公开(公告)号：US20170316971A1

公开(公告)日：2017-11-02

申请号：US15653329

申请日：2017-07-18

Applicant: ZIPTRONIX, INC.

Inventor： Paul M. Enquist ,  Gaius Gillman Fountain, JR. ,  Qin-Yi Tong

IPC: H01L21/768 ,  H01L23/00 ,  H01L25/065 ,  H01L25/00 ,  H01L27/06 ,  H01L23/48

CPC classification number: H01L21/76838 ,  H01L21/76898 ,  H01L23/481 ,  H01L24/02 ,  H01L24/81 ,  H01L24/94 ,  H01L24/97 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/0688 ,  H01L2224/0401 ,  H01L2224/81121 ,  H01L2224/81201 ,  H01L2224/8123 ,  H01L2224/81801 ,  H01L2224/81894 ,  H01L2224/81931 ,  H01L2224/83894 ,  H01L2224/9202 ,  H01L2224/97 ,  H01L2225/06513 ,  H01L2225/06541 ,  H01L2924/01002 ,  H01L2924/01004 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01018 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01022 ,  H01L2924/01023 ,  H01L2924/01027 ,  H01L2924/01028 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01042 ,  H01L2924/01046 ,  H01L2924/01049 ,  H01L2924/0105 ,  H01L2924/01055 ,  H01L2924/01059 ,  H01L2924/01073 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01077 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/01082 ,  H01L2924/014 ,  H01L2924/04941 ,  H01L2924/04953 ,  H01L2924/05042 ,  H01L2924/10329 ,  H01L2924/12044 ,  H01L2924/14 ,  H01L2924/19043 ,  H01L2924/3025 ,  H01L2224/81

Abstract: A method of three-dimensionally integrating elements such as singulated die or wafers and an integrated structure having connected elements such as singulated dies or wafers. Either or both of the die and wafer may have semiconductor devices formed therein. A first element having a first contact structure is bonded to a second element having a second contact structure. First and second contact structures can be exposed at bonding and electrically interconnected as a result of the bonding. A via may be etched and filled after bonding to expose and form an electrical interconnect to interconnected first and second contact structures and provide electrical access to this interconnect from a surface.

公开(公告)号：US09391143B2

公开(公告)日：2016-07-12

申请号：US14957501

申请日：2015-12-02

Applicant: ZIPTRONIX, INC.

Inventor： Qin-Yi Tong ,  Gaius Gillman Fountain, Jr. ,  Paul M. Enquist

IPC: H01L21/30 ,  H01L21/46 ,  H01L29/16 ,  H01L21/02 ,  H01L21/20 ,  H01L21/311 ,  H01L21/762 ,  H01L23/00 ,  H01L29/06 ,  H01L21/322 ,  H01L27/085

CPC classification number: H01L24/83 ,  H01L21/0206 ,  H01L21/2007 ,  H01L21/31105 ,  H01L21/31116 ,  H01L21/322 ,  H01L21/76251 ,  H01L24/26 ,  H01L24/75 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/085 ,  H01L29/06 ,  H01L29/16 ,  H01L2224/8301 ,  H01L2224/8303 ,  H01L2224/83031 ,  H01L2224/8309 ,  H01L2224/83099 ,  H01L2224/8319 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/83948 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01018 ,  H01L2924/0102 ,  H01L2924/01023 ,  H01L2924/01033 ,  H01L2924/01039 ,  H01L2924/0106 ,  H01L2924/01061 ,  H01L2924/01072 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01084 ,  H01L2924/01093 ,  H01L2924/0132 ,  H01L2924/05442 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/10329 ,  H01L2924/14 ,  Y10S148/012 ,  Y10S438/974 ,  Y10T156/10 ,  Y10T156/1043 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01049 ,  H01L2924/01031 ,  H01L2924/3512 ,  H01L2924/00

Abstract: A method for bonding at low or room temperature includes steps of surface cleaning and activation by cleaning or etching. The method may also include removing by-products of interface polymerization to prevent a reverse polymerization reaction to allow room temperature chemical bonding of materials such as silicon, silicon nitride and SiO2. The surfaces to be bonded are polished to a high degree of smoothness and planarity. VSE may use reactive ion etching or wet etching to slightly etch the surfaces being bonded. The surface roughness and planarity are not degraded and may be enhanced by the VSE process. The etched surfaces may be rinsed in solutions such as ammonium hydroxide or ammonium fluoride to promote the formation of desired bonding species on the surfaces.

公开(公告)号：US20150340285A1

公开(公告)日：2015-11-26

申请号：US14813972

申请日：2015-07-30

Applicant: ZIPTRONIX, INC.

Inventor： Paul M. ENQUIST ,  Gaius Gillman FOUNTAIN, JR. ,  Qin-Yi TONG

IPC: H01L21/768 ,  H01L27/06

CPC classification number: H01L21/76838 ,  H01L21/76898 ,  H01L23/481 ,  H01L24/02 ,  H01L24/81 ,  H01L24/94 ,  H01L24/97 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/0688 ,  H01L2224/0401 ,  H01L2224/81121 ,  H01L2224/81201 ,  H01L2224/8123 ,  H01L2224/81801 ,  H01L2224/81894 ,  H01L2224/81931 ,  H01L2224/83894 ,  H01L2224/9202 ,  H01L2224/97 ,  H01L2225/06513 ,  H01L2225/06541 ,  H01L2924/01002 ,  H01L2924/01004 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01018 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01022 ,  H01L2924/01023 ,  H01L2924/01027 ,  H01L2924/01028 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01042 ,  H01L2924/01046 ,  H01L2924/01049 ,  H01L2924/0105 ,  H01L2924/01055 ,  H01L2924/01059 ,  H01L2924/01073 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01077 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/01082 ,  H01L2924/014 ,  H01L2924/04941 ,  H01L2924/04953 ,  H01L2924/05042 ,  H01L2924/10329 ,  H01L2924/12044 ,  H01L2924/14 ,  H01L2924/19043 ,  H01L2924/3025 ,  H01L2224/81

Abstract: A method of three-dimensionally integrating elements such as singulated die or wafers and an integrated structure having connected elements such as singulated dies or wafers. Either or both of the die and wafer may have semiconductor devices formed therein. A first element having a first contact structure is bonded to a second element having a second contact structure. First and second contact structures can be exposed at bonding and electrically interconnected as a result of the bonding. A via may be etched and filled after bonding to expose and form an electrical interconnect to interconnected first and second contact structures and provide electrical access to this interconnect from a surface. Alternatively, first and/or second contact structures are not exposed at bonding, and a via is etched and filled after bonding to electrically interconnect first and second contact structures and provide electrical access to interconnected first and second contact structure to a surface. Also, a device may be formed in a first substrate, the device being disposed in a device region of the first substrate and having a first contact structure. A via may be etched, or etched and filled, through the device region and into the first substrate before bonding and the first substrate thinned to expose the via, or filled via after bonding.

公开(公告)号：US20130178062A1

公开(公告)日：2013-07-11

申请号：US13783553

申请日：2013-03-04

Applicant: Ziptronix, Inc.

Inventor： Paul M. Enquist ,  Gaius Gillman Fountain, JR. ,  Qin-Yi Tong

IPC: H01L21/768

CPC classification number: H01L21/76838 ,  H01L21/76898 ,  H01L23/481 ,  H01L24/02 ,  H01L24/81 ,  H01L24/94 ,  H01L24/97 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/0688 ,  H01L2224/0401 ,  H01L2224/81121 ,  H01L2224/81201 ,  H01L2224/8123 ,  H01L2224/81801 ,  H01L2224/81894 ,  H01L2224/81931 ,  H01L2224/83894 ,  H01L2224/9202 ,  H01L2224/97 ,  H01L2225/06513 ,  H01L2225/06541 ,  H01L2924/01002 ,  H01L2924/01004 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01018 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01022 ,  H01L2924/01023 ,  H01L2924/01027 ,  H01L2924/01028 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01042 ,  H01L2924/01046 ,  H01L2924/01049 ,  H01L2924/0105 ,  H01L2924/01055 ,  H01L2924/01059 ,  H01L2924/01073 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01077 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/01082 ,  H01L2924/014 ,  H01L2924/04941 ,  H01L2924/04953 ,  H01L2924/05042 ,  H01L2924/10329 ,  H01L2924/12044 ,  H01L2924/14 ,  H01L2924/19043 ,  H01L2924/3025 ,  H01L2224/81

Abstract: A method of three-dimensionally integrating elements such as singulated die or wafers and an integrated structure having connected elements such as singulated dies or wafers. Either or both of the die and wafer may have semiconductor devices formed therein. A first element having a first contact structure is bonded to a second element having a second contact structure. First and second contact structures can be exposed at bonding and electrically interconnected as a result of the bonding. A via may be etched and filled after bonding to expose and form an electrical interconnect to interconnected first and second contact structures and provide electrical access to this interconnect from a surface. Alternatively, first and/or second contact structures are not exposed at bonding, and a via is etched and filled after bonding to electrically interconnect first and second contact structures and provide electrical access to interconnected first and second contact structure to a surface. Also, a device may be formed in a first substrate, the device being disposed in a device region of the first substrate and having a first contact structure. A via may be etched, or etched and filled, through the device region and into the first substrate before bonding and the first substrate thinned to expose the via, or filled via after bonding.

公开(公告)号：US20170170132A1

公开(公告)日：2017-06-15

申请号：US15385545

申请日：2016-12-20

Applicant: ZIPTRONIX, INC.

Inventor： Paul M. Enquist ,  Gaius Gillman Fountain, JR.

IPC: H01L23/00 ,  H01L25/00 ,  H01L25/065

CPC classification number: H01L24/08 ,  H01L21/187 ,  H01L21/2007 ,  H01L21/6835 ,  H01L21/76251 ,  H01L21/76898 ,  H01L21/8221 ,  H01L23/13 ,  H01L23/36 ,  H01L23/481 ,  H01L23/5384 ,  H01L23/5385 ,  H01L23/5389 ,  H01L23/552 ,  H01L24/24 ,  H01L24/26 ,  H01L24/27 ,  H01L24/30 ,  H01L24/48 ,  H01L24/80 ,  H01L24/82 ,  H01L24/83 ,  H01L24/94 ,  H01L25/0652 ,  H01L25/0655 ,  H01L25/0657 ,  H01L25/16 ,  H01L25/167 ,  H01L25/18 ,  H01L25/50 ,  H01L27/0688 ,  H01L27/14634 ,  H01L2221/6835 ,  H01L2221/68359 ,  H01L2221/68363 ,  H01L2223/6677 ,  H01L2224/0807 ,  H01L2224/08123 ,  H01L2224/1134 ,  H01L2224/16 ,  H01L2224/24011 ,  H01L2224/24225 ,  H01L2224/24226 ,  H01L2224/24227 ,  H01L2224/3005 ,  H01L2224/30104 ,  H01L2224/305 ,  H01L2224/48091 ,  H01L2224/48101 ,  H01L2224/48227 ,  H01L2224/48247 ,  H01L2224/80896 ,  H01L2224/81894 ,  H01L2224/8303 ,  H01L2224/83092 ,  H01L2224/83099 ,  H01L2224/8319 ,  H01L2224/83193 ,  H01L2224/83345 ,  H01L2224/83359 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/83912 ,  H01L2224/83948 ,  H01L2224/9202 ,  H01L2224/9212 ,  H01L2225/06513 ,  H01L2225/06524 ,  H01L2225/06541 ,  H01L2225/06555 ,  H01L2225/06589 ,  H01L2924/00013 ,  H01L2924/00014 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01015 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01047 ,  H01L2924/01057 ,  H01L2924/01074 ,  H01L2924/01082 ,  H01L2924/0132 ,  H01L2924/014 ,  H01L2924/05442 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/10329 ,  H01L2924/1305 ,  H01L2924/13062 ,  H01L2924/13063 ,  H01L2924/13064 ,  H01L2924/13091 ,  H01L2924/14 ,  H01L2924/1461 ,  H01L2924/15153 ,  H01L2924/15165 ,  H01L2924/19041 ,  H01L2924/19043 ,  H01L2924/30105 ,  H01L2924/30107 ,  H01L2924/3011 ,  H01L2924/3025 ,  H01L2924/351 ,  Y10S148/012 ,  Y10S438/977 ,  H01L2224/13099 ,  H01L2924/01049 ,  H01L2924/01031 ,  H01L2924/00 ,  H01L2224/45099 ,  H01L2224/45015 ,  H01L2924/207 ,  H01L2224/8203 ,  H01L2224/821 ,  H01L2224/80001 ,  H01L2224/82

Abstract: A method may include the steps of directly bonding a semiconductor device having a substrate to an element; and removing a portion of the substrate to expose a remaining portion of the semiconductor device after bonding. The element may include one of a substrate used for thermal spreading, impedance matching or for RF isolation, an antenna, and a matching network comprised of passive elements. A second thermal spreading substrate may be bonded to the remaining portion of the semiconductor device. Interconnections may be made through the first or second substrates. The method may also include bonding a plurality of semiconductor devices to an element, and the element may have recesses in which the semiconductor devices are disposed.

公开(公告)号：US20170062366A1

公开(公告)日：2017-03-02

申请号：US14835379

申请日：2015-08-25

Applicant: ZIPTRONIX, INC.

Inventor： Paul M. ENQUIST

IPC: H01L23/00 ,  H01L25/065 ,  H01L25/00

CPC classification number: H01L24/09 ,  H01L21/50 ,  H01L24/03 ,  H01L24/80 ,  H01L24/89 ,  H01L25/0657 ,  H01L25/50 ,  H01L2224/036 ,  H01L2224/05005 ,  H01L2224/05078 ,  H01L2224/05082 ,  H01L2224/08145 ,  H01L2224/8019 ,  H01L2224/80895 ,  H01L2225/06513

Abstract: A method for forming a direct hybrid bond and a device resulting from a direct hybrid bond including a first substrate having a first set of metallic bonding pads, preferably connected to a device or circuit, capped by a conductive barrier, and having a first non-metallic region adjacent to the metallic bonding pads on the first substrate, a second substrate having a second set of metallic bonding pads capped by a second conductive barrier, aligned with the first set of metallic bonding pads, preferably connected to a device or circuit, and having a second non-metallic region adjacent to the metallic bonding pads on the second substrate, and a contact-bonded interface between the first and second set of metallic bonding pads capped by conductive barriers formed by contact bonding of the first non-metallic region to the second non-metallic region.

Abstract translation: 一种用于形成直接杂化键的方法和由直接杂化键形成的器件，其包括具有第一组金属接合焊盘的第一衬底，该第一衬底优选地连接到被导电屏障覆盖的器件或电路上， 金属区域，与第一基板上的金属接合焊盘相邻，第二基板具有由第二导电屏障覆盖的第二组金属接合焊盘，第二组导电屏障与第一组金属焊盘对准，优选地连接到设备或电路，以及 具有与所述第二基板上的所述金属接合焊盘相邻的第二非金属区域，以及所述第一和第二组金属接合焊盘之间的接触接合界面，所述第一和第二组金属接合焊盘由所述第一非金属区域与所述第一非金属区域的接合形成的导电屏障 第二个非金属区域。

公开(公告)号：US20160190093A1

公开(公告)日：2016-06-30

申请号：US15064467

申请日：2016-03-08

Applicant: ZIPTRONIX, INC.

Inventor： Paul M. Enquist ,  Gaius Gillman Fountain, JR.

IPC: H01L23/00 ,  H01L25/065 ,  H01L25/00 ,  H01L23/538

CPC classification number: H01L24/08 ,  H01L21/187 ,  H01L21/2007 ,  H01L21/6835 ,  H01L21/76251 ,  H01L21/76898 ,  H01L21/8221 ,  H01L23/13 ,  H01L23/36 ,  H01L23/481 ,  H01L23/5384 ,  H01L23/5385 ,  H01L23/5389 ,  H01L23/552 ,  H01L24/24 ,  H01L24/26 ,  H01L24/27 ,  H01L24/30 ,  H01L24/48 ,  H01L24/80 ,  H01L24/82 ,  H01L24/83 ,  H01L24/94 ,  H01L25/0652 ,  H01L25/0655 ,  H01L25/0657 ,  H01L25/16 ,  H01L25/167 ,  H01L25/18 ,  H01L25/50 ,  H01L27/0688 ,  H01L27/14634 ,  H01L2221/6835 ,  H01L2221/68359 ,  H01L2221/68363 ,  H01L2223/6677 ,  H01L2224/0807 ,  H01L2224/08123 ,  H01L2224/1134 ,  H01L2224/16 ,  H01L2224/24011 ,  H01L2224/24225 ,  H01L2224/24226 ,  H01L2224/24227 ,  H01L2224/3005 ,  H01L2224/30104 ,  H01L2224/305 ,  H01L2224/48091 ,  H01L2224/48101 ,  H01L2224/48227 ,  H01L2224/48247 ,  H01L2224/80896 ,  H01L2224/81894 ,  H01L2224/8303 ,  H01L2224/83092 ,  H01L2224/83099 ,  H01L2224/8319 ,  H01L2224/83193 ,  H01L2224/83345 ,  H01L2224/83359 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/83912 ,  H01L2224/83948 ,  H01L2224/9202 ,  H01L2224/9212 ,  H01L2225/06513 ,  H01L2225/06524 ,  H01L2225/06541 ,  H01L2225/06555 ,  H01L2225/06589 ,  H01L2924/00013 ,  H01L2924/00014 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01015 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01047 ,  H01L2924/01057 ,  H01L2924/01074 ,  H01L2924/01082 ,  H01L2924/0132 ,  H01L2924/014 ,  H01L2924/05442 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/10329 ,  H01L2924/1305 ,  H01L2924/13062 ,  H01L2924/13063 ,  H01L2924/13064 ,  H01L2924/13091 ,  H01L2924/14 ,  H01L2924/1461 ,  H01L2924/15153 ,  H01L2924/15165 ,  H01L2924/19041 ,  H01L2924/19043 ,  H01L2924/30105 ,  H01L2924/30107 ,  H01L2924/3011 ,  H01L2924/3025 ,  H01L2924/351 ,  Y10S148/012 ,  Y10S438/977 ,  H01L2224/13099 ,  H01L2924/01049 ,  H01L2924/01031 ,  H01L2924/00 ,  H01L2224/45099 ,  H01L2224/45015 ,  H01L2924/207 ,  H01L2224/8203 ,  H01L2224/821 ,  H01L2224/80001 ,  H01L2224/82

Abstract: A method may include the steps of directly bonding a semiconductor device having a substrate to an element; and removing a portion of the substrate to expose a remaining portion of the semiconductor device after bonding. The element may include one of a substrate used for thermal spreading, impedance matching or for RF isolation, an antenna, and a matching network comprised of passive elements. A second thermal spreading substrate may be bonded to the remaining portion of the semiconductor device. Interconnections may be made through the first or second substrates. The method may also include bonding a plurality of semiconductor devices to an element, and the element may have recesses in which the semiconductor devices are disposed.

Abstract translation: 一种方法可以包括将具有衬底的半导体器件直接接合到元件的步骤; 以及去除所述衬底的一部分以在结合之后露出所述半导体器件的剩余部分。 元件可以包括用于热扩散，阻抗匹配或RF隔离的衬底之一，天线以及由无源元件组成的匹配网络。 第二热扩散基板可以结合到半导体器件的其余部分。 互连可以通过第一或第二基底进行。 该方法还可以包括将多个半导体器件接合到元件，并且元件可以具有设置半导体器件的凹部。

公开(公告)号：US20160086913A1

公开(公告)日：2016-03-24

申请号：US14957501

申请日：2015-12-02

Applicant: ZIPTRONIX, INC.

Inventor： Qin-Yi Tong ,  Gaius Gillman Fountain, JR. ,  Paul M. Enquist

IPC: H01L23/00

CPC classification number: H01L24/83 ,  H01L21/0206 ,  H01L21/2007 ,  H01L21/31105 ,  H01L21/31116 ,  H01L21/322 ,  H01L21/76251 ,  H01L24/26 ,  H01L24/75 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/085 ,  H01L29/06 ,  H01L29/16 ,  H01L2224/8301 ,  H01L2224/8303 ,  H01L2224/83031 ,  H01L2224/8309 ,  H01L2224/83099 ,  H01L2224/8319 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/83948 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01018 ,  H01L2924/0102 ,  H01L2924/01023 ,  H01L2924/01033 ,  H01L2924/01039 ,  H01L2924/0106 ,  H01L2924/01061 ,  H01L2924/01072 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01084 ,  H01L2924/01093 ,  H01L2924/0132 ,  H01L2924/05442 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/10329 ,  H01L2924/14 ,  Y10S148/012 ,  Y10S438/974 ,  Y10T156/10 ,  Y10T156/1043 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01049 ,  H01L2924/01031 ,  H01L2924/3512 ,  H01L2924/00

Abstract: A method for bonding at low or room temperature includes steps of surface cleaning and activation by cleaning or etching. The method may also include removing by-products of interface polymerization to prevent a reverse polymerization reaction to allow room temperature chemical bonding of materials such as silicon, silicon nitride and SiO2. The surfaces to be bonded are polished to a high degree of smoothness and planarity. VSE may use reactive ion etching or wet etching to slightly etch the surfaces being bonded. The surface roughness and planarity are not degraded and may be enhanced by the VSE process. The etched surfaces may be rinsed in solutions such as ammonium hydroxide or ammonium fluoride to promote the formation of desired bonding species on the surfaces.

公开(公告)号：US20150064498A1

公开(公告)日：2015-03-05

申请号：US14474501

申请日：2014-09-02

Applicant: Ziptronix, Inc.

Inventor： Qin-Yi TONG

IPC: B32B7/04

CPC classification number: B32B7/04 ,  B32B2250/04 ,  B81C1/00357 ,  B81C2201/019 ,  B81C2203/0118 ,  B81C2203/019 ,  H01L21/3105 ,  H01L21/76251 ,  H01L24/26 ,  H01L24/29 ,  H01L24/81 ,  H01L24/83 ,  H01L24/92 ,  H01L2224/0401 ,  H01L2224/08059 ,  H01L2224/29186 ,  H01L2224/80896 ,  H01L2224/81894 ,  H01L2224/81895 ,  H01L2224/8319 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/9202 ,  H01L2224/9212 ,  H01L2224/92125 ,  H01L2924/01004 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01013 ,  H01L2924/01015 ,  H01L2924/01016 ,  H01L2924/01018 ,  H01L2924/01019 ,  H01L2924/01023 ,  H01L2924/01033 ,  H01L2924/01039 ,  H01L2924/01058 ,  H01L2924/01067 ,  H01L2924/01072 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01082 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/1305 ,  H01L2924/14 ,  H01L2924/1461 ,  H01L2924/351 ,  Y10T156/10 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/31504 ,  Y10T428/31678 ,  H01L2924/3512 ,  H01L2924/00 ,  H01L2924/05442

Abstract: A method of bonding includes using a bonding layer having a fluorinated oxide. Fluorine may be introduced into the bonding layer by exposure to a fluorine-containing solution, vapor or gas or by implantation. The bonding layer may also be formed using a method where fluorine is introduced into the layer during its formation. The surface of the bonding layer is terminated with a desired species, preferably an NH2 species. This may be accomplished by exposing the bonding layer to an NH4OH solution. High bonding strength is obtained at room temperature. The method may also include bonding two bonding layers together and creating a fluorine distribution having a peak in the vicinity of the interface between the bonding layers. One of the bonding layers may include two oxide layers formed on each other. The fluorine concentration may also have a second peak at the interface between the two oxide layers.

Abstract translation: 接合方法包括使用具有氟化氧化物的接合层。 可以通过暴露于含氟溶液，蒸汽或气体或通过注入将氟引入结合层。 接合层也可以使用在其形成期间将氟引入层中的方法形成。 接合层的表面用所需的物质，优选NH 2物质终止。 这可以通过将结合层暴露于NH 4 OH溶液来实现。 在室温下获得高粘结强度。 该方法还可以包括将两个结合层结合在一起并产生在接合层之间的界面附近具有峰的氟分布。 结合层之一可以包括彼此形成的两个氧化物层。 氟浓度也可以在两个氧化物层之间的界面处具有第二个峰。

公开(公告)号：US20140206176A1

公开(公告)日：2014-07-24

申请号：US14197070

申请日：2014-03-04

Applicant: ZIPTRONIX, INC.

Inventor： Qin-Yi TONG ,  Gaius Gillman FOUNTAIN, JR. ,  Paul M. ENQUIST

IPC: H01L21/02 ,  H01L21/322

CPC classification number: H01L24/83 ,  H01L21/0206 ,  H01L21/2007 ,  H01L21/31105 ,  H01L21/31116 ,  H01L21/322 ,  H01L21/76251 ,  H01L24/26 ,  H01L24/75 ,  H01L25/0657 ,  H01L25/50 ,  H01L27/085 ,  H01L29/06 ,  H01L29/16 ,  H01L2224/8301 ,  H01L2224/8303 ,  H01L2224/83031 ,  H01L2224/8309 ,  H01L2224/83099 ,  H01L2224/8319 ,  H01L2224/8385 ,  H01L2224/83894 ,  H01L2224/83896 ,  H01L2224/83948 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01007 ,  H01L2924/01013 ,  H01L2924/01018 ,  H01L2924/0102 ,  H01L2924/01023 ,  H01L2924/01033 ,  H01L2924/01039 ,  H01L2924/0106 ,  H01L2924/01061 ,  H01L2924/01072 ,  H01L2924/01074 ,  H01L2924/01075 ,  H01L2924/01084 ,  H01L2924/01093 ,  H01L2924/0132 ,  H01L2924/05442 ,  H01L2924/07802 ,  H01L2924/10253 ,  H01L2924/10329 ,  H01L2924/14 ,  Y10S148/012 ,  Y10S438/974 ,  Y10T156/10 ,  Y10T156/1043 ,  H01L2924/01014 ,  H01L2924/01015 ,  H01L2924/01049 ,  H01L2924/01031 ,  H01L2924/3512 ,  H01L2924/00

Abstract: A method for bonding at low or room temperature includes steps of surface cleaning and activation by cleaning or etching. The method may also include removing by-products of interface polymerization to prevent a reverse polymerization reaction to allow room temperature chemical bonding of materials such as silicon, silicon nitride and SiO2. The surfaces to be bonded are polished to a high degree of smoothness and planarity. VSE may use reactive ion etching or wet etching to slightly etch the surfaces being bonded. The surface roughness and planarity are not degraded and may be enhanced by the VSE process. The etched surfaces may be rinsed in solutions such as ammonium hydroxide or ammonium fluoride to promote the formation of desired bonding species on the surfaces.