FUEL ADDITIVES FOR TREATING INTERNAL DEPOSITS OF FUEL INJECTORS

    公开(公告)号:US20170158977A1

    公开(公告)日:2017-06-08

    申请号:US14958974

    申请日:2015-12-04

    Abstract: Methods for improving the injector performance, unsticking fuel injectors, and reducing an amount of alkali metal carboxylate deposits on internal components of fuel injectors. The method includes operating the diesel engine on a fuel composition comprising a major amount of diesel fuel and from about 45 to about 550 ppm by weight based on a total weight of fuel composition of a fuel additive consisting essentially of a compound of the formula wherein R is an alkyl or alkenyl group containing from 20 to 170 carbon atoms. The additive has a total acid number (TAN) ranging from about 50 to about 290 mg KOH/g. Fuel injectors of the fuel injected diesel engine have an average injector hole diameter of less than 160 μm and an average smallest clearance between injector needle and injector barrel/casing of less than about 10 μm.

    ALKOXYLATED QUATERNARY AMMONIUM SALTS AND DIESEL FUELS CONTAINING THE SALTS
    2.
    发明申请
    ALKOXYLATED QUATERNARY AMMONIUM SALTS AND DIESEL FUELS CONTAINING THE SALTS 有权
    烷基季铵盐和含有盐的柴油

    公开(公告)号:US20140318487A1

    公开(公告)日:2014-10-30

    申请号:US13871508

    申请日:2013-04-26

    Abstract: A fuel soluble additive for a diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel soluble additive includes a quaternary ammonium salt derived from an amido amine containing at least one tertiary amino group and an epoxide, in the presence of a proton donor selected from a carboxylic acid and an alkyl phenol. The amido amine is made in a reaction medium that is substantially devoid of an acylating agent.

    Abstract translation: 用于柴油发动机的燃料可溶性添加剂,用于改善燃料喷射器的性能的方法和用于清洁用于柴油发动机的燃料喷射器的方法。 燃料可溶性添加剂包括衍生自含有至少一个叔氨基和环氧化物的酰氨基的季铵盐,在选自羧酸和烷基苯酚的质子供体存在下。 酰胺胺在基本上不含酰化剂的反应介质中制备。

    HYDROCARBYL SOLUBLE QUATERNARY AMMONIUM CARBOXYLATES AND FUEL COMPOSITIONS CONTAINING THEM
    3.
    发明申请
    HYDROCARBYL SOLUBLE QUATERNARY AMMONIUM CARBOXYLATES AND FUEL COMPOSITIONS CONTAINING THEM 有权
    碳氢化合物可溶性季戊四醇酯和含有它们的燃料组合物

    公开(公告)号:US20150376524A1

    公开(公告)日:2015-12-31

    申请号:US14315302

    申请日:2014-06-25

    Abstract: A fuel additive composition, fuel composition, method of improving the injector performance of a fuel injected engine, method for preventing or cleaning up deposits in an engine or fuel system, method of reducing wear in a fuel system of an engine, and method of improving the demulsibility of a fuel composition. The fuel composition includes from about 5 to about 300 ppm by weight based on a total weight of the fuel composition of a hydrocarbyl soluble quaternary ammonium carboxylate derived from a quaternary ammonium carbonate and an organic acid.

    Abstract translation: 燃料添加剂组合物,燃料组合物,改善燃料喷射发动机的喷射器性能的方法,用于防止或清除发动机或燃料系统中的沉积物的方法,减少发动机的燃料系统中的磨损的方法和改进方法 燃料组合物的破乳性。 基于燃料组合物的总重量计,燃料组合物包含衍生自碳酸季铵和有机酸的烃基可溶性季铵盐的约5至约300重量ppm。

    QUATERNARY AMMONIUM DETERGENT FUEL ADDITIVES
    4.
    发明申请
    QUATERNARY AMMONIUM DETERGENT FUEL ADDITIVES 有权
    第四季度清洁剂燃料添加剂

    公开(公告)号:US20150096528A1

    公开(公告)日:2015-04-09

    申请号:US14048879

    申请日:2013-10-08

    Abstract: A fuel soluble additive for a diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel soluble additive includes a quaternary ammonium salt derived from the reaction of (a) a hydrocarbyl amine containing at least one tertiary amino group, (b) an epoxide compound selected from a glycidol, a glycidyl ether, glycidyl ester, polyglycidyl ether, a polyglycidyl ester, and combinations thereof, wherein substituents of the glycidyl group have, on average, less than five carbon atoms per hetero atom, and (c) optionally a proton donor.

    Abstract translation: 用于柴油发动机的燃料可溶性添加剂,用于改善燃料喷射器的性能的方法和用于清洁用于柴油发动机的燃料喷射器的方法。 燃料可溶性添加剂包括衍生自(a)含有至少一个叔氨基的烃基胺的反应的季铵盐,(b)选自缩水甘油,缩水甘油醚,缩水甘油酯,聚缩水甘油醚, 聚缩水甘油酯及其组合,其中缩水甘油基的取代基平均每个杂原子平均具有小于5个碳原子,和(c)任选的质子供体。

    FUEL ADDITIVE FOR DIESEL ENGINES
    7.
    发明申请
    FUEL ADDITIVE FOR DIESEL ENGINES 审中-公开
    燃油添加剂柴油发动机

    公开(公告)号:US20150232774A1

    公开(公告)日:2015-08-20

    申请号:US14184188

    申请日:2014-02-19

    Abstract: In accordance with the disclosure, exemplary embodiments provide a method for improving injector performance, a method for restoring power to a diesel fuel injected engine, and a method of operating a fuel injected diesel engine. The method includes combining a fuel with a reaction product derived from (i) a hydrocarbyl substituted dicarboxylic acid or anhydride, wherein the hydrocarbyl substituent has a number average molecular weight ranging from about 600 to about 800 and (ii) a polyamine includes a compound of the formula H2N—((CHR1—(CH2)n—NH)m—H, wherein R1 is hydrogen, n is 1 and m is 4, wherein a molar ratio of (i) reacted with (ii) ranges from about 1.3:1 to about 1.6:1. The reaction product, as made, contains no more than 3.0 wt. % unreacted polyamine in the reaction product based on active material in the reaction product.

    Abstract translation: 根据本公开,示例性实施例提供了一种用于改善喷射器性能的方法,用于恢复柴油喷射发动机的功率的方法以及操作燃料喷射柴油发动机的方法。 该方法包括将燃料与源自(i)烃基取代的二羧酸或酸酐的反应产物组合,其中烃基取代基的数均分子量为约600至约800,和(ii)多胺包括 式(II)其中R1为氢,n为1,m为4,其中(i)与(ⅱ)反应的摩尔比为约1.3: 1至约1.6:1。反应产物如反应产物中基于活性物质在反应产物中含有不多于3.0重量%的未反应的多胺。

    FUEL ADDITIVE FOR IMPROVED PERFORMANCE IN FUEL INJECTED ENGINES
    9.
    发明申请
    FUEL ADDITIVE FOR IMPROVED PERFORMANCE IN FUEL INJECTED ENGINES 有权
    燃油添加剂用于燃油喷射发动机的改进性能

    公开(公告)号:US20130333650A1

    公开(公告)日:2013-12-19

    申请号:US13666226

    申请日:2012-11-01

    Abstract: In accordance with the disclosure, exemplary embodiments provide a fuel additive concentrate, a method for cleaning fuel injectors, a method for restoring power to a diesel fuel injected engine, a fuel composition, and a method of operating a fuel injected diesel engine. The additive concentrate includes (a) a hydrocarbyl substituted quaternary ammonium internal salt; and (b) a reaction product of (i) a hydrocarbyl substituted dicarboxylic acid, anhydride, or ester and (ii) an amine compound or salt thereof of the formula wherein R is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product (b) on average has less than 2 amino-triazole groups per molecule. A weight ratio of (a) to (b) in the additive concentrate ranges from about 10:1 to about 1:10.

    Abstract translation: 根据本公开,示例性实施例提供燃料添加剂浓缩物,用于清洁燃料喷射器的方法,用于恢复柴油燃料喷射发动机的功率的方法,燃料组合物和操作燃料喷射柴油发动机的方法。 添加剂浓缩物包括(a)烃基取代的季铵盐; 和(b)(i)烃基取代的二羧酸,酸酐或酯的反应产物和(ii)下式的胺化合物或其盐其中R选自氢和含约1至约 15个碳原子,并且R 1选自氢和含有约1至约20个碳原子的烃基。 反应产物(b)每分子平均具有少于2个氨基 - 三唑基团。 添加剂浓缩物中(a)至(b)的重量比为约10:1至约1:10。

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