圆柱形膜电解池和组装阳极和隔膜

    公开(公告)号:US08298383B2

    公开(公告)日:2012-10-30

    申请号:US12428962

    申请日:2009-04-23

    Abstract: The disclosure is directed to the area of electrochemical processing of liquids and production of gases, and is used for anolyte and catholyte synthesis. The electrolytic cell comprises an assembled anode and a diaphragm. Elements of the anode and the diaphragm are assembled in axial alignment with help of sleeves, and free ends of the anode and the diaphragm are fixed in a coaxial manner with solid of electrolyte input and output covers. The cathode is made solid from a single pipe with current terminals on each side. The cathode is the internal electrode of the electrolytic cell, while the anode is the external one. The anode is may be provided with a visual indicator as a positive electrode.

    Abstract translation: 本发明涉及液体的电化学处理领域和气体的生产,并用于阳极电解液和阴极电解液的合成。 电解池包括组装的阳极和隔膜。 阳极和隔膜的元件在套筒的帮助下轴向对准组装,阳极和隔膜的自由端与电解质输入和输出盖的固体同轴地固定。 阴极从每侧具有电流端子的单个管制成固体。 阴极是电解池的内部电极,而阳极是外部电极。 阳极可以设置有作为正极的视觉指示器。

    Electrolyser for production of catholyte

    公开(公告)号:US11807949B2

    公开(公告)日:2023-11-07

    申请号:US17851730

    申请日:2022-06-28

    CPC classification number: C25B9/015 C25B9/19

    Abstract: Electrolyzer for catholyte production comprises an inner hollow cylindrical anode, an outer cylindrical cathode, and a diaphragm interposed between them. The length of the working part of the anode is at most 2 to 6 times the outer diameter of the anode. The inner hollow anode is made of one or two sections, the sections being connected to each other by a flow dielectric cylindrical sleeve having a diameter not larger than the outer diameter of the anode. The inner hollow anode has openings for introduction of water into inner cavity of the anode and openings for discharge of water at opposite ends of diameters of the anode lid. The electrolyzer for catholyte production operates in a horizontal position because outlet openings of the anode lid are located at the ends of the diameter of the anode lid, close to the outlet openings of the electrolyzer lid facing vertically upwards.

    Energy-efficient diaphragm-electrolyser
    10.
    发明申请
    Energy-efficient diaphragm-electrolyser 审中-公开
    节能隔膜电解槽

    公开(公告)号:US20160251764A1

    公开(公告)日:2016-09-01

    申请号:US15055787

    申请日:2016-02-29

    Abstract: The invention relates to the field of electrochemical production of disinfectants, where a solution of alkaline metals is used as the electrolyte in the anode chamber. The invention offers a new design for electrolysers, reducing power consumption in the production of disinfectants by known methods. As a result of this invention, power consumed in the production of 1 gram of active chlorine by known methods will be reduced by 20%, and the possibilities for producing disinfectants with active chlorine content 7500 ppm in an electrolyser without channelling the water into external cooling devices will also expand.

    Abstract translation: 本发明涉及消毒剂的电化学生产领域,其中碱金属溶液用作阳极室中的电解质。 本发明为电解槽提供了新的设计,通过已知方法降低消毒剂生产中的功耗。 作为本发明的结果,通过已知方法生产1克活性氯消耗的功率将降低20%,并且在电解槽中生产活性氯含量为7500ppm的消毒剂的可能性不会导致水进入外部冷却 设备也将扩大。

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